Polyester-imide precondensates - useful as impregnating, laminating and adhesive agents

    公开(公告)号:DE2412472A1

    公开(公告)日:1975-10-23

    申请号:DE2412472

    申请日:1974-03-15

    Applicant: BASF AG

    Abstract: Impregnating-, or laminating and adhesive agent based on polyesterimide precondensates, and opt. contg. polar organic solvents, comprises the reaction prod. of (A) melamine, (B) >=1 di or polybasic acid and/or its anhydride, acid chloride or ester of a lower mono-alkanol, (C) >=1 polyvalent alcohol and, opt. (D) >=1 aromatic dicarboxylic acids or their esters with lower alkanols, the molar relationship of (A):(B)being from 1:1.1 to 1:3. Pref. the precondensate contains (condensed) 5-15 wt.% (A), 15-70 wt.% (B), 10-25 wt.% (C) and 5-55 wt.% (D). The precondensates show esp. advantageous processing props. and impregnates, laminates and adhesive bonds made with the agent show excellent flexural strength and good temp. stability.

    Di-imido-di-carbonyl chlorides prodn - via acid obtd from trimellitic anhydride and aromatic diamine in inert org suspension

    公开(公告)号:DE2425667A1

    公开(公告)日:1975-12-11

    申请号:DE2425667

    申请日:1974-05-28

    Applicant: BASF AG

    Abstract: Dicarbonyl chlorides (I) contg. imide gps. are produced by (a) suspending trimellitic anhydride (II) and aromatic diamines (III) of the formula H2N.C6H4.X.C6H4.NH2) (in which X is CH2, 0, S, SO2 or CO; the NH2 gps. can be in the o-, m- or p-position) in a high-boiling inert organic liquid (IV) and reacting to the diimido-dicarboxylic acid (V) and then (b) converting (V) to (I) with SOCL2 or COCL2. High temp. -resistant polymers and pigments are produced by reacting a suspension of (I) in PhNO2, without further purificn., with diphenols, diamines or aminophenols. (I) are obtd. in almost 100% yield and in high purity by a process suitable for technical operation.

    Aqueous polyesterimide dispersn - for forming coatings, impregnates and adhesive bonds

    公开(公告)号:DE2412470A1

    公开(公告)日:1975-10-23

    申请号:DE2412470

    申请日:1974-03-15

    Applicant: BASF AG

    Abstract: Finely divided aqs. polyesterimided dispn. contains 20-60 wt. % polyesterimide with a particle dia. of 5 mum., 0.5-8 wt. % flow-promoting agent and -8 wt. % catalyst, the polyesterimide being a precondensate of (A) melamine, (B) >=1 di or poly-basic acid and/or its anhydride, acid chloride or ester of a lower mono-alkanol, (C) >=1 polyvalent alcohol and opt. (D) >=1 aromatic dicarboxylic acid or their esters with lower alkanols, the molar ratio of (A):(B) being from 1:1. 1 to 1:3. Prep. the precondensate contains (condensed) 5-15 wt. % (A), 15-70 wt. % (B), 15-25 wt. % (C) and 5-55 wt. % (D). The dispersion exhibits excellent storage stability and is suitable for prodn. of coatings, impregnations and adhesives bonds with improved heat stability, hardness and solvent stability.

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