公开(公告)号：DE19511691A1

公开(公告)日：1996-10-02

申请号：DE19511691

申请日：1995-03-30

Applicant: BASF AG

Inventor： PATSCH MANFRED DR ,  KILBURG HEIKE DR ,  ZAMPONI ANDREA DR

IPC: C09B62/507 ,  C09B62/006 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66 ,  C07C317/32 ,  C07D295/04

Abstract: Reactive azo dyes of formula (I) are new: (I): in which n =1 or 2; R = H or OH; and D when n = 1, is a residue of formula (II) or when n = 2, is a residue of formula (III); (III): in which the ring A may be benzoannelated; R , R and R independently = H, 1-4 C alkyl, 1-4 C alkoxy, halogen or hydroxysulphonyl; E = H, an heterocyclic anchoring gp. or an aliphatic anchoring gp.; Y = vinyl or C2H4-Q; Q = a gp. that is split off under alkaline reaction conditions; and T = a bridging member, provided that when n = 1, R = OH and R , R and R each = H, E is neither H nor a residue of formula SO2-Y, W -SO2-Y or CONX-W -SO2-Y, in which Y is as above, W = 1-4 C alkylene and X = H or 1-4 C alkyl.

公开(公告)号：DE4434989A1

公开(公告)日：1996-04-04

申请号：DE4434989

申请日：1994-09-30

Applicant: BASF AG

Inventor： DORNHAGEN JUERGEN DR ,  KILBURG HEIKE DR ,  PATSCH MANFRED DR ,  LOEFFLER HERMANN ,  SCHAFFER ORTWIN DR

IPC: C09B62/513 ,  C07C309/47 ,  C07C309/50 ,  C09B62/08 ,  C09B62/44 ,  C09B62/507 ,  C09B62/008 ,  C09B62/085 ,  C09B62/51 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66 ,  C07C303/22 ,  C07D295/04 ,  C07D251/50 ,  C07D403/12

Abstract: Reactive dyes have the formula (I), in which n equals 1 or 2; R stands for hydrogen or hydroxylsulfonyl; R stands for hydrogen or hydroxy; R stands for substituted C1-C4-alkyl, C5-C7-cycloalkyl or substituted phenyl; R stands for hydrogen or R and R form a heterocyclic rest together with the nitrogen atom that interconnects them; and D stands for the rest of a diazo or tetrazo component with at least one anchor rest. Also disclosed is the use of said dyes for dyeing or printing organic substrates having hydroxy groups or nitrogen atoms, and new aminonaphthalenes.

公开(公告)号：ES2081659T3

公开(公告)日：1996-03-16

申请号：ES93107552

申请日：1993-05-10

Applicant: BASF AG

Inventor： ETZBACH KARL-HEINZ DR ,  KILBURG HEIKE DR ,  MUELLER HARRY ,  NUYKEN OSKAR PROF DR ,  STROHRIEGL PETER DR

IPC: C08F8/32 ,  C08F8/30 ,  C09B69/10 ,  G02F1/35 ,  G02F1/361

Abstract: The invention relates to a process for the preparation of (meth)acrylate polymers containing pendant (side-chain) nonlinear-optical chromophores and having moelcular weights of between 5000 and 5,000,000, in which polymers of (meth)acryloyl chloride are reacted in a polymer-analogous reaction in solution with D- omega -aminoalkyl chromophores of the formula (I) in which D is an electron donor, A is an electron acceptor, R is H, alkyl or cycloalkyl, X are CH groups and/or N atoms and m is from 2 to 11. The polymers prepared according to the invention can be used in optical components.

公开(公告)号：DE4218359A1

公开(公告)日：1993-12-09

申请号：DE4218359

申请日：1992-06-04

Applicant: BASF AG

Inventor： ETZBACH KARL-HEINZ DR ,  SENS RUEDIGER DR ,  KILBURG HEIKE DR

IPC: C08F20/34 ,  C08F20/38 ,  C08F246/00 ,  C09B69/10 ,  G02F1/35 ,  G02F1/355 ,  G02F1/361 ,  G03C1/12 ,  C09B23/04 ,  C09B23/16 ,  C09K19/60 ,  C08F20/30 ,  C08F20/54

Abstract: Methine or azamethine dye polymers containing as characteristic monomer units the radicals of the formulae I, II, III and IV where G is a bivalent organic radical, Z is nitrogen or CH, R and R are each hydrogen, C1-C6-alkyl or optionally substituted C1-C6-alkoxy, R is hydrogen, C1-C6-alkyl, C5-C7-cycloalkyl or C3-C4-alkenyl, R is hydrogen, deuterium, methyl, trideuterated methyl or chlorine, R is hydrogen or deuterium, Y and Y are each C2-C10-alkylene, E is oxygen, imino or C1-C4-alkylimino, and X is hydroxyl, optionally substituted C1-C6-alkoxy, phenoxy, amino or C1-C4-mono- or -dialkylamino, the ring A can be benzofused, and the average molecular weight of the polymer is 1,000 to 100,000, its use in nonlinear optics, and the use of monomeric methine or azamethine dyes for preparing the novel polymers.

公开(公告)号：DE19619239A1

公开(公告)日：1997-11-20

申请号：DE19619239

申请日：1996-05-13

Applicant: BASF AG

Inventor： ZAMPONI ANDREA DR ,  PATSCH MANFRED DR ,  KILBURG HEIKE DR

IPC: C07C317/36 ,  C07D251/50 ,  C09B62/44 ,  C09B62/51 ,  C09B62/008 ,  C09B62/01 ,  D06P1/38 ,  D06P3/10 ,  D06P3/66

Abstract: The invention relates to reactive dyes of the general formula (I), in which Y is vinyl or a radical of the formula C2H4Q, Q being a group which can be split in alkaline reaction conditions, Z is hydrogen, C1-C4 alkanoyl or a heterocyclic reactive anchor group which can optionally carry a further chromophore radical and K is the radical of a coupling component, provided that K is not hydroxy naphthylamine coupled to the hydroxyl group in the o position. The invention also relates to the use of said dyes for dyeing or printing of organic substrates having hydroxy groups or nitrogen atoms, and also to their intermediate products.

公开(公告)号：DE4419659A1

公开(公告)日：1995-12-07

申请号：DE4419659

申请日：1994-06-06

Applicant: BASF AG

Inventor： PATSCH MANFRED DR ,  DORNHAGEN JUERGEN DR ,  KILBURG HEIKE DR

IPC: B01D61/14 ,  C09B62/517 ,  C07D487/22 ,  C07F19/00 ,  C09B67/54 ,  D06P1/384

Abstract: Phthalocyanine reactive dyes of formula (I) are new. Pc = an opt. metallised phthalocyanine system, opt. substd. by Cl or Ph; R = H or 1-6C alkyl; R , R = H; 1-6C alkyl, opt. with 1 or 2 ether O atoms in the chain; or Ph; or NR R = a 5-6-membered satd. heterocyclic gp., opt. with other hetero-atoms; L = 2-4C alkylene, opt. with an ether O atom in the chain; naphthylene; -Phe-; -(CH2)n-Phe- or -Phe-(CH2)n-; Phe = phenylene, opt. with a HOSO2-CH2- or HOSO2- substit.; n = 1 or 2; K = -Phem-, -(CH2)n-Phem or -Phem-(CH2)n; Phem = m-phenylene, opt. with a HOSO2-CH2- or HOSO2- substit.; J = -Phep-, -(CH2)n-Phep- or -Phep-(CH2)n-; Phep = p-phenylene, opt. with a HOSO2-CH2- or HOSO2- substit.; Y = vinyl or C2H4-Q; Q = a gp. eliminated under alkaline conditions; M = the equiv. of a cation; m, t = 0 or 1; r = 0-3; s = 0.5-3; p + q = 1-3.5; p, q not = 0. The dye (HO3S)1.5-CuPc-(SO2-NH-Phem, p-SO2C2H4OSO3H)2.3 (Phem,Phep = m- or p-phenylene) is excluded.

公开(公告)号：DE4215357A1

公开(公告)日：1993-11-18

申请号：DE4215357

申请日：1992-05-13

Applicant: BASF AG

Inventor： ETZBACH KARL-HEINZ DR ,  KILBURG HEIKE DR ,  MUELLER HARRY ,  NUYKEN OSKAR PROF DR ,  STROHRIEGL PETER DR

IPC: C08F8/32 ,  C08F8/30 ,  C09B69/10 ,  G02F1/35 ,  G02F1/361 ,  C08F8/14 ,  C08F20/58 ,  C08F20/60

Abstract: The invention relates to a process for the preparation of (meth)acrylate polymers containing pendant (side-chain) nonlinear-optical chromophores and having moelcular weights of between 5000 and 5,000,000, in which polymers of (meth)acryloyl chloride are reacted in a polymer-analogous reaction in solution with D- omega -aminoalkyl chromophores of the formula (I) in which D is an electron donor, A is an electron acceptor, R is H, alkyl or cycloalkyl, X are CH groups and/or N atoms and m is from 2 to 11. The polymers prepared according to the invention can be used in optical components.

公开(公告)号：DE4116594A1

公开(公告)日：1992-11-26

申请号：DE4116594

申请日：1991-05-22

Applicant: BASF AG

Inventor： KILBURG HEIKE DR ,  ETZBACH KARL-HEINZ DR ,  BECK KARIN HEIDRUN DR ,  STROHRIEGL PETER DR ,  MUELLER HARRY ,  NUYKEN OSKAR PROF DR

IPC: C08F20/30 ,  C08F8/00 ,  C08F20/26 ,  C08F20/34 ,  G02F1/361

Abstract: The invention relates to a process for the preparation of (meth)acrylate polymers with side-chain, non-linear optical chromophores and molecular weights of from 5000 to 5000000, which comprises reacting polymers of (meth)acryloyl chloride in solution with D- omega -hydroxyalkyl chromophores of the formula (I) or the alcoholates thereof (I) where D is an electron donor, A is an electron acceptor, X is CH and/or N, and m is from 2 to 11. The polymers can be used in optical components.