公开(公告)号：DE19622332A1

公开(公告)日：1997-12-11

申请号：DE19622332

申请日：1996-06-04

Applicant: BASF AG

Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  BAYER HERBERT DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: C07C251/60 ,  A01N37/18 ,  A01N37/40 ,  C07C57/58

Abstract: 2-Iminooxyphenylacetic acid derivatives of formula (I) and their salts are new. R = C(CO2Me)=NOMe, C(CONHMe)=NOMe, C(CONH2)=NOMe, C(CO2Me)=COMe or C(CO2Me)=CHMe; R2 = CN, NO2, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; m = 0-2; R3 = H, CN, OH, halo, 1-6C alkyl (optionally substituted by halo or 1-6C alkoxy) 1-6C alkoxy, 1-6C haloalkoxy, 1-6C alkylthio, cyclopropyl, 2-6C alkenyl, or aryloxy-1-6C alkyl, benzyl or benzyloxy (all optionally ring-substituted by 1-3 CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy) or C(Me)=N-Y-Ra; Ra = 1-6C alkyl; Y = O, NH or NRa; R4 = H, CN, -Qp-C(R5)=N-Y'-R6 or -Q-O-N=CR7R8; or alkyl, alkenyl, alkynyl, cycloalkyl, heterocyclyl, aryl, heteroaryl, alkoxy, alkenyloxy, alkynyloxy, cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio (all optionally substituted); or CR3R4 = 4-8 membered ring containing C atoms an optionally 1 or 2 of O, S, NH and/or N(1-4C alkyl) (optionally substituted on C by halo, 1-6C alkyl or 1-4C alkoxyimino), provided R3 and R4 are not both bonded to C via hetero atoms; Q = bond, CH2, CH(Me), CH(Et) or 1,1-cyclopropyl; p = 0 or 1; Y' = O, NH or N(1-4C alkyl); R5 = as for R3 or optionally substituted cycloalkoxy, heterocyclyloxy, aryloxy, heteroaryloxy, arylthio or heteroarylthio; R6 = optionally substituted 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, 1-10C alkylcarbonyl, 2-10C alkenylcarbonyl, 2-10C alkynylcarbonyl, 1-10C alkylsulphonyl, aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl; R7, R8 = Me, Et, Ar or CH2Ar; Ar = phenyl (optionally mono-, di- or trisubstituted by CN, NO2, halo, 1-6C alkyl, 1-6C alkoxy, 1-6C haloalkyl or 1-6C haloalkoxy.

公开(公告)号：DE19548370A1

公开(公告)日：1997-07-03

申请号：DE19548370

申请日：1995-12-27

Applicant: BASF AG

Inventor： GROTE THOMAS DR ,  SAUTER HUBERT DR ,  KIRSTGEN REINHARD DR ,  BAYER HERBERT DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N37/38 ,  A01N37/50 ,  C07C251/60 ,  C07C251/56 ,  A01N35/10 ,  A01N37/10 ,  A01N37/34 ,  A01N41/04 ,  A01N43/78 ,  C07C249/12 ,  C07C249/14 ,  C07C251/58 ,  C07C255/61 ,  C07C257/06

Abstract: 2-(2-(Iminooxy)-phenyl)-2-(methoxyimino, methoxymethylene or ethylidene)-acetic acid amide or methyl ester derivatives of formula (I) and their salts are new. R = (a) -C(=NOMe)-COOMe, (b) -C(=NOMe)-CONHMe, (c) -C(=NOMe)-CONH2, (d) -C(=CHOMe)-COOMe or (e) -C(=CHMe)-COOMe; R = CN, NO2, CF3, halogen, 1-4C alkyl or 1-4C alkoxy; m = 0-2; R = H, OH, cyclopropyl, halogen, 1-4C alkyl, CN, 1-4C alkoxy or 1-4C alkylthio; R = 1-8C alkyl, 2-8C alkenyl, 2-8C alkynyl, 3-8C cycloalkyl, aryl or heteroaryl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl and heteroaryloxy); or R -Y-N=C(R )-; R = (i) H; (ii) 1-10C alkyl, 3-6C cycloalkyl, 2-10C alkenyl, 3-10C alkynyl, (1-10C) alkylcarbonyl, (2-10C) alkenylcarbonyl, (3-10C) alkynylcarbonyl or (1-10C) alkylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy and heteroarylthio (where aromatic or heteroaromatic moieties are themselves optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and -C(=NOR )-An-R )); or (iii) aryl, heteroaryl, arylcarbonyl, heteroarylcarbonyl, arylsulphonyl or heteroarylsulphonyl (all optionally partially or completely halogenated or substituted by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halogen, alkyl, haloalkyl, alkylcarbonyl, alkylsulphonyl, alkylsulphoxyl, 3-6C cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, heteroaryl, heteroaryloxy and -C(=NOR )-An-R ); A = O, S, NH or N(alkyl); n = 0 or 1; R ,R = H or alkyl; R = H, OH, halogen or as R ; Y = O or NR ; R = H or alkyl; unless specified otherwise alkyl moieties have 1-6C and alkenyl moieties 2-6C. Intermediates of formulae (IV) and (IIA) are also new. R = 1-8C alkyl; X = F or other nucleofugeous leaving group.

公开(公告)号：DE19545094A1

公开(公告)日：1997-06-05

申请号：DE19545094

申请日：1995-12-04

Applicant: BASF AG

Inventor： MUELLER RUTH DR ,  BAYER HERBERT DR ,  KIRSTGEN REINHARD DR ,  SAUTER HUBERT DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  MUELLER BERND DR ,  GROTE THOMAS DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  ROEHL FRANZ DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  STRATHMANN SIEGFRIED DR

IPC: A01N43/36 ,  A01N43/56 ,  A01N43/76 ,  A01N43/78 ,  C07D207/33 ,  C07D231/12 ,  C07D263/30 ,  C07D277/22 ,  C07D277/28 ,  C07D521/00 ,  A01N37/50 ,  A01N43/00 ,  C07D227/04 ,  C07D247/00 ,  C07D255/02 ,  C07D261/08 ,  C07D263/32 ,  C07D271/02 ,  C07D307/36 ,  C07D333/06

Abstract: The invention relates to phenylacetic acid derivatives of the formula (I), in which the substituents and the index have the following meaning: X is NOCH3, CHOCH3, CHCH3 and CHCH2CH3; Y is NR and O; R , R are hydrogen and alkyl; R is cyano, nitro, halogen, alkyl, alkyl halide and alkoxy; m is 0, 1 or 2; R is hydrogen, hydroxy, amino, cyano, halogen, alkyl, alkyl halide, cycloalkyl, alkoxy, alkylthio, alkylamino and dialkylamino; A is a 5 or 6 membered hetero-aromatic ring; R is a substituted aryl; R is hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl and hetaryl. The invention also relates to the salts of said derivatives, a process and intermediates for the preparation and use thereof.

公开(公告)号：DE19541382A1

公开(公告)日：1997-05-15

申请号：DE19541382

申请日：1995-11-07

Applicant: BASF AG

Inventor： MUELLER RUTH DR ,  BAYER HERBERT DR ,  GROTE THOMAS DR ,  SAUTER HUBERT DR ,  MUELLER BERND DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: A01N37/36 ,  A01N37/50 ,  A01N43/56 ,  A01N47/12 ,  A01N47/48 ,  C07C251/40 ,  C07C251/60 ,  C07C255/64 ,  C07C331/12 ,  C07C333/04 ,  C07D231/26 ,  A01N37/10 ,  A01N43/00 ,  C07C249/04 ,  C07C255/63 ,  C07C317/26 ,  C07C323/47 ,  C07C327/16

Abstract: alpha -(Methoximino, methoxymethylene or ethylidene)-2-(oximinoalkylideneaminooxymethyl)-phenylacetic acid derivs. of formula (I) and their salts are new. X = NOMe, CHOMe or CHMe; Y = NR or O; R, R1 = H or 1-4C alkyl; R2 = H, alkyl, 1-4C haloalkyl or cycloalkyl; R3 = (i) 4-6C cycloalkyl; (ii) 2-6C alkyl; or (iii) alkyl, alkynyl or alkenyl, (all partially or completely halogenated and/or substd. by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, halo, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkylsulphonyl, alkylsulphoxyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, alkenyloxy, cycloalkyl, cycloalkoxy, heterocyclyl, heterocyclyloxy, aryl, aryloxy, aryl(1-4C)alkoxy, arylthio, aryl(1-4C)alkylthio, heteroaryl, heteroaryloxy, heteroaryl(1-4C)alkoxy, heteroarylthio and heteroaryl(1-4C)alkylthio (where the cyclic gps. are themselves opt. partially or completely halogenated and/or substd. by 1-3 of CN, NO2, OH, SH, NH2, COOH, CONH2, CSNH2, alkyl, haloalkyl, alkylsulphonyl, alkylsulphoxyl, cycloalkyl, alkoxy, haloalkoxy, alkoxycarbonyl, alkylthio, mono- or dialkylamino, mono- or dialkylaminocarbonyl, mono- or dialkylaminothiocarbonyl, alkenyl, alkenyloxy, benzyl, benzyloxy, aryl, aryloxy, arylthio, heteroaryl, heteroaryloxy, heteroarylthio and C(=NORa)-An-Rb)); R4 = (i) H; (ii) 1-10C alkyl, cycloalkyl, 2-10C alkenyl, 2-10C alkynyl, (1-10C)alkylcarbonyl, (2-10C)alkenylcarbonyl, 3-10C alkynylcarbonyl or 1-10C alkylsulphonyl, all opt. halogenated and/or substd. as for alkyl in R3, or (iii) aryl, arylcarbonyl, arylsulphonyl, heteroaryl, heteroarylcarbonyl or heteroarylsulphonyl (all opt. halogenated and/or substd. as for the cyclic gps. in R3); A = O, S , NH or N(alkyl); n = 0 or 1; Ra, Rb = H or alkyl; alkyl and alkoxy have 1-6C, alkenyl and alkynyl 2-6C and cycloalkyl has 3-6C unless specified otherwise; excluded are cpds. where (a) R1, R2 = Me, R3 = Et, R4 = Me or Et, X = NOMe and Y = NH or O; or (b) R3 = t-Bu.

公开(公告)号：DE19540361A1

公开(公告)日：1997-05-07

申请号：DE19540361

申请日：1995-10-30

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR ,  GOETZ NORBERT DR ,  HARREUS ALBRECHT DR

IPC: C07D521/00 ,  A01N35/10 ,  A01N37/36 ,  A01N37/50 ,  A01N43/08 ,  A01N43/10 ,  A01N43/36 ,  A01N43/40 ,  A01N43/50 ,  A01N43/54 ,  A01N43/56 ,  A01N43/58 ,  A01N43/60 ,  A01N43/64 ,  A01N43/76 ,  A01N43/78 ,  A01N43/80 ,  A01N47/20 ,  C07C49/76 ,  C07C251/40 ,  C07C251/48 ,  C07C251/60 ,  C07C255/17 ,  C07C271/28 ,  C07C249/04 ,  C07C49/213 ,  A01N37/10

Abstract: The invention concerns phenylacetic acid derivatives of formula (I), in which the variables have the following meanings: X = NOCH3, CHOCH3 or CHCH3; Y = O or NZ, Z standing for hydrogen or alkyl; R = H or alkyl; R = cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy; m = 0, 1 or 2, wherein the group R can be different when m = 2; R = H, cyano, alkyl, alkyl halide, alkoxy or cyclopropyl; R = alkylenedioxy, the alkylene groups being partially or completely halogenated, or one of the groups: -(C=O)-R , -C(=NOR )-Ap-R , -NR -(C=O)-Ap-R , -O-(C=O)-NR R or -N(R )-OR , R , R , independently of each other, being H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl or heteroaryl; R , R , independently of each other, being H or optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkoxycarbonyl, alkenyloxycarbonyl, alkinyloxycarbonyl, cycloalkyl, cycloalkylcarbonyl, cycloalkyloxycarbonyl, arylcarbonyl or heteroarylcarbonyl; p = 0 or 1; A = O, S or N, the N-atom carrying H or alkyl; n = 1 or 2, wherein the group R can be different when n = 2; and R = H, alkylsulphonyl or optionally substituted alkyl, alkenyl, alkinyl or cycloalkyl. The invention further concerns salts of these substances, a process and intermediate products for their preparation, and their use as fungicides and pesticides.

公开(公告)号：DE19537750A1

公开(公告)日：1997-04-17

申请号：DE19537750

申请日：1995-10-10

Applicant: BASF AG

Inventor： BAYER HERBERT DR ,  SAUTER HUBERT DR ,  OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER BERND DR ,  MUELLER RUTH DR ,  ROEHL FRANZ DR ,  AMMERMANN EBERHARD DR ,  HARRIES VOLKER DR ,  LORENZ GISELA DR ,  STRATHMANN SIEGFRIED DR ,  GOETZ NORBERT DR

IPC: C07D233/64 ,  A01N37/52 ,  C07C259/12 ,  C07C259/14 ,  C07C327/56 ,  C07D207/335 ,  C07D207/34 ,  C07D213/61 ,  C07D213/64 ,  C07D213/65 ,  C07D213/74 ,  C07D213/84 ,  C07D213/85 ,  C07D231/20 ,  C07D231/38 ,  C07D261/08 ,  C07D263/32 ,  C07D263/34 ,  C07D271/06 ,  C07D271/10 ,  C07D275/02 ,  C07D275/04 ,  C07D277/20 ,  C07D277/28 ,  C07D277/32 ,  C07D277/42 ,  C07D277/82 ,  C07D285/08 ,  C07D285/12 ,  C07D307/52 ,  C07D307/56 ,  C07D307/68 ,  C07D317/54 ,  C07D317/62 ,  C07D317/66 ,  C07D333/20 ,  C07D333/24 ,  C07D333/28 ,  C07D333/58 ,  C07D521/00 ,  C07D227/02 ,  C07C251/60 ,  C07C251/50 ,  C07C255/17 ,  C07C327/38 ,  C07D247/00 ,  C07D315/00 ,  C07D255/00 ,  C07D257/00 ,  C07D269/00 ,  A01N43/00

Abstract: The disclosure concerns oxyamino oxime ethers of formula (I), wherein: X is NOCH3, CHOCH3, CHCH3; Y is O or NZ, Z being H or alkyl; R is H or alkyl; R is cyano, nitro, trifluoromethyl, halogen, alkyl or alkoxy, m = 0, 1 or 2 and the groups R can be different if m = 2; R is H, alkyl, alkyl halide or cycloalkyl; R is H or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, heterocyclyl, aryl, heteroaryl; R is H or alkylsulphonyl, or optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl; and their salts. Also disclosed are methods and intermediate products for use in producing them and their use for controlling harmful fungi and insect pests.

公开(公告)号：DE19605903A1

公开(公告)日：1997-08-21

申请号：DE19605903

申请日：1996-02-17

Applicant: BASF AG

Inventor： OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  SAUTER HUBERT DR ,  GROTE THOMAS DR ,  MUELLER BERND DR ,  KIRSTGEN REINHARD DR ,  MUELLER RUTH DR ,  BAYER HERBERT DR ,  PTOCK ARNE DR ,  RACK MICHAEL DR ,  HARREUS ALBRECHT DR ,  ROEHL FRANZ DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: A01N43/40 ,  C07D213/64 ,  C07D213/643 ,  C07D401/12 ,  C07D405/12 ,  C07D409/12 ,  C07D413/12 ,  C07D417/12 ,  C07D213/61 ,  A01N43/54 ,  A01N43/66

Abstract: The invention concerns pyridyl-phenyl- and benzylethers of formula (I), and their salts and N-oxides, in which the substituents and indices have the following meanings: Q is C(CO2CH3)=CHCH3, C(CO2CH3)=CHOCH3, C(CONH2)=NOCH3, C(CO2CH3)=NOCH3, C(CONHCH3)=NOCH3 or N(OCH3)-CO2CH3; n is 0 or 1; R is hydrogen or an organic group bonded via a carbon atom; R is hydrogen, cyano, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; R is hydrogen, halogen, C1-C4 alkyl or C1-C2 alkyl halide; x is 0, 1 or 2; R is cyano, nitro, halogen or an organic group bonded via a carbon, oxygen, sulphur or nitrogen atom; y is 0, 1, 2 or 3; and R is cyano, halogen, C1-C4 alkyl, C1-C4 alkyl halide or C1-C4 alkoxy. The invention further concerns a process and intermediate products for preparing these substances and their use.

公开(公告)号：DE19546699A1

公开(公告)日：1997-06-19

申请号：DE19546699

申请日：1995-12-14

Applicant: BASF AG

Inventor： OBERDORF KLAUS DR ,  GRAMMENOS WASSILIOS DR ,  SAUTER HUBERT DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  MUELLER RUTH DR ,  MUELLER BERND DR ,  ROEHL FRANZ DR ,  RACK MICHAEL DR ,  BAYER HERBERT DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: A01N43/54 ,  C07D239/34 ,  A01N37/52

Abstract: 2-(pyrimidin-4-yloxy)methyl)phenylacetic acid derivatives of formula (I) and their salts and N-oxides are new. R1 = H or 1-4C alkyl; R2 = halo, CH3, CH2CH3, halomethyl or haloethyl; R3 = phenyl, phenoxy, phenoxymethyl, benzyloxy or heteroaryl, (all optionally ring-substituted), H, amino, OH, SH, halo, 1-8C alkyl (optionally substituted by Ar or halo), alkoxy-(1-4C alkyl), alkoxy, mono- or di- alkylamino, alkylthio, alkylsulphoxy, alkylsulphonyl, 3-8C cycloalkyl, trialkylsilyloxy; Ar = phenyl (optionally mono- or di-substituted by halo, CN, NO2, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy); R4 = H, CN, halo, 1-4C alkyl, 1-4C haloalkyl or 1-4C alkoxy; Q = C(=NOCH3)CONHCH3, C(=NOCH3)COOCH3 or N(OCH3)COOCH3; alkyl, alkoxy have 1-8 C unless specified otherwise.

公开(公告)号：DE19545878A1

公开(公告)日：1997-06-12

申请号：DE19545878

申请日：1995-12-08

Applicant: BASF AG

Inventor： MUELLER BERND DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  OBERDORF KLAUS DR ,  ROEHL FRANZ DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  MUELLER RUTH DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR ,  PTOCK ARNE DR

IPC: C07D213/75 ,  A01N47/18 ,  C07D213/74 ,  C07D213/76 ,  C07D213/79 ,  C07D213/81 ,  C07D401/12 ,  C07D401/14 ,  C07D405/12 ,  C07D405/14 ,  C07D409/12 ,  C07D409/14 ,  C07D413/12 ,  C07D413/14 ,  C07D417/12 ,  C07D417/14 ,  C07D215/38 ,  C07D471/04 ,  C07D491/04 ,  C07D495/04 ,  A01N43/40

Abstract: The invention relates to pyridyl carbamates of formula (I), in which the index and the substituents have the follwing meaning: R' is hydrogen, optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, alkyl carbonyl and alkoxy carbonyl; R" is optionally substituted alkyl, alkenyl, alkinyl, cycloalkyl, cycloalkenyl, or where V is an amino group, also hydrogen; V is oxygen (-O-), sulphur (-S-) or an amino group which can carry one of the following radicals: alkyl, alkenyl, alkinyl or cycloalkyl; X is cyano, nitro, halogen, optionally substituted alkyl, alkenyl, alkinyl, alkoxy, alkenyloxy, alkinyloxy, or where n > 1, an optionally substituted bridge bound to two adjacent C-atoms of the pyridyl ring and containing 3 to 4 members from the group of 3 or 4 carbon atoms, 2 to 3 carbon atoms and one or two nitrogen, oxygen and/or sulphur atoms, said bridge being able to form a partially unsaturated or aromatic radical together with the ring to which it is bound; n is 0, 1, 2 or 3, and the radicals X may be different when n > 1; R is halogen, hydroxy, mercapto, amino, formyl, carboxyl, carbonylamino or an organic radical which is bound directly or via an oxy group, mercapto group, amino group, carboxyl or carbonylamino group, or along with one group X and the pyridyl ring to which they are bound, an optionally substituted bicyclic, partially or completely unsaturated system which can contain heteroatoms from the group of oxygen, sulphur and nitrogen in addition to carbon ring members. It also relates to a process and intermediates for the preparation of said pyridil carbamates and use thereof.

公开(公告)号：DE19540989A1

公开(公告)日：1997-05-07

申请号：DE19540989

申请日：1995-11-03

Applicant: BASF AG

Inventor： MUELLER BERND DR ,  SAUTER HUBERT DR ,  BAYER HERBERT DR ,  GRAMMENOS WASSILIOS DR ,  GROTE THOMAS DR ,  KIRSTGEN REINHARD DR ,  OBERDORF KLAUS DR ,  ROEHL FRANZ DR ,  GOETZ NORBERT DR ,  RACK MICHAEL DR ,  MUELLER RUTH DR ,  LORENZ GISELA DR ,  AMMERMANN EBERHARD DR ,  STRATHMANN SIEGFRIED DR ,  HARRIES VOLKER DR

IPC: C07D213/30 ,  A01N43/40 ,  C07D213/53 ,  C07D213/54 ,  C07D213/55

Abstract: The invention concerns pyridylacetic acid derivatives of formula (I), in which the substituents and the index have the following meanings: X - NOCH3, CHOCH3, CHCH3 and CHCH2CH3; Y - oxygen or NR', R' representing hydrogen or alkyl; R - cyano, nitro, trifluoromethyl, halogen, alkyl and alkoxy; m is 0, 1 or 2; R is hydrogen and alkyl; R - hydrogen, cyano, nitro, hydroxy, amino, halogen, alkyl, alkyl halide, alkoxy, alkoxy halide, alkyl thio, alkylamino or dialkylamino; R - hydrogen, cyano, nitro, hydroxy, amino, halogen; or optionally substituted alkyl, alkoxy, alkylthio, alkylamino, dialkylamino, alkenyl, alkenyloxy, alkenylthio, alkenylamino, N-alkenyl-N-alkylamino, alkinyl, alkinyloxy, alkinylthio, alkinylamino, N-alkinyl-N-alkylamino, cycloalkyl, cycloalkyloxy, cycloalkylthio, cycloalkylamino, N-cycloalkyl-N-alkylamino, cycloalkenyl, cycloalkenyloxy, cycloalkenylthio, cycloalkenylamino, N-cycloalkenyl-N-alkylamino, heterocyclyl, heterocyclyloxy, heterocyclylthio, heterocyclylamino, N-heterocyclyl-N-alkylamino,aryl, aryloxy, arylthio,arylamino, N-aryl-N-alkylamino, hetaryl, hetaryloxy, hetarylthio, hetarylamino, and N-hetaryl-N-alkylamino; R - hydrogen, optionally substituted alkyl, alkenyl, alkinyl, alkylcarbonyl, alkenylcarbonyl, alkinylcarbonyl, alkylsulphonyl, cycloalkyl, aryl, arylcarbonyl, arylsulphonyl, hetaryl, hetarylcarbonyl, or hetarylsulphonyl. Also disclosed are the salts of the above derivatives,and methods and intermediate products for producing them and agents containing them.