公开(公告)号：DE3528313A1

公开(公告)日：1987-02-12

申请号：DE3528313

申请日：1985-08-07

Applicant: BASF AG

Inventor： BOEHNING KARL-HEINZ DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR ,  BECKER HANS-JUERGEN DR ,  PLUECKHAN JUERGEN DR ,  RENNER KLAUS-CHRISTIAN DR

IPC: B01J23/66 ,  B01J35/10 ,  C07D301/10 ,  B01J23/50

公开(公告)号：DE3368920D1

公开(公告)日：1987-02-12

申请号：DE3368920

申请日：1983-03-18

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/04 ,  B01J29/86 ,  C07C1/20 ,  C07C11/02

Abstract: Olefins are prepared by converting methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures by a process wherein the catalyst used is a borosilicate zeolite which has been molded together with an amorphous binder containing aluminum oxide and silicon dioxide. The advantage of using the borosilicate catalyst is that the yield of C2-C4-olefins is improved at the expense of formation of higher hydrocarbons.

公开(公告)号：AT23327T

公开(公告)日：1986-11-15

申请号：AT84108454

申请日：1984-07-18

Applicant: BASF AG

Inventor： TAGLIEBER VOLKER DR ,  HOELDERICH WOLFGANG DR ,  KUMMER RUDOLF DR ,  MROSS WOLF DIETER DR ,  SALADIN GUENTER

IPC: C07B61/00 ,  B01J21/00 ,  B01J29/04 ,  B01J29/86 ,  C07C67/00 ,  C07C209/00 ,  C07C209/60 ,  C07C211/02 ,  C07C85/18 ,  C07C87/06

公开(公告)号：DE3361378D1

公开(公告)日：1986-01-16

申请号：DE3361378

申请日：1983-03-18

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  HIMMEL WALTER DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/04 ,  B01J29/86 ,  C07C1/20 ,  C07C11/02

Abstract: Olefins are prepared by converting methanol and/or dimethyl ether in the presence of a zeolite catalyst at elevated temperatures by a process wherein the catalyst used is a borosilicate zeolite which has been molded together with an amorphous binder containing aluminum oxide and silicon dioxide. The advantage of using the borosilicate catalyst is that the yield of C2-C4-olefins is improved at the expense of formation of higher hydrocarbons.

公开(公告)号：DE3407289A1

公开(公告)日：1985-09-05

申请号：DE3407289

申请日：1984-02-29

Applicant: BASF AG

Inventor： BIFFAR WERNER DR ,  KRATTE KLAUS DR ,  LEHNERT RUDI DR ,  MROSS WOLF DIETER DR ,  STARKE KLAUS ,  SCHWARZMANN MATTHIAS DR

IPC: B01D53/94 ,  F02B1/04 ,  B01D53/36 ,  F01N3/20

Abstract: The application relates to a process for the catalytic purification of nitrogen oxide-containing exhaust gases from internal combustion engines, in which ammonia is added to the exhaust gases and the gas mixture is passed over a non-noble metal catalyst which may, if appropriate, be applied to a support.

公开(公告)号：DE3263412D1

公开(公告)日：1985-06-05

申请号：DE3263412

申请日：1982-09-09

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: C07C1/20 ,  C07C11/02

Abstract: A process for the preparation of olefins from methanol and/or dimethyl ether by conversion in the presence of a zeolite catalyst, in particular a borosilicate zeolite, at elevated temperature, with the addition of a small amount of an electron donor.

公开(公告)号：DE3261547D1

公开(公告)日：1985-01-24

申请号：DE3261547

申请日：1982-07-16

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/90 ,  B01J37/26 ,  C07C1/20 ,  C07C11/02 ,  B01J29/38

Abstract: The process for the preparation of olefins by converting methanol and/or dimethyl ether in the presence of a zeolite catalyst is improved by treating the catalyst with hydrogen fluoride. Aluminosilicate zeolites and borosilicate zeolites, especially those of the pentasil type, are chiefly used.

公开(公告)号：DE3164202D1

公开(公告)日：1984-07-19

申请号：DE3164202

申请日：1981-10-05

Applicant: BASF AG

Inventor： HOELDERICH WOLFGANG DR ,  MAROSI LASZLO DR ,  MROSS WOLF DIETER DR ,  SCHWARZMANN MATTHIAS DR

IPC: B01J29/40 ,  C01B39/02 ,  C01B39/36 ,  C07C1/20 ,  C07C2/66 ,  C07C15/00 ,  C10G3/00 ,  C01B33/28 ,  B01J29/28

公开(公告)号：DE2641000A1

公开(公告)日：1978-03-16

申请号：DE2641000

申请日：1976-09-11

Applicant: BASF AG

Inventor： MROSS WOLF DIETER DR ,  TITZENTHALER ECKART DR ,  SCHARZMANN MATTHIAS DR ,  KOOPMANN JUERGEN DR

IPC: B01J23/66 ,  C07D301/10 ,  C07D303/02

Abstract: Catalysts for ethylene oxide prepn. from ethylene and O2 comprise Ag and alkali metals or their cpds. deposited on a support. The catalysts contain (a) 0.1-2 atom % Na and (b) either 0.05-0.35 atom % K, 0.003-0.25 atom % Rb, 0.0005-0.2 atom % Cs or a corresp. amt. of a mixt. thereof. All percentages are based on the Ag content. The Ag content is pref. 2-12 (esp. 5-10) wt.% based on the wt. of the catalyst. The catalysts are pref. prepd. by impregnating the support with an aq. soln. of an Ag complex salt (e.g. an Ag-amine carboxylate) and suitable alkali metal cpds. (e.g. hydroxides), steaming the resulting composite until the Ag cpd. decomposes, and calcining the product at 100-400 degrees C to constant wt. Other standard methods can also be used. The catalysts have higher activity and selectivity than conventional Ag catalysts promoted with alkali(ne earth) metals, and/or have a longer life.

公开(公告)号：DE2622228A1

公开(公告)日：1977-12-08

申请号：DE2622228

申请日：1976-05-19

Applicant: BASF AG

Inventor： MROSS WOLF DIETER DR ,  TITZENTHALER ECKART DR ,  SCHWARZMANN MATTHIAS DR ,  KOOPMANN JUERGEN DR

IPC: B01J23/66 ,  C07D301/10

Abstract: Catalysts for ethylene oxide prepn. from ethylene and O2 comprise Ag and alkali metals or their cpds. deposited on a support. The catalysts contain (a) 0.1-2 atom % Na and (b) either 0.05-0.35 atom % K, 0.003-0.25 atom % Rb, 0.0005-0.2 atom % Cs or a corresp. amt. of a mixt. thereof. All percentages are based on the Ag content. The Ag content is pref. 2-12 (esp. 5-10) wt.% based on the wt. of the catalyst. The catalysts are pref. prepd. by impregnating the support with an aq. soln. of an Ag complex salt (e.g. an Ag-amine carboxylate) and suitable alkali metal cpds. (e.g. hydroxides), steaming the resulting composite until the Ag cpd. decomposes, and calcining the product at 100-400 degrees C to constant wt. Other standard methods can also be used. The catalysts have higher activity and selectivity than conventional Ag catalysts promoted with alkali(ne earth) metals, and/or have a longer life.