公开(公告)号：BR0314178A

公开(公告)日：2005-08-09

申请号：BR0314178

申请日：2003-09-11

Applicant: BASF AG

Inventor： LUNKWITZ RALPH ,  SEITZ ANDREAS

IPC: C14C9/02

Abstract: A fat liquoring agent for use in production or treatment of leather or hides contains a mixture of an oxidized sulfited native oil and an oxidized sulfated native oil; an emulsifier mixture of (i) a 4-12-alkoxylated 6-14C alkanol, (ii) a 15-40-alkoxylated 12-24C alkanol and (iii) a 50-100-alkoxylated 12-24C alkano. A fat liquoring agent for use in production or treatment of leather or hides contains a mixture of an oxidized sulfited native oil and an oxidized sulfated native oil; an emulsifier mixture of a 4-12-alkoxylated 6-14C alkanol, a 15-40-alkoxylated 12-24C alkanol and a 50-100-alkoxylated 12-24C alkanol; and optionally a linear, cyclic or branched polymer of a dialkylsilanediol of formula SiR2(OH)2 (I); R = methyl, ethyl, n-propyl or phenyl; and/or a sulphonated succinic acid, salt or mono- or di-ester of formula (I) . R1 and R2 = H, M, saturated linear 1-18C alkyl or saturated branched 3-18C alkyl, with at least1 of R1 and R2 not being H or M; M = alkali metal or 0.5 alkaline earth metal; and M+ = H+, (NH4)+, alkali metal+ or 0.5 alkaline earth metal+

公开(公告)号：DE10320110A1

公开(公告)日：2004-11-25

申请号：DE10320110

申请日：2003-05-06

Applicant: BASF AG

Inventor： LUNKWITZ RALPH ,  SEITZ ANDREAS

IPC: C14C9/02 ,  B01F17/42 ,  C09G1/10

Abstract: Fatliquoring agents for the production and/or for the treatment of leather comprising (A) at least one natural lipoid; (B) at least one polymer based on the monomers acrylic acid and/or methacrylic acid; (C) an emulsifier composition containing a C 6 - to C 17 -alkanol alkoxylated with up to 12 alkylene oxide units or a mixture of two or more such alkanols and a C 12 - to C 24 -fatty alcohol mixture alkoxylated with at least 15 alkylene oxide units.

公开(公告)号：DE10111196A1

公开(公告)日：2002-09-19

申请号：DE10111196

申请日：2001-03-08

Applicant: BASF AG

Inventor： LUNKWITZ RALPH ,  SEITZ ANDREAS ,  PABST GUNTHER

IPC: C07C303/02 ,  C07C309/17 ,  C09K23/00 ,  C09K23/10 ,  C14C9/00 ,  C07C69/587 ,  C07C69/604 ,  B01F17/10 ,  B01F17/52 ,  C09K3/18

Abstract: Mixture comprising sulfo-functional di- or tribasic carboxylic acid esters and nonhydroxylic ethers and esters with 18-45C atoms, is new. Composition (I) comprises: (a) di- or tribasic carboxylic acid esters of formula (I); (b) nonhydroxylic ethers and esters with 18-45C; and (c) optionally alkanols of formula (II) and alkanediols of formula (III) Provided that, based on the sum of the weights of nonhydroxylic ethers, nonhydroxylic esters, alkanols, alkanediols and OR and (O)2R groups, the mixture comprises up to 85% OR groups, up to 16% (O)2R groups and up to 45% nonhydroxylic ethers and esters. ((MOOC)a-bR (COO)b)m(R )n(R )p(OH)q (I) R OH (II) R (OH)2 (III) a, b = 2 or 3, provided that b = (a) a 2-6C di- or trivalent, saturated or mono- or diunsaturated, aliphatic or alicyclic hydrocarbon group, at least 50 mole% of R being saturated or monounsaturated and having a sulfonic acid group or (b) a 6C di- or trivalent aromatic hydrocarbon group bearing a sulfonic acid group; R = branched 9-51C alkyl optionally substituted by alkoxy, alkylcarbonyloxy or alkoxycarbonyl; and R = 10-30C alkanediyl. Independent claims are included for: (1) a process for preparing (I); (2) aqueous and nonaqueous compositions comprising: (i) an ester mixture comprising (I) and optionally monoesters of formula (IV) and (V); and (ii) dubbing and/or hydrophobizing substances. (MOOC)dR COOR (IV) ((MOOC)dR COO)2R (V) d = 1 or 2.

公开(公告)号：DE102004024798A1

公开(公告)日：2005-12-08

申请号：DE102004024798

申请日：2004-05-17

Applicant: BASF AG

Inventor： ERHARDT RAINER ,  PABST GUNTHER ,  OETTER GUENTER ,  SEITZ ANDREAS ,  DANISCH PETER

IPC: C07C43/11 ,  C08G71/00 ,  C14C9/02 ,  C08L71/00 ,  C08L91/00

Abstract: Aqueous compositions containing alkoxylated alcohols and hydrophobic components, method for the production and use thereof Compositions comprising, as components, a) at least two alkoxylated alcohols, b) at least one hydrophobic component selected from natural, modified natural and synthetic hydrophobic substances, c) at least 20% by weight, based on the total weight of the composition, of water, wherein the compositions have a mean hydrodynamic radius in the range from 1 to 200 nm, determined by dynamic light scattering.

公开(公告)号：BR0307592A

公开(公告)日：2005-02-01

申请号：BR0307592

申请日：2003-02-20

Applicant: BASF AG

Inventor： LUNKWITZ RALPH ,  SEITZ ANDREAS ,  PABST GUNTHER

IPC: C14C9/02

Abstract: Agents for the fatliquoring of, in particular, leathers and hides tanned in the absence of chromium comprise A) at least one modified natural oil and B) at least one stabilizer L n R where R a is H or methyl, R b is methyl, ethyl or tert-butyl, R c is methyl, tert-butyl, cyclohexyl or methylcyclohexyl, R is an n-valent C 3 - to C 30 -hydrocarbon radical which is unsubstituted or substituted and/or contains hetero atoms and n is an integer from 1 to 10, the stabilizer L n R having altogether at least 20, in particular altogether at least 28, carbon atoms, and, where n is 2, -R- also being -S-, -O-, -N(H)-, -CH 2 -, -(CH 2 ) 2 -, -CH(CH 3 )-, -CH 2 ) 3 -, -CH(C 2 H 5 )- or -C(CH 3 ) 2 -. The novel fatliquoring agents are used in leather production and/or leather treatment, and leather is produced and/or treated using aqueous dispersions of these fatliquoring agents.

公开(公告)号：BR0212245A

公开(公告)日：2004-10-05

申请号：BR0212245

申请日：2002-09-06

Applicant: BASF AG

Inventor： PABST GUNTHER ,  SEITZ ANDREAS ,  LUNKWITZ RALPH

IPC: A61L15/00 ,  A61L15/22 ,  A61L15/60 ,  B01J8/10 ,  C08F2/01 ,  C08F6/00 ,  C09K23/42 ,  C14C9/02 ,  F26B3/20 ,  F26B5/04 ,  F26B21/14 ,  F26B25/00 ,  C11D1/72

Abstract: The invention relates to an emulsifying agent composition which is particularly suitable for the production of low-fogging, high-exhaust stuffing agents, the stuffing agents thus produced and preferred and the utilization of an emulsifying agent composition and the stuffing agent in the production of leather.

公开(公告)号：AU2003206938A1

公开(公告)日：2003-09-09

申请号：AU2003206938

申请日：2003-02-20

Applicant: BASF AG

Inventor： SEITZ ANDREAS ,  PABST GUNTHER ,  LUNKWITZ RALPH

IPC: C14C9/02

Abstract: Agents for the fatliquoring of, in particular, leathers and hides tanned in the absence of chromium comprise A) at least one modified natural oil and B) at least one stabilizer L n R where R a is H or methyl, R b is methyl, ethyl or tert-butyl, R c is methyl, tert-butyl, cyclohexyl or methylcyclohexyl, R is an n-valent C 3 - to C 30 -hydrocarbon radical which is unsubstituted or substituted and/or contains hetero atoms and n is an integer from 1 to 10, the stabilizer L n R having altogether at least 20, in particular altogether at least 28, carbon atoms, and, where n is 2, -R- also being -S-, -O-, -N(H)-, -CH 2 -, -(CH 2 ) 2 -, -CH(CH 3 )-, -CH 2 ) 3 -, -CH(C 2 H 5 )- or -C(CH 3 ) 2 -. The novel fatliquoring agents are used in leather production and/or leather treatment, and leather is produced and/or treated using aqueous dispersions of these fatliquoring agents.

公开(公告)号：DE10143948A1

公开(公告)日：2003-03-27

申请号：DE10143948

申请日：2001-09-07

Applicant: BASF AG

Inventor： PABST GUNTHER ,  ADAMS STEFAN ,  SEITZ ANDREAS ,  LUNKWITZ RALPH ,  VILL KARL

IPC: C14C9/02 ,  C14C13/00

Abstract: Surprisingly, it has been shown that the drawbacks of the previous state of the art, e.g. composition, purity and quality, and price variations of lanolin, can be avoided by substitution of crude, cleaned, and chemically modified wool fat and wool fat based mixtures by polyisobutene and polyisobutene derivatives as stuffing agents. A new stuffing agent for stuffing of skins and leather production including neutral and/or chemically modified native stuffing components (0-97 wt.%), one or more emulsifiers, and polyisobutene and/or polyisobutene derivatives of formula (I): R = a residue of formula (II), (III), or (IV); n = no value between 8 and 800; R = H or 2-8C alkyl, which can be substituted by one or two carboxyl or carboxylate groups, 1-6C alkoxycarbonyl with 1-6C in the alkoxy residue, alkylamino or dialkylamino-alkoxycarbonyl with a total of 1-6C in the alkylamino or dialkylamino groups, amidocarbonyl, cyan, phenyl, hydroxy, poly-lower alkoxy, lower acyloxy, or by the divalent group -O-CO-O- with which it forms a five-or six membered ring; R = R or with the exception of H, where the two R residues can be the same or different; R and R = H, OH, lower alkoxy, poly-lower alkoxy, or R or R = H and the other residue = sulfate (-OSO3H) or sulfone group (-SO3H), amino, alkylamino dialkylamino, with a total of 1-6C in the alkyamino or dialkylamino groups, or for groups of formula -O(CpH2p)COOH); p = 1-7, or their salts or 1-5C lower alkyl ester. The polymer has the formula (I), where R = a residue of formula (II) and R = H. Independent claims are included for: (1) a process for preparation of a polyisobutene stuffing composition by mixing at least one neutral and/or optionally a chemically modified, native stuffing component; and (2) a process for stuffing hides using polyisobutene directly as the stuffing material and/or a polyisobutene derivative in use singly or in combination with other stuffing materials, e.g. in the form of an aqueous emulsion.

公开(公告)号：BR0212315A

公开(公告)日：2004-09-21

申请号：BR0212315

申请日：2002-09-06

Applicant: BASF AG

Inventor： PABST GUNTHER ,  ADAMS STEFAN ,  SEITZ ANDREAS ,  LUNKWITZ RALPH ,  VILL KARL

IPC: C14C9/02

公开(公告)号：AU2003267342A1

公开(公告)日：2004-04-08

申请号：AU2003267342

申请日：2003-09-11

Applicant: BASF AG

Inventor： LUNKWITZ RALPH ,  SEITZ ANDREAS

IPC: C14C9/02

Abstract: A fat liquoring agent for use in production or treatment of leather or hides contains a mixture of an oxidized sulfited native oil and an oxidized sulfated native oil; an emulsifier mixture of (i) a 4-12-alkoxylated 6-14C alkanol, (ii) a 15-40-alkoxylated 12-24C alkanol and (iii) a 50-100-alkoxylated 12-24C alkano. A fat liquoring agent for use in production or treatment of leather or hides contains a mixture of an oxidized sulfited native oil and an oxidized sulfated native oil; an emulsifier mixture of a 4-12-alkoxylated 6-14C alkanol, a 15-40-alkoxylated 12-24C alkanol and a 50-100-alkoxylated 12-24C alkanol; and optionally a linear, cyclic or branched polymer of a dialkylsilanediol of formula SiR2(OH)2 (I); R = methyl, ethyl, n-propyl or phenyl; and/or a sulphonated succinic acid, salt or mono- or di-ester of formula (I) . R1 and R2 = H, M, saturated linear 1-18C alkyl or saturated branched 3-18C alkyl, with at least1 of R1 and R2 not being H or M; M = alkali metal or 0.5 alkaline earth metal; and M+ = H+, (NH4)+, alkali metal+ or 0.5 alkaline earth metal+