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11.
公开(公告)号:AT48006T
公开(公告)日:1989-12-15
申请号:AT86116462
申请日:1986-11-27
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , HISGEN BERND DR , PORTUGALL MICHAEL DR
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公开(公告)号:DE3629208A1
公开(公告)日:1988-03-03
申请号:DE3629208
申请日:1986-08-28
Applicant: BASF AG
Inventor: HISGEN BERND DR , KOCK HANS-JAKOB DR , PORTUGALL MICHAEL DR , SEILER ERHARD DR , BLINNE GERD DR
IPC: C08G63/68 , C08G63/19 , C08G63/60 , C08G63/685 , C08G63/688 , C08G73/16 , C09K19/38 , D01F6/84 , C08G73/10 , C08L67/00 , C08L79/08 , C08J5/18
Abstract: Fully aromatic thermotropic polyesters based on (A) from 30 to 60 mol % of 4-hydroxybenzoic acid, (B) from 20 to 35 mol % of a mixture of (B1) terephthalic acid, (B2) isophthalic acid and (B3) from 0.5 to 5 mol % of a dicarboxylic acid of the general formula I where X is -O-, -S-, -SO2-, -CO-, -CH2- or -C(CH3)2-, n is 0 or 1 and the two imide nitrogen atoms are meta or para to X, or their C1-C8-alkyl, C1-C8-alkoxy, aryl, chlorine or bromine derivatives which are substituted in the nucleus, the molar ratio of B1 to B2 being from 1.04:1 to 19:1, and (C) from 20 to 35 mol % of a mixture of (C1) hydroquinone and (C2) 4,4'-dihydroxydiphenyl, the molar ratio of C1 to C2 being from 0.1:1 to 2.67:1 and the molar ratio of B to C being from 0.9:1 to 1.1:1.
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公开(公告)号:DE3542855A1
公开(公告)日:1987-06-11
申请号:DE3542855
申请日:1985-12-04
Applicant: BASF AG
Inventor: HISGEN BERND DR , KOCK HANS-JAKOB DR
Abstract: Wholly aromatic mesomorphic polyester amides which form a liquid-crystalline fiber-forming melt below 320 DEG C., composed of (a) from 3 to 30 mol % of repeat units of the formula I I (b) from 3 to 30 mol % of repeat units of the formula II and/or III II III (c) from 2 to 25 mol % of one or more of the repeat units of the formula IV, V or VI, IV V VI (d) a molar amount corresponding to the total amount of components (a), (b) and (c) excluding the repeat unit of the formula III, of the repeat units of the formula VII VII which, if desired, can in part be replaced by repeat units of the formula VIII VIII (e) if desired from 5 to 25 mol % of repeat units of the formula IX IX (f) repeat units of the formula X X the molar proportions of components (a), (b), (c), (d), (e) and (f) in each case adding up to 100 mol %, and preparation thereof.
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公开(公告)号:DE3542779A1
公开(公告)日:1987-06-11
申请号:DE3542779
申请日:1985-12-04
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , HISGEN BERND DR
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公开(公告)号:DE3533252A1
公开(公告)日:1987-03-19
申请号:DE3533252
申请日:1985-09-18
Applicant: BASF AG
Inventor: NAARMANN HERBERT DR , PORTUGALL MICHAEL DR , HISGEN BERND DR
Abstract: A process for the preparation of oriented, electroconductive homopolymers and copolymers of compounds from the class consisting of 5-membered heterocyclic compounds having a conjugated pi -electron system containing nitrogen or sulphur as hetero atom, by electrochemical oxidation of these compounds in electrolyte solvents in the presence of conductive salts and in the presence of liquid crystals, and the use of such polymers as conductors in electro technology.
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公开(公告)号:DE3689663D1
公开(公告)日:1994-03-31
申请号:DE3689663
申请日:1986-11-24
Applicant: BASF AG
Inventor: HISGEN BERND DR , PORTUGALL MICHAEL , STERZEL HANS-JOSEF DR
Abstract: Wholly aromatic mesomorphic polyester amides which form a liquid-crystalline fiber-forming melt below 320 DEG C. and are composed of (a) from 3 to 30 mol % of repeat units of the formula I (b) from 3 to 25 mol % of one or more of the repeat units of the formulae II, III and IV II III IV (c) a molar amount corresponding to the total amount of components (a) and (b) of repeat units of the formulae V and/or VI V VI (d) repeat units of the formula VII VII (e) if desired from 5 to 25 mol % of repeat units of the formula VIII VIII the mole percentages of components (a), (b), (c), (d) and (e) adding up to 100 mol % in each case, and the preparation and use thereof.
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公开(公告)号:DE3775658D1
公开(公告)日:1992-02-13
申请号:DE3775658
申请日:1987-08-20
Applicant: BASF AG
Inventor: PORTUGALL MICHAEL DR , HISGEN BERND DR , KOCK HANS-JAKOB DR , SEILER ERHARD DR , BLINNE GERD DR
IPC: C08G63/60 , C08G63/68 , C08G63/682 , C09K19/38 , D01F6/84
Abstract: New fully aromatic thermotropic polyesters consist, by mol., of : (A) 30-60% 4-hydroxybenzoic acid, (B) 20-35 % mixt of: (B1) tetephthalic acid and (B2) isophthalic acid in molar ratio (B1) : (B2) 1.04 : 1 to 19 : 1 (1.5 : 1 to 10 : 1), and (C) 20-35 % mixt of : (C1) hydroquinone, (C2) 4,4'-dihydroxydiphenyl and (C3) 0-5 (0.5-5) esp 1-4 % dihydroxy cpd having formula (I) R,R' each = 1- alkyl, halogen or aryl; n, p each = 1, 2 or 3; m = 0 or 1. The molar ratio (C1) : (C2) is 0.1 : 1 to 2.67 : 1 (0.5 : 1 to 2.33 : 1) and the molar ratio (B) : (C) is 0.9 to 1.1 : 1.
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公开(公告)号:DE3766889D1
公开(公告)日:1991-02-07
申请号:DE3766889
申请日:1987-06-23
Applicant: BASF AG
Inventor: KOCK HANS-JAKOB DR , PORTUGALL MICHAEL DR , HISGEN BERND DR , MERTES JUERGEN DR
Abstract: Fully aromatic mesomorphic polyesters which give a liquid crystalline filament-forming melt below 300 DEG C. consist of (a) from 5 to 25 mol % of repeating units of the formula I (I) (b) from 5 to 25 mol % of repeating units of the formula II (II) (c) from 10 to 50 mol % of repeating units of the formula III (III) and (d) not less than 10 mol % of repeating units of the formula IV (IV) the sum of the molar amounts of components (a), (b), (c) and (d) being 100 mol %, and the molar ratio of components (a) and (b) to component (c) being from 0.9:1 to 1.1:1.
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公开(公告)号:DE3900717A1
公开(公告)日:1990-07-19
申请号:DE3900717
申请日:1989-01-12
Applicant: BASF AG
Inventor: HISGEN BERND DR , POHLEMANN HEINZ DR , HEINZ GERHARD DR , ROSENAU BERNHARD DR , ZEINER HARTMUT DR , SCHLEMMER LOTHAR , LAUN MARTIN DR
Abstract: Polymer compositions comprising A) thermotropic-mesomorphic polycondensates (5-99.9% by weight), B) apatite (0.1-70% by weight) and optionally C) fillers other than B) and D) non-thermotropic-mesomorphic polymers other than A), have an interesting property profile.
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