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公开(公告)号:DE50111245D1
公开(公告)日:2006-11-30
申请号:DE50111245
申请日:2001-04-17
Applicant: BASF AG
Inventor: WALSDORFF CHRISTIAN DR , MEISSNER RUPRECHT , HARTH KLAUS DR
IPC: B01J21/04 , B01J23/78 , B01J23/83 , B01J27/122 , B01J32/00 , C07B61/00 , C07C17/02 , C07C17/15 , C07C17/156 , C07C19/045
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公开(公告)号:BG64695B1
公开(公告)日:2005-12-30
申请号:BG10454500
申请日:2000-06-19
Applicant: BASF AG
Inventor: HEINEKE DANIEL , MEISSNER RUPRECHT , HESSE MICHAEL , GEHRKEN HENNING-PETER
IPC: B01J23/72 , B01J31/06 , B01J37/02 , B01J37/03 , B01J37/04 , B01J37/08 , C07B35/04 , C07B61/00 , C07C45/00 , C07C45/29 , C07C49/403
Abstract: The invention relates to a method for producing oxidic catalysts containing copper with an oxidation number > 0 by treating a solid oxidic supporting material with an aqueous solution containing at least one copper salt and by means of a subsequent calcination. The invention is characterized in that the aqueous solution of the copper salt contains at least one organic, water soluble polymer, said polymer coordinately bonding copper ions, in concentration of 0.1 to 100 g/l. The invention also relates to the catalysts obtained by said method. In addition, the invention relates to a method for dehydrating secondary alcohols into ketones by utilizing the inventive catalysts, especially for dehydrating cycloxexanol.
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公开(公告)号:ES2237001T3
公开(公告)日:2005-07-16
申请号:ES99116658
申请日:1999-08-26
Applicant: BASF AG
Inventor: FLICK KLEMENS PROF DR , MEISSNER RUPRECHT , HEFNER WERNER DR , FESER RAINER DR , KUNZ FABIAN DR
IPC: B01J23/38 , B01J21/08 , B01J23/44 , B01J23/50 , B01J23/72 , B01J23/755 , B01J32/00 , B01J33/00 , B01J35/10 , C07B63/02 , C07C11/04 , C07C11/06 , C10G35/06 , C10G45/40 , C10G70/02
Abstract: Catalizador que contiene en su masa activa un 0, 05 a un 1, 0% en peso de al menos un metal o un compuesto de un metal del décimo grupo del Sistema Periódico de los Elementos, y un 0, 05 a un 1, 0% en peso de al menos un metal o un compuesto de un metal del grupo 11 del Sistema Periódico de los Elementos, ascendiendo la proporción ponderal del metal contenido del grupo 11 respecto al metal contenido del grupo 10 a un 0, 95 hasta un 1, 05, y como soporte un soporte de catalizador que contiene dióxido de silicio con una superficie BET entre 2 y 400 m2/g, y presentándose al menos un 20% del volumen de poros total del catalizador en poros con un diámetro por encima de 100 nanómetros.
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公开(公告)号:AU3597399A
公开(公告)日:1999-10-18
申请号:AU3597399
申请日:1999-03-19
Applicant: BASF AG
Inventor: HEBGEN WERNER , RIEKER CHRISTOPHER WILLIAM , MEISSNER RUPRECHT
IPC: B01J23/78 , B01J23/83 , B01J27/122 , B01J37/00 , C07B61/00 , C07C17/156 , C07C19/045
Abstract: A process for preparing 1,2-dichloroethane by reacting about 2 mols of ethylene, about 4 mols of hydrogen chloride and about 1 mol of oxygen in the presence of a fixed bed of supported catalyst based on copper(II) chloride in only one reaction zone at a pressure of from 2 to 10 bar and at from 220 to 280° C., separating off 1,2-dichloroethane and water from the reaction mixture emerging from the reaction zone and passing most of the exhaust gas back into the reaction zone, where, prior to entry into the reaction zone, the exhaust gas is mixed with ethylene, hydrogen chloride and oxygen, and the oxygen content of the mixture does not exceed 7% by volume, and where the ethylene content of the gas mixture entering into the reaction zone is regulated so that the exhaust gas comprises less than 20% by volume of ethylene, where the supported catalyst used is obtained by tableting a mixture of pseudoboehmite and gamma-Al2O3 in a weight ratio from 4:1 to 1:4, if desired with addition of tableting auxiliaries, loading this support with the active components by saturating with a CuCl2/KCl solution so that the copper content is from 1 to 15% by weight and the potassium content is from 0.1 to 8% by weight, based in each case on the total weight of the catalyst, and then drying the catalyst at from 60 to 400° C.
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公开(公告)号:DE3469850D1
公开(公告)日:1988-04-21
申请号:DE3469850
申请日:1984-06-25
Applicant: BASF AG
Inventor: MEISSNER RUPRECHT , NETH NORBERT DR
IPC: B01J23/22 , B01J27/055 , C01B17/79
Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.
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公开(公告)号:DE3322940A1
公开(公告)日:1985-01-03
申请号:DE3322940
申请日:1983-06-25
Applicant: BASF AG
Inventor: MEISSNER RUPRECHT , NETH NORBERT DR
IPC: B01J23/22 , B01J27/055 , C01B17/79
Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.
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公开(公告)号:DK306084A
公开(公告)日:1984-12-26
申请号:DK306084
申请日:1984-06-22
Applicant: BASF AG
Inventor: MEISSNER RUPRECHT , NETH NORBERT
IPC: B01J23/22 , B01J27/055 , C01B17/79 , B01J , C01B
Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.
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公开(公告)号:FI842546A0
公开(公告)日:1984-06-25
申请号:FI842546
申请日:1984-06-25
Applicant: BASF AG
Inventor: MEISSNER RUPRECHT , NETH NORBERT
IPC: B01J23/22 , B01J27/055 , C01B17/79 , B01J
Abstract: Catalysts for the oxidation of sulfur dioxide to sulfur trioxide, consisting of a silica-based carrier and, applied on this, an active substance containing vanadium and alkali metal compounds, are prepared by dissolving vanadium pentoxide in an alkali solution, acidifying the solution with sulfuric acid, mixing the acidified solution with the carrier, molding the mixture and drying and calcining the molding. To obtain mechanically stable catalysts, a dissolved alkali metal silicate and/or silica sol are added to the alkaline solution before acidification, the latter process is carried out at below 35 DEG C. and the solution is then immediately incorporated into the carrier. The resulting moist crumbly material contains from 2 to 6% by weight of V2O5, from 35 to 45% by weight of H2O and from 15 to 50% by weight of SiO2. From 5 to 25% by weight of the total silica content originates from the dissolved alkali metal silicate and/or silica sol.
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公开(公告)号:AU2003206831A8
公开(公告)日:2003-09-02
申请号:AU2003206831
申请日:2003-02-04
Applicant: BASF AG
Inventor: KUHRS CHRISTIAN , MEISSNER RUPRECHT
IPC: B01J21/04 , B01J23/89 , B01J27/122 , B01J27/138 , B01J35/02 , B01J35/10 , B01J37/02 , C07B61/00 , C07C17/156 , C07C19/045 , B01J27/128 , B01J27/051
Abstract: A supported catalyst composition for the oxychlorination of ethylene comprises 3-12 wt.% copper as copper salt and 0.001-0.1 (0.005-0.05) wt.% of ruthenium, rhodium, palladium, osmium, iridium and/or platinum and/or 0.0001-0.1 (0.001-0.05) wt.% gold as the corresponding metal salt of tetrachloroauric acid. A catalyst composition (I) for the oxychlorination of ethylene comprises a mixture of metal salts on a support and consists of (wt. % with respect to total weight of the catalyst including support): (A) copper as copper salt (3-12); (B) an alkaline earth metal as a salt (0-3); (C) an alkali metal as a salt (0-3); and (D) ruthenium, rhodium, palladium, osmium, iridium and/or platinum (0.005-0.05) and/or gold as the corresponding metal salt of tetrachloroauric acid (0.001-0.05). An independent claim is also included for a process for the production of 1,2-dichloroethane by oxychlorination of ethylene using the catalyst composition (I).
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公开(公告)号:AT232897T
公开(公告)日:2003-03-15
申请号:AT98916941
申请日:1998-03-13
Applicant: BASF AG
Inventor: FLICK KLEMENS , MEISSNER RUPRECHT , ARTRIP DAVID J , KUNZ FABIAN , HEFNER WERNER , FESER RAINER
Abstract: Alkines, dienes, and/or singly unsaturated hydrocarbons; compounds containing sulphur, arsenic and/or antimony; oxygen, hydrogen and/or carbon monoxide are removed from material flows in a total of at most three process steps. In a first process step, after hydrogen has been added to the feed material flow at a hydrogenation catalyst which is largely resistant to compounds containing sulphur, arsenic and/or antimony, alkines, dienes and/or singly unsaturated hydrocarbons are removed by hydrogenation, oxygen which may optionally be present also being at least partially removed by hydrogenation. In a second process step, compounds containing sulphur, arsenic and/or antimony and/or residual oxygen from the first process step are removed by absorption on a contact mass, and/or residual oxygen, carbon monoxide and/or residual hydrogen are at least partially converted catalytically into water and carbon dioxide. Optionally, in a third process step, residual carbon monoxide and/or residual hydrogen from the preceding process steps is/are converted on a contact mass into carbon dioxide and/or water.
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