公开(公告)号：DE50102261D1

公开(公告)日：2004-06-17

申请号：DE50102261

申请日：2001-01-10

Applicant: BASF AG

Inventor： HECHLER CLAUS ,  KAMMEL ULRICH ,  MACHHAMMER OTTO ,  OLBERT GERHARD ,  ZEHNER PETER

IPC: B01J8/02 ,  B01J19/24 ,  C07C51/265 ,  C07C51/31 ,  C07C57/145 ,  F28D9/00 ,  F28F13/08

公开(公告)号：DE10054462B4

公开(公告)日：2005-02-17

申请号：DE10054462

申请日：2000-11-03

Applicant: BASF AG

Inventor： KAMMEL ULRICH ,  BENFER REGINA ,  LENZ WALTER ,  MUGRAUER HANS-MARTIN ,  SPIEGLER WOLFGANG ,  ZEHNER PETER ,  ZIPPLIES MATTHIAS ,  FLORY KLAUS

IPC: B01J19/24 ,  C07C41/03 ,  C08G65/26 ,  C08G65/28 ,  C07B41/04 ,  C07C43/11 ,  C07C43/13

公开(公告)号：BR0210334A

公开(公告)日：2004-09-21

申请号：BR0210334

申请日：2002-06-10

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26

Abstract: A process is described for preparing sorbitol by catalytic hydrogenation of a monosaccharide forming sorbitol on hydrogenation in the liquid phase, which comprises the catalyst being obtainable by: i) single or multiple treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i).

公开(公告)号：AU2002317792A1

公开(公告)日：2002-12-23

申请号：AU2002317792

申请日：2002-06-10

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK ,  MAAS-BRUNNER MELANIE

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26

Abstract: A process is described for preparing sorbitol by catalytic hydrogenation of a monosaccharide forming sorbitol on hydrogenation in the liquid phase, which comprises the catalyst being obtainable by: i) single or multiple treatment of an amorphous silicon dioxide based support material with a halogen-free aqueous solution of a low-molecular-weight ruthenium compound and subsequent drying of the treated support material at below 200° C., ii) reducing the solid obtained in i) with hydrogen at from 100 to 350° C., step ii) being carried out immediately after step i).

公开(公告)号：DE10128205A1

公开(公告)日：2002-12-12

申请号：DE10128205

申请日：2001-06-11

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  C07H1/00 ,  B01J37/18 ,  C07B61/00 ,  C07C29/132 ,  C07C29/141 ,  C07C29/145 ,  C07C31/18 ,  C07C31/26 ,  C07H15/04 ,  C13B35/00

Abstract: Providing a ruthenium catalyst for the production of sugar alcohols. Ruthenium catalysts (I) are prepared by: (A) a single or multiple treatment of an amorphous silicon dioxide support material with a halogen free solution of a low mol. wt. ruthenium compound followed by drying at below 200 deg C; (B) reduction of the resulting solid with hydrogen at 100-350 deg C such that step (B) is carried out immediately after step (A). An Independent claim is included for a process for the production of sugar alcohols by catalytic hydrogenation of the corresponding mono- and oligosaccharides in the liquid phase at the heterogeneous catalyst (I), excluding a process for the production of sorbitol.

公开(公告)号：DE10054462A1

公开(公告)日：2002-06-06

申请号：DE10054462

申请日：2000-11-03

Applicant: BASF AG

Inventor： KAMMEL ULRICH ,  BENFER REGINA ,  LENZ WALTER ,  MUGRAUER HANS-MARTIN ,  SPIEGLER WOLFGANG ,  ZEHNER PETER ,  ZIPPLIES MATTHIAS ,  FLORY KLAUS

IPC: B01J19/24 ,  C07C41/03 ,  C08G65/26 ,  C08G65/28 ,  C07B41/04 ,  C07C43/11 ,  C07C43/13

Abstract: Preparation of polyalcoholates involves the steps: (a) reaction of alcohols with bases with formation of an alcoholate containing mixture, (b) preparation of the mixture in a water-free form, (1c) feeding of the mixture into a rotary reactor, (d) feeding of alkylene oxide into the reactor in a number of sites, (e) reaction of the alcoholate and/or products of reaction. Preparation of polyalcoholates involves the steps: (a) reaction of alcohols with bases with formation of an alcoholate containing mixture; (b) preparation of the mixture in a water-free form; (c) feeding of the mixture into a rotary reactor; (d) feeding of alkylene oxide into the reactor in a number of sites; (e) reaction of the alcoholate and/or products of reaction between the alcoholate and alkylene oxide into the reactor. The steps (a) to (e) are continuous, the reactor is cooled externally, and the reactor is in the form of a plate-type heat exchanger, a plate-type heat exchanger system in a container with vapor cooling, a single way tube type heat exchanger, or a multi-way tube heat exchanger.

公开(公告)号：CA2449522A1

公开(公告)日：2002-12-19

申请号：CA2449522

申请日：2002-06-10

Applicant: BASF AG

Inventor： KAMMEL ULRICH ,  MAAS-BRUNNER MELANIE ,  ARNDT JAN-DIRK ,  VANOPPEN DOMINIC

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26

Abstract: The invention relates to a method for the production of sorbit by catalytic hydrogenation of a monosaccharide forming sorbit during said hydrogenation i n a liquid phase, characterized in that the catalyst is obtained by 1) single or multiple treatment of an amorphous silicon dioxide based carrier material wi th a halogen-free aqueous solution of a low-molecular ruthenium compound and subsequent drying of the treated carrier material at a temperature of less than 200~ C, ii) reduction of the solid obtained in I) with hydrogen at a temperature ranging from 100 to 350~ C, wherein step ii) is carried out directly after step i).

公开(公告)号：DE10128203A1

公开(公告)日：2002-12-12

申请号：DE10128203

申请日：2001-06-11

Applicant: BASF AG

Inventor： VANOPPEN DOMINIC ,  MAAS-BRUNNER MELANIE ,  KAMMEL ULRICH ,  ARNDT JAN-DIRK

IPC: B01J21/08 ,  B01J23/46 ,  B01J35/10 ,  B01J37/02 ,  B01J37/18 ,  C07B61/00 ,  C07C29/14 ,  C07C29/141 ,  C07C31/26 ,  C07C29/132

Abstract: A process for the production of sorbitol comprises catalytic hydrogenation of an aqueous solution of a monosaccharide. A process for the production of sorbitol comprises catalytic hydrogenation of an aqueous solution of a monosaccharide using a ruthenium catalyst whereby the catalyst is prepared by: (A) a single or multiple treatment of an amorphous silicon dioxide support material with a halogen free solution of a low mol. wt. ruthenium compound followed by drying at below 200 deg C; (B) reduction of the resulting solid with hydrogen at 100-350 deg C such that step (B) is carried out immediately after step (A).

公开(公告)号：AU2515801A

公开(公告)日：2001-08-07

申请号：AU2515801

申请日：2001-01-12

Applicant: BASF AG

Inventor： KAMMEL ULRICH ,  MACHHAMMER OTTO ,  ZEHNER PETER

IPC: B01D3/14 ,  B01D3/00

公开(公告)号：DE10002810A1

公开(公告)日：2001-07-26

申请号：DE10002810

申请日：2000-01-24

Applicant: BASF AG

Inventor： WALCH ANDREAS ,  KAMMEL ULRICH ,  HEIDEMANN THOMAS

IPC: C07C51/265 ,  C07C51/46 ,  C07D307/89 ,  B01D3/00

Abstract: Production of phthalic anhydride from o-xylene by 2-stage oxidation with recycle of unreacted xylene from the first stage comprises removing toluene from the xylene recycle stream by distillation. Production of phthalic anhydride comprises: (1) partially oxidizing o-xylene in the liquid phase with oxygen or a mixture of oxygen and an inert gas in the presence of a catalyst; (2) distilling the partially oxidized mixture to separate a fraction comprising unreacted xylene; (3) distilling the xylene fraction to remove toluene; (4) recycling the xylene fraction to step (a); and (5) oxidizing the xylene-depleted partially oxidized mixture in the gas phase to produce phthalic anhydride.