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公开(公告)号:BR9711230A
公开(公告)日:1999-08-17
申请号:BR9711230
申请日:1997-08-26
Applicant: BASF AG
Inventor: HERRMANN CHRISTOF , HUEBINGER WOLFGANG , KREMESKOETTER JENS , MINGES ROLAND , SCHMIDT-THUMMES JURGEN , MORITZ HANS-ULRICH , SCHMIDT WOLFGANG , RIDDER MAREN
Abstract: A curved tubular flow reactor designed for carrying out chemical reactions continuously, for preparing mixtures and as a liquid-phase heat exchanger comprises a plurality of successive bends having alternating directions of curvature.
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公开(公告)号:CA2089204C
公开(公告)日:1998-05-12
申请号:CA2089204
申请日:1993-02-10
Applicant: BASF AG
Inventor: SCHERZER DIETRICH , LUGMAYR MICHAEL , BRUCHMANN BERND , ZSCHIESCHE RUTH , SPANG CLAUDIA , LUTTER HEINZ-DIETER , MINGES ROLAND
IPC: C08G18/10 , C08G18/12 , C08G18/40 , C08G18/48 , C08G18/65 , C08G18/72 , C08G18/76 , C08G101/00 , C08J9/02 , C08J9/04 , C08L75/08 , C08G18/66
Abstract: The invention relates to a process for the preparation of CFC-free, flexible polyurethane foams or molded foams by reacting A) liquid polyisocyanate mixtures containing bonded urethane groups and having a content of NCO groups of from 20 to 30% by weight, these mixtures themselves being prepared by reacting a mixture of diphenylmethane diisocyantes and polyphenyl-poly-methylene polyisocyanates (crude diphenylmethane diisocyanate) with a polyether-polyol mixture, having a hydroxyl number of from 120 to 25, of at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene-polyoxyethylene glycol having a content of ethylene oxide units of from 90 to 10% by weight or by reacting 4,4'-diphenylmethane diisocyanate (diphenylmethyl diisocyanate) or an diphenylmethane diisocyanate isomer mixture with said polyether-polyol mixture to give an NCO-containing quasi-prepolymer and diluting this quasi-prepolymer with crude diphenylmethane diisocyanate, with B) relatively high-molecular-weight polyhydroxyl compound, and, if desired, C) low-molecular-weight chain extenders and/or cross-linking agents, in the presence of D) blowing agents, E) catalysts and, if desired, F) assistants and/or additives, and to the polyisocyanate mixtures (A) which have been modified by means of urethane groups and can be used according to the invention.
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公开(公告)号:AU4207597A
公开(公告)日:1998-03-19
申请号:AU4207597
申请日:1997-08-26
Applicant: BASF AG
Inventor: HERRMANN CHRISTOF , HUBINGER WOLFGANG , KREMESKOTTER JENS , MINGES ROLAND , SCHMIDT-THUMMES JURGEN , MORITZ HANS-ULRICH , SCHMIDT WOLFGANG , RIDDER MAREN
Abstract: A curved tubular flow reactor designed for carrying out chemical reactions continuously, for preparing mixtures and as a liquid-phase heat exchanger comprises a plurality of successive bends having alternating directions of curvature.
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公开(公告)号:CA2089204A1
公开(公告)日:1993-08-12
申请号:CA2089204
申请日:1993-02-10
Applicant: LUTTER HEINZ DIETER , BRUCHMANN BERND , SPANG CLAUDIA , MINGES ROLAND , SCHERZER DIETRICH , LUGMAYR MICHAEL , ZSCHIESCHE RUTH , BASF AG
Inventor: LUTTER HEINZ-DIETER , BRUCHMANN BERND , SPANG CLAUDIA , MINGES ROLAND , SCHERZER DIETRICH , LUGMAYR MICHAEL , ZSCHIESCHE RUTH
IPC: C08G18/10 , C08G18/12 , C08G18/40 , C08G18/48 , C08G18/65 , C08G18/72 , C08G18/76 , C08G101/00 , C08J9/02 , C08G18/79 , C08G18/66 , C08L75/08 , C08J9/04
Abstract: The invention relates to a process for the preparation of CFC-free flexible polyurethane(moulded) foams by reacting A) liquid polyisocyanate mixtures containing bonded urethane groups and containing from 20 to 30% by weight of NCO groups, themselves prepared by reacting a mixture of diphenylmethane diisocyanates and polyphenyl polymethylene polyisocyanates (crude MDI) with a polyether-polyol mixture having a hydroxyl number of from 120 to 25 comprising at least one polyoxypropylene glycol and at least one trifunctional polyoxypropylene polyoxyethylene polyol containing from 90 to 10% by weight of ethylene oxide units or by reacting 4,4'-diphenylmethane diisocyanate (MDI) or an MDI isomer mixture with said polyether polyol mixture to give an NCO-containing quasi-prepolymer, and diluting this quasi-prepolymer with crude MDI, with B) relatively high-molecular-weight polyhydroxyl compounds and optionally C) low-molecular-weight chain extenders and/or crosslinking agents, in the presence of D) blowing agents E) catalysts and optionally F) auxiliaries and/or additives, and to the urethane group-modified polyisocyanate mixtures (A) which can be used according to the invention.
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