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    11.
    发明专利
    未知

    公开(公告)号：DE4132264A1

    公开(公告)日：1993-04-01

    申请号：DE4132264

    申请日：1991-09-27

    Applicant: BASF AG

    Inventor： NIESSNER NORBERT DR ,  NEUMANN RAINER DR ,  RUPPMICH KARL ,  SEITZ FRIEDRICH DR ,  ZELTNER DORIS DR

    IPC: C08L25/08 ,  C08L35/00 ,  C08L43/00 ,  C08L43/02 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L69/00

    Abstract: A moulding composition containing, based on the total amount of A to E, A: 40-90% by weight of a halogen-free polycarbonate A, B: 5-40% by weight of at least one halogen-free graft polymer B built up from, based on B, B1: 40-80% by weight of an elastomer B1 having a glass transition temperature of below 0 DEG C, B2: 20-60% by weight of a graft shell B2 comprising, based on B2, B21: 40-98% by weight of styrene, alpha -methylstyrene, ring-substituted styrene and/or C1-C8-alkyl (meth)acrylate, B22: 50-1% by weight of (meth)acrylonitrile and/or maleic anhydride, B23: 1-50% by weight of an organic phosphorus compound of the formula (I) in which R is H or CH3, R and R are each, independently of one another, halogen-free C1-C8-alkyl or halogen-free C6-C20-aryl which is optionally substituted by halogen-free substituents, X , X and X are O, S or NR (where R is hydrogen or halogen-free C1-C8-alkyl), and n is from 0 to 10, C: 5-40% by weight of a halogen-free, thermoplastic copolymer C comprising, based on C, C1: from 50 to 95% by weight of styrene, alpha -alkylstyrene, ring-substituted styrene and/or C1-C8-alkyl (meth)acrylate (C1), C2: from 4 to 50% by weight of (meth)acrylonitrile C1-C8-alkyl (meth)acrylate and/or maleic anhydride (C2), C3: from 1 to 46% by weight of a halogen-free phosphorus compound of the formula (I), D: up to 20% by weight of a halogen-free phosphorus compound of the formula (II) in which R , R and R are each, independently of one another, halogen-free C1-C8-alkyl or halogen-free, unsubstituted or substituted C6-C20-aryl E: up to 5% by weight of a tetrafluoroethylene polymer having a mean particle size of from 0.05 to 20 mu m.

    Halogen-free, fire-resistant poly:carbonate moulding materials - contain poly:carbonate, graft copolymer, styrene] copolymer, organic phosphate and fluoroalkane-sulphonic or -carboxylic acid deriv.
    12.
    发明专利
    Halogen-free, fire-resistant poly:carbonate moulding materials - contain poly:carbonate, graft copolymer, styrene] copolymer, organic phosphate and fluoroalkane-sulphonic or -carboxylic acid deriv. 未知

    公开(公告)号：DE4034336A1

    公开(公告)日：1992-04-30

    申请号：DE4034336

    申请日：1990-10-29

    Applicant: BASF AG

    Inventor： NEUMANN RAINER DR ,  MUEHLBACH KLAUS DR ,  RUPPMICH KARL ,  BUESCHL RAINER DR ,  SEITZ FRIEDRICH DR

    IPC: C08K5/521 ,  C08L69/00

    Abstract: Chlorine- and bromine-free, fire-resistant thermoplastic moulding materials (I) are claimed, contg. (A) 40-85.99 wt.% halogen-free polycarbonate, (B) 5-25 wt.% halogen-free graft copolymer, (C) 5-40 wt.% halogen-free thermoplastic copolymer, (D) 4-20 wt.% halogen-free phosphorus cpd(s). of formula (II), (E) 0.01-5 wt.% perfluoro- or polyfluoroalkane-sulphonic acid or -carboxylic acid deriv. of formula (F-(CF2CF2)x-(CH2CH2)y-X)mM (III) and (F) 0-50 wt.% fibrous and/or particulate fillers; (B) consists of (B1) 40-80 wt.% rubber polymer base with Tg below 0 deg.C grafted with (B2) 20-60 wt.% copolymer of (B2.1) 50-95 wt.% opt. substd. styrene of formula (IV) and/or MMA and (B2.2) 5-50 wt.% (meth)acrylonitrile, MMA and/or maleic anhydride; (C) is a copolymer of (C1) 50-95 wt.% monomer of type (B2.1) and (C2) 5-50 wt.% monomer of type (B2.2); (I) contain no PTFE. R = H or 1-8C alkyl; R1 = 1-8C alkyl; R2-R4 = 1-8C alkyl or 6-20C aryl, opt. substd. with 1-2 1-4C alkyl gps. n = 0, 1, 2 or 3; X = -SO3 or -COO; M = H, alkali or alkaline earth metal; x = 1-6; y = 0 or 1; m = valency of M. Also claimed is a process for the prodn. of (I), in which component (E) is used in the prodn. of (B) in emulsion, pref. by adding (E) to an aq. dispersion of (B), precipitating the mxit., removing water and drying, and then adding the other components. Amts. are 50-85 wt.% (A), 5-25 wt.% (B), 5-40 wt.% (C), 4-15 wt.% (D), 0.01-2 wt.% (E) and 0.05-30 wt.% (F); (B1) is a crosslinked butadiene polymer or a copolymer of (B1.1) 70-99.9 wt.% (1-8C alkyl) acrylate(s), (B1.2) 0-30 wt.% mono-unsatd. comonomer(s) and (B1.3) 0.1-5 wt.% polyfunctional crosslinking comonomer, in which case (B) consist of 30-70 wt.% coarse graft copolymer with d5o 200-700 nm and 70-30 wt.% fine graft copolymer with d5o 50-180 nm. USE/ADVANTAGE - (I) are useful for the prodn. of fibres, film and mouldings (claimed); also claimed are moulded prods. obtd. from (I). The invention provides halogen-free polycarbonate moulding materials with good fire resistance and high multiaxial impact strength at low temp.

    15.
    发明专利
    未知

    公开(公告)号：DE3735754A1

    公开(公告)日：1989-05-03

    申请号：DE3735754

    申请日：1987-10-22

    Applicant: BASF AG

    Inventor： MUEHLBACH KLAUS DR ,  PORTUGALL MICHAEL DR ,  RUPPMICH KARL ,  SEILER ERHARD DR ,  BRANDT HERMANN DR

    IPC: C08L51/04 ,  C08L69/00

    Abstract: A thermoplastic material containing, based in each case on the molding material comprising A and B, A from 30 to 80% be weight of one or more polycarbonates and B from 70 to 20% by weight of a blend of two different components B1 and B2, each of which consists of one or more graft copolymers b11 and b21 and each of which consists of one or more copolymers (hard matrix) b12 and b22, respectively, the graft copolymer b11 being prepared in emulsion and the graft copolymer b21 being prepared by another method.

    18.
    发明专利
    未知

    公开(公告)号：DE4221293A1

    公开(公告)日：1994-01-05

    申请号：DE4221293

    申请日：1992-06-29

    Applicant: BASF AG

    Inventor： NIESSNER NORBERT DR ,  SEITZ FRIEDRICH DR ,  FISCHER WOLFGANG DR ,  MOORS RAINER DR ,  GUENTHERBERG NORBERT DR ,  RUPPMICH KARL ,  WEISS ROBERT DR

    IPC: C08L51/04 ,  C08L51/06 ,  C08L55/02 ,  C08L101/00 ,  C08L51/00 ,  C08L25/08 ,  C08L27/06 ,  C08L33/12 ,  C08L59/00 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L81/06 ,  C08L81/02

    Abstract: A moulding material based on an impact-modified thermoplastic A, selected from ABS, ASA, high-impact polystyrene (HIPS), high-impact polymethylmethacrylate, high-impact PVC, polycarbonate, polyester carbonate, polyester, polyamide (nylon), polyphenylene ether, polyether ketone, polyether sulphone, polysulphone, polyoxyalkylene, polyarylene sulphide and mixtures thereof, containing a matting agent B comprising from 30 to 80 % by weight of an elastomeric graft base B1 comprising from 75 to 99.8 % by weight of an alkyl acrylate having 1 to 8 carbon atoms in the alkyl radical (B11), from 0.1 to 5 % by weight of a polyfunctional, crosslinking monomer (B12) and from 0.1 to 20 % by weight of a monomer containing one or more acid groups or from 49.9 to 99.9 % by weight of one or more dienes (B111), up to 50 % by weight of a further ethylenically unsaturated monomer (B112) and from 0.1 to 20 % by weight of a monomer containing one or more acid groups (B113), and from 20 to 70 % by weight of a graft shell (B2) comprising from 40 to 99.9 % by weight of a vinyl aromatic monomer (B21), up to 49.9 % by weight of a polar, copolymerisable, ethylenically unsaturated monomer (B22) and from 0.1 to 20 % by weight of a monomer containing one or more basic groups (B23), and a moulding material whose constituents B13 or B113 and B23 have been interchanged.

    20.
    发明专利
    未知

    公开(公告)号：DE4142910A1

    公开(公告)日：1993-07-01

    申请号：DE4142910

    申请日：1991-12-24

    Applicant: BASF AG

    Inventor： NIESSNER NORBERT DR ,  FISCHER WOLFGANG DR ,  GUENTHERBERG NORBERT DR ,  RUPPMICH KARL ,  SEITZ FRIEDRICH DR

    IPC: C08F285/00 ,  C08L25/12 ,  C08L27/06 ,  C08L51/00 ,  C08L69/00

    Abstract: A graft copolymer A comprising - in the sequence A1 to A4 from the inside outward and in each case based on the sum of A1 to A4 - A1: from 5 to 90% by weight of a core having a glass transition temperature Tg of above 25 DEG C, comprising, based on A1: A11: from 50 to 99.9% by weight of a vinylaromatic monomer, A12: from 0.1 to 10% by weight of a polyfunctional, crosslinking monomer and/or a graft-active monomer containing two or more functional groups of different reactivity, where the crosslinking and graft-active action can apply to a single monomer, and A13: up to 49.9% by weight of one or more copolymerisable monomers; A2: from 5 to 90% by weight of a first shell of elastomeric material having a glass transition temperature Tg of below 10 DEG C, comprising, based on A2: A21: from 50 to 99.8% by weight of an alkyl acrylate having 1 to 18 carbon atoms in the alkyl radical and/or of a diene, A22: from 0.1 to 10% by weight of a polyfunctional, crosslinking monomer and/or at least one graft-active monomer containing two or more functional groups of different reactivity, where the crosslinking and graft-active action can apply to a single monomer, A23: from 0 to 49.8% by weight of one or more copolymerisable, unsaturated monomers, and A24: from 0.1 to 10% by weight of one or more acid group-containing monomers, A3: from 5 to 90% by weight of a second shell of hard material having a glass transition temperature Tg of above 25 DEG C, comprising, based on A3: A31: from 50 to 99.9% by weight of a vinylaromatic monomer, A32: up to 10% by weight of a polyfunctional, crosslinking monomer and/or at least one graft-active monomer containing two or more functional groups of different reactivity, A33: up to 49.9% by weight of one or more copolymerisable monomers, and A34: from 0.1 to 20% by weight of one or more basic group-containing monomers; A4: up to 85% by weight of a third shell of a copolymer comprising, based on A4: A41: from 1 to 99% by weight of one or more vinylaromatic monomers, A42: from 1 to 99% by weight of one or more copolymerisable monomers, Original abstract incomplete. f

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