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    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS
    1.
    发明申请
    TWO-STAGE METHOD FOR PRODUCING BUTANDIOL IN TWO REACTORS 审中-公开
    两步反应器制备丁醇的两步法

    公开(公告)号：WO03104214A8

    公开(公告)日：2004-05-13

    申请号：PCT/EP0306060

    申请日：2003-06-10

    Applicant: BASF AG ,  HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    Inventor： HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    IPC: C07C29/149 ,  C07D315/00 ,  C07C31/20 ,  C07D307/20

    CPC classification number: C07D315/00 ,  C07C29/149 ,  C07C31/207

    Abstract: The invention relates to a method for producing optionally akyl-substituted 1,4-butandiol by two-stage catalytic hydration in the gaseous phase of C4 dicarboxylic acids and/or the derivatives thereof with the steps of: a) introducing a gaseous flow of a C4 dicarboxylic acid or a derivative thereof at 200 to 300 °C and 2 to 60 bar in a first reactor and catalytic gas phase hydration to a mainly optionally alkyl-substituted gamma-butyrolactone containing product; b) introducing the product flow so obtained into a second reactor at a temperature of from 150 °C to 240 °C and a pressure of from 15 to 100 bar and catalytic gas phase hydration to optionally alkyl-substituted 1,4-butandiol; c) removing the desired product from the intermediates, byproducts and possibly not reacted educt; d) optionally returning non-reacted intermediates to one or both hydration stages, whereby in both hydration stages one catalyst each is used which comprises = 5 % by weight, preferably 5 to 95 % by weight, especially 20 to 90 % by weight of an oxidic carrier, the pressure prevailing in the second reactor is higher than in the first reactor, and the product mixture removed from the first reactor is introduced into the second reactor without further purifying it.

    Abstract translation: 本发明涉及一种用于在C4二羧酸和/或其衍生物，包括以下步骤的气相制备任选被烷基取代的1,4-丁二醇，通过两阶段催化氢化：a）将C4二羧酸的气体流或它们的衍生物 在200〜300℃和2至在第一反应器和催化气相加氢在含有产物主要为任选被烷基取代的γ-丁内酯60巴; b）将由此获得进入第二反应器在150℃的温度至240℃的产品流和15至100巴和催化气相任选烷基取代的1,4-丁二醇的压力; c）从中间体，副产物和任选未反应的离析物中分离所需产物; d）任选地回收未转化的中间体在一个或两个氢化阶段，其中，在每种情况下，催化剂在两个氢化中使用的<= 95重量％，优选为5〜95重量％，特别是10至80重量％的CuO 和> = 5具有重量％，优选为5〜95重量％，特别是20至90重量的氧化载体的％，在第二反应器更高的压力占优势比在第一反应器和与第一反应器的产物混合物将取出的 不经进一步纯化而引入第二反应器中。

    METHOD FOR PRODUCING ALKYLARYL COMPOUNDS
    3.
    发明申请
    METHOD FOR PRODUCING ALKYLARYL COMPOUNDS 审中-公开
    用于生产烷CONNECTIONS

    公开(公告)号：WO2005061447A3

    公开(公告)日：2007-01-04

    申请号：PCT/EP2004014444

    申请日：2004-12-17

    Applicant: BASF AG ,  BOTTKE NILS ,  TROPSCH JUERGEN ,  NARBESHUBER THOMAS ,  STEPHAN JUERGEN ,  ROEPER MICHAEL ,  HEIDEMANN THOMAS ,  STEINBRENNER ULRICH ,  BENFER REGINA

    Inventor： BOTTKE NILS ,  TROPSCH JUERGEN ,  NARBESHUBER THOMAS ,  STEPHAN JUERGEN ,  ROEPER MICHAEL ,  HEIDEMANN THOMAS ,  STEINBRENNER ULRICH ,  BENFER REGINA

    IPC: C07C2/66 ,  C07C303/06 ,  C07C309/31 ,  C11D1/22 ,  C11D11/04

    CPC classification number: C07C6/04 ,  C07C2/08 ,  C07C2/66 ,  C07C5/2506 ,  C07C303/06 ,  C11D1/22 ,  C11D11/04 ,  C07C309/31 ,  C07C11/02 ,  C07C11/10 ,  C07C15/107

    Abstract: The production of alkylaryl compounds comprises the following stages: a) reaction of a C4/C5 olefin mixture on a metathesis catalyst to produce a C 4-8 olefin mixture containing 2-pentene and the optional isolation of the C 4-8 olefin mixture; b) isolation of between 5 and 100 % of the 2-pentene obtained in step a) and subsequent reaction on an isomerisation catalyst to form a mixture of 2-pentene and 1-pentene, which is returned to stage a); c) dimerisation of the C 4-8 olefin mixture obtained in stage b) after the isolation process, to form a mixture containing C 8-16 olefins, isolation of the C 8-16 olefins and optional isolation of a partial stream of the latter; d) reaction of the C 8-16 olefin mixtures obtained in stage c) or the partial stream with an aromatic hydrocarbon in the presence of an alkylation catalyst, to form alkyl aromatic compounds, whereby prior to the reaction an additional 0 to 60 wt. % linear olefins, in relation to the C 8-16 olefin mixtures obtained in stage c), can be added; e) optional sulphonation of the alkyl aromatic compounds obtained in stage d) and neutralisation to form alkylaryl sulphonates, whereby prior to the sulphonation an additional 0 to 60 wt. % linear alkyl benzols, in relation to the alkyl aromatic compounds obtained in stage d), can be added, provided that there were no admixtures in stage d); f) optional mixing of the alkylaryl sulphonates obtained in stage e) with between 0 and 60 wt. %, linear alkylaryl sulphonates, in relation to the alkylaryl sulphonates obtained in stage e), provided that there were no admixtures in stages d) and e).

    Abstract translation: 烷基芳基化合物通过C4 / C5烯烃混合物的超过一个C含有2-戊烯 4-8 烯烃混合物的制备复分解催化剂的C 的）反应，和可选地移除该制剂 4-8 烯烃混合物，b）中的5％至100％的分离在步骤a）所得2-戊烯和异构化催化剂的2-戊烯与1-戊烯的混合物随后的反应，在阶段a） 再循环，C）C的分离之后，在步骤b中得到的二聚） 4-8 在二聚催化剂存在下烯烃混合物，得到含烯烃-C 8-16 混合物， 的C 8-16 烯烃，和任选除去一个部分流体，D）在步骤C中获得的化合物反应）C 8-16 烯烃混合物或所述部分与芳族料流的分离 在烷基化催化剂的存在下烃以形成烷基芳香族Ve的 rbindungen，其中烯烃，e）可以反应，0〜60重量％之前添加到直链烯烃，基于在步骤c得到的）C在磺化 8-16，任选地 获得步骤d）的烷基芳族化合物中和以得到烷基芳基磺酸盐，其中之前的磺化，0至60重量％，基于在步骤d）中获得的烷基，可被加入到直链烷基苯的芳族化合物中，如果在步骤d没有掺合）下进行 中，f）如果到60重量％）的0）在步骤e中得到的烷基芳基磺酸盐的适当的混合，基于在步骤e烷芳基磺酸盐所获得的），线性烷基芳基磺酸盐，如果在步骤没有外加剂d）和e被执行。

    6.
    发明专利
    未知

    公开(公告)号：DE102005013631A1

    公开(公告)日：2006-09-28

    申请号：DE102005013631

    申请日：2005-03-24

    Applicant: BASF AG

    Inventor： RICHTER INGO ,  PUETTER HERMANN ,  GRIESBACH ULRICH ,  BOTTKE NILS

    IPC: C07D307/32 ,  C07D307/89 ,  C25B3/23

    Abstract: A process for the preparation of 2,5-dihydrofuran derivatives substituted in the 3- or 4-position, which in the 2- or in the 5-position or at both positions each carry a C 1 - to C 6 -alkoxy radical (DHF-alkoxy derivatives 1), or 1,1,4,4-tetraalkoxy-but-2-ene derivatives substituted in the 3- or 4-position, from 2-butene-1 ,4-diol derivatives of the general formula (I) in which the radicals R 1 and R 2 independently of one another are hydrogen, C 1 - to C 6 -alkyl, C 6 - to C 12 -aryl or C 5 - to C 12 -cycloalkylene or R 1 and R 2 , together with the double bond to which they are bonded, form a C 6 - to C 12 -aryl radical or a mono- or polyunsaturated C 5 - to C 12 -cycloalkyl radical, or from their mixture with 2,5-dihydrofuran derivatives substituted in the 3- position or 4-position, which in the 2- or in the 5-position carry a C 1 - to C 6 -alkoxy radical, by electro-chemical oxidation in the presence of a C 1 - to C 6 -monoalkyl alcohol.

    METHODS FOR PRODUCING ALKYLARYL SULFONATES BY USING MODIFIEDDIMERIZED OLEFINS
    7.
    发明专利
    METHODS FOR PRODUCING ALKYLARYL SULFONATES BY USING MODIFIEDDIMERIZED OLEFINS 未知

    公开(公告)号：CA2511184A1

    公开(公告)日：2004-07-15

    申请号：CA2511184

    申请日：2003-12-22

    Applicant: BASF AG

    Inventor： BOTTKE NILS ,  WIEBELHAUS DAG ,  STEINBRENNER ULRICH ,  NARBESHUBER THOMAS

    IPC: C11D1/22 ,  C11D11/04 ,  C07C303/06

    Abstract: The invention relates to methods for producing alkylaryl sulfonates by: a) reacting a C4-olefin mixture on a metathesis catalyst in order to produce a 2- pentene and/or an olefin mixture containing 3-hexene, and optionally separating out 2-pentene and/or 3-hexene; b) dimerizing the 2-pentene and/or 3- hexene obtained in step a) in the presence of a dimerization catalyst to for m a mixture containing C10-12-olefins and optionally separating out the C10-12 - olefins; c) reacting the C10-12-olefin mixtures obtained in step b) with an aromatic hydrocarbon in the presence of an alkylation catalyst in order to form alkyl-aromatic compounds, whereby linear olefins can be additionally added before the reaction; d) sulfonating the alkyl-aromatic compounds obtained in step c) and neutralizing them in order to form alkylaryl sulfonates, whereby linear alkyl benzenes can be additionally added before t he sulfonation; e) optionally mixing the alkylaryl sulfonates obtained in step d) with linear alkylaryl sulfonates.

    10.
    发明专利
    未知

    公开(公告)号：DE10225926A1

    公开(公告)日：2003-12-24

    申请号：DE10225926

    申请日：2002-06-11

    Applicant: BASF AG

    Inventor： HESSE MICHAEL ,  SCHLITTER STEPHAN ,  BORCHERT HOLGER ,  SCHUBERT MARKUS ,  ROESCH MARKUS ,  BOTTKE NILS ,  FISCHER ROLF-HARTMUTH ,  WECK ALEXANDER ,  WINDECKER GUNTHER ,  HEYDRICH GUNNAR

    IPC: C07B61/00 ,  C07C29/149 ,  C07C31/20 ,  C07C29/132 ,  C07D307/20 ,  C07D307/32

    Abstract: The present invention relates to a process for preparing optionally alkyl-substituted 1,4-butanediol by two-stage catalytic hydrogenation in the gas phase of C 4 -dicarboxylic acids and/or of derivatives thereof having the following steps: a) introducing a gas stream of a C 4 -dicarboxylic acid or of a derivative thereof at from 200 to 300° C. and from 10 to 100 bar into a first reactor or into a first reaction zone of a reactor and catalytically hydrogenating it in the gas phase to a product which contains mainly optionally alkyl-substituted gamma-butyrolactone; b) introducing the product stream obtained in this way into a second reactor or into a second reaction zone of a reactor at a temperature of from 140° C. to 260° C. and catalytically hydrogenating it in the gas phase to optionally alkyl-substituted 1,4-butanediol; steps a) and b) being carried out at the same pressure; c) removing the desired product from intermediates, by-products and any unconverted reactants; d) optionally recycling unconverted intermediates into one or both hydrogenation stages, said hydrogenation stages each using a catalyst which comprises =5% by weight, preferably from 5 to 95% by weight, in particular from 20 to 90% by weight, of an oxidic support, and the product mixture removed from the first hydrogenation stage being introduced without further purification into the second hydrogenation stage.

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