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    METHOD FOR PRODUCING ALKYL SULPHONATES
    12.
    发明专利
    METHOD FOR PRODUCING ALKYL SULPHONATES 未知

    公开(公告)号：MY134963A

    公开(公告)日：2008-01-31

    申请号：MYPI20013767

    申请日：2001-08-10

    Applicant: BASF AG

    Inventor： MAAS HEIKO DR ,  NARBESHUBER THOMAS ,  ROPER MICHAEL PROF DR

    IPC: C07B61/00 ,  C07C15/107 ,  C07C303/06 ,  C07C303/32 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

    Abstract: THE INVENTION RELATES TO A PROCESS FOR THE PREPARATION OF ALKYLARYLSULFONATES BY A) REACTION OF A C4-OLEFIN MIXTURE OVER A METATHESIS CATALYST FOR THE PREPARATION OF AN OLEFIN MIXTURE COMPRISING 2-PENTENE AND/OR 3-HEXENE, AND OPTIONAL REMOVAL OF 2-PENTENE AND/OR 3-HEXENE, B) DIMERIZATION OF THE 2-PENTENE AND/OR 3-HEXENE OBTAINED IN STAGE A) OVER A DIMERIZATION CATALYST TO GIVE A MIXTURE CONTAINING C10-12-OLEFINS, AND OPTIONAL REMOVAL OF THE C10-12-OLEFINS, C) REACTION OF THE C10-12-OLEFIN MIXTURES OBTAINED IN STAGE B) WITH AN AROMATIC HYDROCARBON IN THE PRESENCE OF AN ALKYLATING CATALYST TO FORM ALKYL- AROMATIC COMPOUNDS, WHERE, PRIOR TO THE REACTION, ADDITIONAL LINEAR OLEFINS MAY BE ADDED, D) SULFONATION OF THE ALKYLAROMATIC COMPOUNDS OBTAINED IN STAGE C), AND NEUTRALIZATION TO GIVE ALKYLARYLSULFONATES, WHERE, PRIOR TO THE SULFONATION, LINEAR ALKYLBENZENES MAY ADDITIONALLY BE ADDED, E) OPTIONAL MIXING OF THE ALKYLARYLSULFONATES OBTAINED IN STAGE D) WITH LINEAR ALKYLARYLSULFONATES.

    13.
    发明专利
    未知

    公开(公告)号：DK1309545T3

    公开(公告)日：2007-10-29

    申请号：DK01967262

    申请日：2001-08-10

    Applicant: BASF AG

    Inventor： MAAS HEIKO ,  NARBESHUBER THOMAS ,  ROEPER MICHAEL

    IPC: C07C303/06 ,  C07B61/00 ,  C07C15/107 ,  C07C303/32 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

    Abstract: The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C 4 -olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C 10-12 -olefins, and optional removal of the C 10-12 -olefins, c) reaction of the C 10-12 -olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.

    14.
    发明专利
    未知

    公开(公告)号：AT370930T

    公开(公告)日：2007-09-15

    申请号：AT01967262

    申请日：2001-08-10

    Applicant: BASF AG

    Inventor： MAAS HEIKO ,  NARBESHUBER THOMAS ,  ROEPER MICHAEL

    IPC: C07C303/06 ,  C07B61/00 ,  C07C15/107 ,  C07C303/32 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

    Abstract: The invention relates to a process for the preparation of alkylarylsulfonates by a) reaction of a C 4 -olefin mixture over a metathesis catalyst for the preparation of an olefin mixture comprising 2-pentene and/or 3-hexene, and optional removal of 2-pentene and/or 3-hexene, b) dimerization of the 2-pentene and/or 3-hexene obtained in stage a) over a dimerization catalyst to give a mixture containing C 10-12 -olefins, and optional removal of the C 10-12 -olefins, c) reaction of the C 10-12 -olefin mixtures obtained in stage b) with an aromatic hydrocarbon in the presence of an alkylating catalyst to form alkylaromatic compounds, where, prior to the reaction, additional linear olefins may be added, d) sulfonation of the alkylaromatic compounds obtained in stage c), and neutralization to give alkylarylsulfonates, where, prior to the sulfonation, linear alkylbenzenes may additionally be added, e) optional mixing of the alkylarylsulfonates obtained in stage d) with linear alkylarylsulfonates.

    17.
    发明专利
    未知

    公开(公告)号：AT279454T

    公开(公告)日：2004-10-15

    申请号：AT99938254

    申请日：1999-07-15

    Applicant: BASF AG

    Inventor： SIGWART CHRISTOPH ,  NARBESHUBER THOMAS ,  GEHRER EUGEN ,  FISCHER ROLF ,  STEINBRENNER ULRICH ,  LIANG SHELUE

    IPC: C08F4/06 ,  C08F4/10 ,  C08F4/12 ,  C08F4/18 ,  C08F4/24 ,  C08F4/26 ,  C08F110/10

    Abstract: A process for preparing halogen-free, reactive polyisobutene having a terminal double bond content of more than 60 mol % and an average molecular weight Mn of 800-3000 dalton by cationic polymerization in the liquid phase of isobutene over an acidic, essentially halogen-free heterogeneous catalyst, wherea) a hydrocarbon mixture of essentially C4-hydrocarbons comprising isobutene in an amount of from 10 to 80% by weight is used as the starting material andb) polymerization is carried out continuously at from -30 to 0° C. with average starting material residence times of one hour or less, where the temperature and the residence time are selected such that the isobutene conversion is less than 60% and, after separation from the resulting polyisobutene, the isobutene is either enriched in the partially converted hydrocarbon mixture and returned to the polymerization or passed to another isobutene reaction coupled with the polymerization.

    METHODS FOR PRODUCING ALKYLARYL SULFONATES BY USING MODIFIEDDIMERIZED OLEFINS
    18.
    发明专利
    METHODS FOR PRODUCING ALKYLARYL SULFONATES BY USING MODIFIEDDIMERIZED OLEFINS 未知

    公开(公告)号：CA2511184A1

    公开(公告)日：2004-07-15

    申请号：CA2511184

    申请日：2003-12-22

    Applicant: BASF AG

    Inventor： BOTTKE NILS ,  WIEBELHAUS DAG ,  STEINBRENNER ULRICH ,  NARBESHUBER THOMAS

    IPC: C11D1/22 ,  C11D11/04 ,  C07C303/06

    Abstract: The invention relates to methods for producing alkylaryl sulfonates by: a) reacting a C4-olefin mixture on a metathesis catalyst in order to produce a 2- pentene and/or an olefin mixture containing 3-hexene, and optionally separating out 2-pentene and/or 3-hexene; b) dimerizing the 2-pentene and/or 3- hexene obtained in step a) in the presence of a dimerization catalyst to for m a mixture containing C10-12-olefins and optionally separating out the C10-12 - olefins; c) reacting the C10-12-olefin mixtures obtained in step b) with an aromatic hydrocarbon in the presence of an alkylation catalyst in order to form alkyl-aromatic compounds, whereby linear olefins can be additionally added before the reaction; d) sulfonating the alkyl-aromatic compounds obtained in step c) and neutralizing them in order to form alkylaryl sulfonates, whereby linear alkyl benzenes can be additionally added before t he sulfonation; e) optionally mixing the alkylaryl sulfonates obtained in step d) with linear alkylaryl sulfonates.

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