公开(公告)号：CZ2003139A3

公开(公告)日：2003-06-18

申请号：CZ2003139

申请日：2001-07-16

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MULLER-ENGEL KLAUS JOACHIM ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07B61/00 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C57/05 ,  C07C57/04 ,  B01J23/883

Abstract: The invention relates to a method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane on a multi-metal oxide mass, said mass containing the elements Mo, V, Te and/or Sb and having a specific X-ray diffractogram.

公开(公告)号：NO20024648A

公开(公告)日：2002-09-27

申请号：NO20024648

申请日：2002-09-27

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  ERDBRUEGGER CRISTINA FREIRE ,  HEIDEMANN THOMAS ,  MEYER GERALD ,  UNVERRICHT SIGNE ,  FRENZEL ANDREA ,  WULFF-DOERING JOACHIM ,  ANSMANN ANDREAS

IPC: B01J35/06 ,  B01J23/44 ,  B01J23/50 ,  B01J37/02 ,  C07B61/00 ,  C07C5/02 ,  C07C7/167 ,  C07C11/04 ,  C07C11/06 ,  C07C11/08 ,  B01J

CPC classification number: C07C5/02 ,  B01J23/44 ,  B01J23/50 ,  B01J35/008 ,  B01J37/0215 ,  C07C7/167 ,  C07C2523/42 ,  C07C2523/44 ,  C07C2523/50 ,  C07C2523/52 ,  C07C2523/72 ,  C07C2523/755 ,  C07C11/00

公开(公告)号：AU2002246034A1

公开(公告)日：2002-08-19

申请号：AU2002246034

申请日：2002-01-12

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  PETZOLDT JOCHEN ,  FELDER RAIMUND ,  UNVERRICHT SIGNE

IPC: B01J23/88 ,  B01J19/30 ,  B01J23/28 ,  B01J23/31 ,  B01J23/887 ,  B01J35/00 ,  B01J35/02 ,  C07B61/00 ,  C07C45/35 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C57/04

Abstract: In a process for the heterogeneously catalyzed gas-phase partial oxidation of precursor compounds of (meth)acrylic acid over a fixed catalyst bed which contains, as a catalyst, a mixed oxide active material shaped into a geometric body, the geometric body is a geometric base body into whose surface a cavity has been introduced.

公开(公告)号：DE10101695A1

公开(公告)日：2002-07-18

申请号：DE10101695

申请日：2001-01-15

Applicant: BASF AG

Inventor： FELDER RAIMUND ,  UNVERRICHT SIGNE ,  ARNOLD HEIKO ,  PETZOLDT JOCHEN

IPC: B01J23/88 ,  B01J19/30 ,  B01J23/28 ,  B01J23/31 ,  B01J23/887 ,  B01J35/00 ,  B01J35/02 ,  C07B61/00 ,  C07C45/35 ,  C07C47/22 ,  C07C51/235 ,  C07C51/25 ,  C07C57/05 ,  C07C57/055 ,  C07C45/28 ,  C01B25/16 ,  C01B19/00 ,  C01G49/02 ,  C01G41/02

Abstract: A process for the heterogeneous catalyzed gas phase partial oxidation of a precursor compound of (meth)acrylic acid to (meth)acrolein and/or meth(acrylic acid) using a mixed oxide catalyst formed into a geometrically shaped article of specific geometric characteristics. A process for the heterogeneous catalyzed gas phase partial oxidation of a precursor compound of (meth)acrylic acid to (meth)acrolein and/or meth(acrylic acid) in which a reaction mixture comprising the precursor compound, molecular oxygen and optionally an inert gas is fed at elevated temperature through a fixed catalyst bed containing a mixed oxide catalyst formed into a geometrically shaped article formed from a base shape that is processed to have at least one cavity such that the ratio of the volume of the geometric shape VK to the volume of the geometric base shape VG is less than or equal to 0.63 and the ratio of the outer surface of the geometric shape (OK) to its volume is at least 22 cm .

公开(公告)号：DE10121592A1

公开(公告)日：2002-05-23

申请号：DE10121592

申请日：2001-05-03

Applicant: BASF AG

Inventor： PETZOLDT JOCHEN ,  UNVERRICHT SIGNE

IPC: C07C45/33 ,  C07C45/35 ,  C07C57/05 ,  B01J23/887

Abstract: Acrolein and acrylic acid are produced from propane and propene by absorption/desorption of propane and propene from a gas mixture followed by oxidation, in which no heterogeneously catalyzed dehydrogenation of propane occurs between the desorption and oxidation stages without addition of oxygen. Acrolein and acrylic acid are produced from propane and propene by: (a) separation of propane and propene from a gas mixture (A) by absorption in an absorption medium; (b) separation of propane and propene from the absorbent to give a mixture (B) containing propane and propene; and (c) using mixture (B) for oxidation to the required product(s). In this process, no catalytic dehydrogenation of propane without the addition of oxygen is carried out between stages (b) and (c).

公开(公告)号：AU2360602A

公开(公告)日：2002-04-22

申请号：AU2360602

申请日：2001-10-09

Applicant: BASF AG

Inventor： PETZOLDT JOCHEN ,  UNVERRICHT SIGNE ,  ARNOLD HEIKO

IPC: B01J23/88 ,  B01J23/887 ,  B01J35/10 ,  B01J37/00 ,  B01J37/02 ,  C07B61/00 ,  C07C45/35 ,  C07C47/22

Abstract: Coated catalysts which are suitable for the gas-phase catalytic oxidation of propene to acrolein are prepared by a process in which rings are used as supports and water is used as a binder.

公开(公告)号：DE10046957A1

公开(公告)日：2002-04-11

申请号：DE10046957

申请日：2000-09-21

Applicant: BASF AG

Inventor： ARNOLD HEIKO ,  UNVERRICHT SIGNE ,  FELDER RAIMUND ,  HARTH KLAUS ,  MUELLER-ENGEL KLAUS JOACHIM

IPC: B01J6/00 ,  B01J19/18 ,  B01J19/22 ,  B01J23/88 ,  B01J23/888 ,  B01J35/00 ,  B01J37/08 ,  C07B61/00 ,  C07C27/14 ,  C07C45/33 ,  C07C45/34 ,  C07C45/35 ,  C07C45/38 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/05 ,  B01J23/887 ,  C07C45/52 ,  C07C51/21

Abstract: Production of a catalyst for gas phase oxidation of organic compounds to alpha ,beta -unsaturated aldehydes and/or carboxylic acids, comprises an active phase of multimetal oxide composition being produced from a particulate precursor containing oxides and/or precursors and activated by calcination. Production of a catalyst for gas phase oxidation of organic compounds to alpha ,beta -unsaturated aldehydes and/or carboxylic acids, comprises an active phase of multimetal oxide composition being produced from a particulate precursor containing oxides and/or precursors and activated by calcination. A stream of precursor is fed at constant rate through calcination zone(s), in which the maximum temperature varies with time and locally are at most 5[deg]C. Independent claims are also included for: (a) a catalyst charge containing a specified active phase; (b) the production of alpha ,beta - unsaturated aldehydes and/or carboxylic acids over this catalyst charge; and (c) a belt calciner with heatable chamber(s) and gas-permeable conveyor belt for particulate material, running through the chamber(s), in which the chamber is provided with means of gas circulation by forced convection.

公开(公告)号：BR0008825A

公开(公告)日：2002-03-26

申请号：BR0008825

申请日：2000-02-28

Applicant: BASF AG

Inventor： UNVERRICHT SIGNE ,  ARNOLD HEIKO ,  TENTEN ANDREAS ,  HAMMON ULRICH

IPC: B01J23/88 ,  B01J8/02 ,  B01J8/04 ,  B01J8/06 ,  B01J23/887 ,  B01J37/02 ,  C07B61/00 ,  C07C51/235 ,  C07C51/25 ,  C07C57/04 ,  C07C57/055

Abstract: In a process for the catalytic gas-phase oxidation of acrolein to acrylic acid, the reaction gas starting mixture is passed, with an acrolein loading of >=150 l (s.t.p.)/l.h, over a fixed-bed catalyst which is housed in two spatially successive reaction zones A, B, the reaction zone B being kept at a higher temperature than the reaction zone A.

公开(公告)号：AU8762201A

公开(公告)日：2002-01-30

申请号：AU8762201

申请日：2001-07-16

Applicant: BASF AG

Inventor： BORGMEIER FRIEDER ,  TENTEN ANDREAS ,  HIBST HARTMUT ,  MULLER-ENGEL KLAUS JOACHIM ,  UNVERRICHT SIGNE ,  COX GERHARD

IPC: B01J23/00 ,  B01J23/28 ,  B01J27/057 ,  B01J37/02 ,  C07B61/00 ,  C07C45/33 ,  C07C45/35 ,  C07C51/215 ,  C07C57/05 ,  C07C51/00

Abstract: The invention relates to a method for producing acrylic acid by the heterogeneously catalysed gas-phase oxidation of propane on a multi-metal oxide mass, said mass containing the elements Mo, V, Te and/or Sb and having a specific X-ray diffractogram.

公开(公告)号：BR0008771A

公开(公告)日：2002-01-08

申请号：BR0008771

申请日：2000-02-28

Applicant: BASF AG

Inventor： UNVERRICHT SIGNE ,  ARNOLD HEIKO ,  TENTEN ANDREAS ,  HAMMON ULRICH ,  NEUMANN HANS-PETER ,  HARTH KLAUS

IPC: B01J23/88 ,  B01J23/00 ,  B01J23/31 ,  B01J23/887 ,  B01J35/00 ,  C07B61/00 ,  C07C27/14 ,  C07C45/35 ,  C07C47/22 ,  C07C51/215 ,  C07C51/25 ,  C07C57/04 ,  C07C57/05

Abstract: A process for the catalytic gas-phase oxidation of propene to acrylic acid, in which the reaction gas starting mixture is oxidized, with an increased propene loading, in a first reaction stage, over a first fixed-bed catalyst and then the acrolein-containing product gas mixture of the first reaction stage is oxidized, in a second reaction stage, with an increased acrolein loading, over a second fixed-bed catalyst, the catalyst moldings in both reaction stages having an annular geometry.