15.
    发明专利
    未知

    公开(公告)号:DK0901982T3

    公开(公告)日:2002-03-04

    申请号:DK98117210

    申请日:1998-09-09

    Applicant: BASF AG

    Abstract: The catalyst is in tablet form having a diameter of 0.8-5 mm and a height of 0.8-5 mm. The catalyst is prepared by: (a) precipitating a solution of zinc and aluminium salts (Zn:Al ratio is 3-1:1-3) with and alkali carbonate or hydroxide solution at a pH of 5-12 and a temperature of 20-100 degrees C; (b) removing and washing the precipitate to remove alkali ions; (c) drying the precipitate; (d) calcining the precipitate at 250-800 degrees C to a mixed oxide; (e) dispersing the mixed oxide in an acid solution of copper and zinc salts (Cu:Zn ratio is 1-20:5-1); (f) precipitating the dispersion with an alkali carbonate or hydroxide solution at a pH of 6-9 and a temperature of 20-100 degrees C; and (g) repeating steps (b) to (d). The solutions in steps (a) and/or (e) additionally contain oxides of platinum group metals, groups 5, 11 and the lanthanides.

    20.
    发明专利
    未知

    公开(公告)号:DE19739773A1

    公开(公告)日:1999-03-11

    申请号:DE19739773

    申请日:1997-09-10

    Applicant: BASF AG

    Abstract: The catalyst is in tablet form having a diameter of 0.8-5 mm and a height of 0.8-5 mm. The catalyst is prepared by: (a) precipitating a solution of zinc and aluminium salts (Zn:Al ratio is 3-1:1-3) with and alkali carbonate or hydroxide solution at a pH of 5-12 and a temperature of 20-100 degrees C; (b) removing and washing the precipitate to remove alkali ions; (c) drying the precipitate; (d) calcining the precipitate at 250-800 degrees C to a mixed oxide; (e) dispersing the mixed oxide in an acid solution of copper and zinc salts (Cu:Zn ratio is 1-20:5-1); (f) precipitating the dispersion with an alkali carbonate or hydroxide solution at a pH of 6-9 and a temperature of 20-100 degrees C; and (g) repeating steps (b) to (d). The solutions in steps (a) and/or (e) additionally contain oxides of platinum group metals, groups 5, 11 and the lanthanides.

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