公开(公告)号：DE3043601A1

公开(公告)日：1982-07-08

申请号：DE3043601

申请日：1980-11-19

Applicant: BASF AG

Inventor： LOCH WERNER DIPL CHEM DR

IPC: C09D5/00 ,  C08L39/06 ,  C09D5/44 ,  C09D17/00 ,  C09D139/06 ,  C09B67/02 ,  C09D3/727 ,  C08J3/22

Abstract: Pigment pastes, comprising an organic solvent, a copolymer of one or more water-immiscible, or only partially water-miscible, copolymerizable alpha , beta -olefinically unsaturated compounds and one or more water-soluble copolymerizable N-vinyl compounds, and a finely divided pigment and/or filler dispersed in the mixture of solvent and copolymer, are used for pigmenting organic and/or aqueous solutions or dispersions of surface-coating binders, for toning pigmented gloss finishes, and for pigmenting and toning anodic or cathodic electrocoating finishes.

公开(公告)号：DE3022824A1

公开(公告)日：1982-01-07

申请号：DE3022824

申请日：1980-06-19

Applicant: BASF AG

Inventor： DERSCH ROLF DIPL CHEM DR ,  LOCH WERNER DIPL CHEM DR ,  NEUBERT GERHARD DIPL CHEM DR ,  WISTUBA ECKEHARDT DIPL CHEM DR

IPC: C08F8/00 ,  C08F8/44 ,  C08F212/00 ,  C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08F220/12 ,  C08F222/14 ,  C09D5/02 ,  C09D125/00 ,  C09D3/733

Abstract: 1. A copolymer which consists essentially of polymerized units of a) from 31 to 64% by weight of one or more vinyl-aromatics, b) from 24 to 65% by weight of one or more esters, free from unesterified carboxyl groups, of an alpha,beta-ethylenically unsaturated monocarboxylic acid or dicarboxylic acid, of 3 to 5 carbon atoms, with a branched or straight-chain monoalkanol of 1 to 14 carbon atoms, c) from 4 to 30% by weight of one or more carboxyl-containing alpha,beta-ethylenically unsaturated compounds of 3 to 14 carbon atoms, and d) from 0 to 5% by weight of other alpha,beta-ethylenically unsaturated compounds, not mentioned under a) to c) with the proviso that the sum of the percentages mentioned under a) to d) is 100, which copolymer has a K value, determined by the Fikentscher method, of from 18 to 60 and contains components (a), (b), (c) and (d) as polymerized units in such a ratio that the copolymer has an A value of from 180 to 220, which value can be calculated according to the following equation 100 . log SZ + 1,6 . see diagramm : EP0044399,P10,F3 where SZ is the acid number in mg of KOH/g of copolymer and see diagramm : EP0044399,P10,F4 is the sum of the corrected contents E1 -En , each in % by weight based on the copolymer, of COO groups in the particular alkyl (meth)acrylate comonomers b)1 - b)n, these contents in percent by weight being corrected by multiplying them by a factor of 0.7 for esters (b) of alpha-branched alkanols and by a factor of 0.8 for esters (b) of beta-branched alkanols.

公开(公告)号：DE3022870A1

公开(公告)日：1982-01-14

申请号：DE3022870

申请日：1980-06-19

Applicant: BASF AG

Inventor： LOCH WERNER DIPL CHEM DR ,  NEUBERT GERHARD DIPL CHEM DR ,  WISTUBA ECKEHARDT DIPL CHEM DR

IPC: C08F220/00 ,  C08F220/04 ,  C08F220/10 ,  C08F220/12 ,  C09D5/02 ,  C09D133/04 ,  C09D3/733 ,  D06M15/36

公开(公告)号：DE2853921A1

公开(公告)日：1980-07-03

申请号：DE2853921

申请日：1978-12-14

Applicant: BASF AG

Inventor： BUETHE INGOLF DIPL CHEM DR ,  LOCH WERNER DIPL CHEM DR

IPC: C08F290/14 ,  C08F299/04 ,  C09D5/02 ,  D04H1/00 ,  C08J3/06 ,  C08J3/28 ,  C08L67/06 ,  C08L71/02 ,  C08L63/10 ,  C08L75/06 ,  C08L33/06

Abstract: A radiation-curable aqueous binder dispersion which comprises water and, dispersed therein, one or more prepolymers which contain from 0.01 to 1.0 mole of polymerizable carbon-carbon double bonds per 100 g of prepolymer and have a mean molecular weight of not less than 350 and a viscosity at 23 DEG C. of not less than 600 cp, as well as from 0.1 to 30 percent by weight, based on prepolymer, of one or more dispersants and from 0 to 20 percent by weight, based on prepolymer, of one or more photoinitiators. The binder dispersions according to the invention may be used as surface coatings for non-metallic and metallic substrates, and for bonding fiber webs.

公开(公告)号：DE2833468A1

公开(公告)日：1980-02-07

申请号：DE2833468

申请日：1978-07-29

Applicant: BASF AG

Inventor： LOCH WERNER DIPL CHEM DR ,  DIEFENBACH HORST DIPL CHEM DR ,  UHL GUENTER ,  MARX MATTHIAS DIPL CHEM DR

IPC: C08F255/06 ,  C08F255/04

Abstract: Thickeners are prepd. by copolymerising monomer mixts. contg., by wt., (a) 20-70% (meth)acrylic acid and/or maleic-, fumaric- and/or itaconic acid mono-esters, (b) 30-80% (meth)acrylates and/or vinyl esters of 2-4C monocarboxylic acids, (c) 0-10% (meth)accrylonitrile and/or (meth)acrylamide, (d) 0-30% opt. substd. styrene and (e) 0-2% of >=1 monomer contg. >=2 ethylenically unsatd. double bonds, in an inert solvent, by pptn. polymerisation, using polymerisation initiators. Polymerisation is at 100-150(105-125) degrees C in the presence of 2-10wt.%, w.r.t. monomers, of a C2H4-C3H6 elastomer contg. 10wt.% inter-polymerised no(-conjugated diene. The elastomer has I2-index 1-15 and Mooney viscosity (100 degrees C, ML 1+4), 30-55. The thickeners can be used inthe prepn. of printing pastes, paper coating mixts. and aq. coating compsns. Elastomer presence prevents formation of highly crosslinked copolymers which do not dissolve in aq. alkali solns. In polymerisation, the elastomers act as protective colloids and are built into the copolymer.

公开(公告)号：DE3121765A1

公开(公告)日：1982-12-16

申请号：DE3121765

申请日：1981-06-02

Applicant: BASF AG

Inventor： LOCH WERNER DIPL CHEM DR

IPC: C09D5/00 ,  C08L39/06 ,  C09D5/02 ,  C09D5/44 ,  C09D11/00 ,  C09D11/10 ,  C09D17/00 ,  C09D139/06

Abstract: Pigment pastes, comprising water, an organic solvent, a copolymer of one or more water-immiscible, or only partially water-miscible, copolymerizable alpha , beta -olefinically unsaturated compounds and one or more water-soluble copolymerizable N-vinyl compounds, and a finely divided pigment and/or filler dispersed in the mixture of water, solvent and copolymer, are used for pigmenting aqueous solutions or dispersions of surface-coating binders, as toner pastes for water-based finishes, and for pigmenting and toning anodic or cathodic electrocoating finishes.

公开(公告)号：DE2829648A1

公开(公告)日：1980-01-24

申请号：DE2829648

申请日：1978-07-06

Applicant: BASF AG

Inventor： KOVACS JENOE DIPL CHEM DR ,  LOCH WERNER DIPL CHEM DR ,  HARTMANN HEINRICH DIPL CHEM DR ,  IMMEL GUENTHER DIPL CHEM DR

IPC: C08G18/80 ,  C09D175/04 ,  C09D3/72 ,  C09D5/08

公开(公告)号：DE2749691A1

公开(公告)日：1979-05-10

申请号：DE2749691

申请日：1977-11-07

Applicant: BASF AG

Inventor： BLUM RAINER ,  LOCH WERNER DIPL CHEM DR

IPC: C08F220/04 ,  C08F246/00 ,  C09D133/02 ,  C09D133/14 ,  C09D3/80

Abstract: Heat-hardening and self-crosslinking aq. coating compsns. contain 20-50wt.% polyacrylate dissolved or dispersed in water, with 20-100% of the free COOH gps. neutralised with amines or NH3 to improve solubility. The polyacrylate is a copolymer of (a) 21-35wt.% hydroxy 2-4C alkyl ester of an alpha, beta-unsatd. carboxylic acid, (b) 15-43% alpha, beta-unsatd. carboxylic acid, and (c) 22-64% monomer free from COOH and OH gps. The compsns. are used, with addn. of other usual additives, as stoving lacquers or metals. Addn. of (C) allows thicker coatings (60-90 mu m) to be applied with blow-holes being formed during stoving, and gives coatings with good gloss, hardness and elasticity.