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公开(公告)号:AU2002238456B2
公开(公告)日:2007-01-04
申请号:AU2002238456
申请日:2001-12-19
Applicant: BASF AG
Inventor: MERGER ROLAND , SCHNEIDER PATRIK , KRAH CLAUDIA , VAMVAKARIS CHRISTOS , WAGENBLAST GERHARD
Abstract: In a method of marking hydrocarbons by addition of at least one first marker, at least one second marker which cannot be removed completely from the hydrocarbons under the conditions of the removal of the first marker or markers is additionally added to the hydrocarbons. Hydrocarbons which have been marked by such a method and solutions comprising at least one first marker and at least one second marker as defined in the method of the present invention and also, if desired, further additives for marking hydrocarbons are also provided by the invention.
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公开(公告)号:AU2005266512A1
公开(公告)日:2006-02-02
申请号:AU2005266512
申请日:2005-07-19
Applicant: BASF AG
Inventor: SENS RUDIGER , EBERT SOPHIA , VAMVAKARIS CHRISTOS , THIEL ERWIN
Abstract: The present invention relates to a method for determining the identity or non-identity of at least one chemical compound V' homogeneous y distributed in a medium, by a) exposing the medium containing at least one homogeneously distributed chemical compound V' to analysis radiation with a variable wavelength lambda, and b) determining the spectral measurement function I'(lambda) with the aid of the absorbed, reflected, emitted and/or scattered radiation, wherein a correlation function K(deltalambda,c',c) is determined according to Equation I K ( delta lambda , c ' , c ) = 1 / N . ∫ - ∞ + ∞ I ' ( lambda , c ' ) . I ( lambda + delta lambda , c ) ⅆ lambda ( I ) in which K(deltalambda,c',c) denotes the correlation depending on the relative shift deltalambda of the functions I'(lambda,c') and I(lambda,c) and the concentrations c' and c of the at least one chemical compound V' and V, c' denotes the concentration of the at least one chemical compound V' homogeneously distributed in the medium, with a known or suspected identity, c denotes the concentration of the at least one chemical compound V homogeneously distributed in the medium, with a known identity, I'(lambda,c') denotes the measurement function of the at least one homogeneously distributed chemical compound V' in a medium containing the concentration c', I(lambda,c) denotes the comparison function of the at least one homogeneously distributed chemical compound V in a medium containing the concentration c, and N denotes a normalization factor and identity or non-identity between the compounds V and V' is determined with the aid of the correlation function K(deltalambda,c',c).
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公开(公告)号:PE20051059A1
公开(公告)日:2006-01-20
申请号:PE2005000012
申请日:2005-01-03
Applicant: BASF AG
Inventor: EBERT SOPHIA , SENS RUDIGER , VAMVAKARIS CHRISTOS , SOMOGYI LASZLO
IPC: C07C50/00 , C07C225/34 , C10L1/00 , C10L1/10 , C10L1/185 , C10L1/223 , C10L1/232 , C10M129/24 , C10M171/00
Abstract: ABARCANDO EL DERIVADO DE ANTRAQUINONA LOS COMPUESTOS DE FORMULA (I), DE FORMULA (II) Y DE FORMULA (III), DONDE: Z1 y Z2 SON H, HIDROXI, OR, NHR o NR2; R1 y R2 SON R o COR; X ES H, CIANO, NITRO, HIDROXI, OR, AMINO, NHR, R o CH(R9)(R10); n y m SON 0, 1, 2, 3 o 4, SIENDO PRECISO QUE CUANDO n o m SON MAYORES DE 1, LOS RADICALES R o X SEAN IGUALES O DIFERENTES; R9 y R10 SON CIANO, COOH o COOR; R3 a R8 SON H, R o NHR; y R ES ALQUILO C1-C20 OPCIONALMENTE INTERRUMPIDO POR 1 A 4 ATOMOS DE OXIGENO EN FUNCION DE ETER, CICLOALQUILO C5-C7 SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO, UN RADICAL SATURADO HETEROCICLICO DE 5 o 6 MIEMBROS SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO, ARILO C6-C10 SUSTITUIDO POR UNO O VARIOS HALOGENOS, CIANO, NITRO, HIDROXI, AMINO O DICHO ALQUILO TAMBIEN INTERRUMPIDO CON ALCOXI C1-C20, ALQUILAMINO C1-C20 o DIALQUILAMINO C1-20, HETEROARILO C3-C12 SUSTITUIDO POR UNO O VARIOS DE DICHO ALQUILO TAMBIEN INTERRUMPIDO CON ALCOXI C1-C20, ALQUILAMINO C1-C20 o DIALQUILAMINO C1-20, ARIL C6-C10-ALQUILO C1-C4 DONDE EL ARIL ES EL ANTES MENCIONADO, Y HETEROARILALQUILO C1-C4 CON C3-C12 EN EL ATOMO HETEROARILO SIMILAR AL ANTES MENCIONADO. LOS CONCENTRADOS SE UTILIZAN PARA LA ADITIVACION DE ACEITES MINERALES
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公开(公告)号:CA2554132A1
公开(公告)日:2005-08-04
申请号:CA2554132
申请日:2005-01-14
Applicant: BASF AG
Inventor: SENS RUDIGER , GESSNER THOMAS , EBERT SOPHIA , VAMVAKARIS CHRISTOS
IPC: C07D487/22 , C09B47/067 , C09B47/08 , C09B47/12 , C09B47/30 , C10L1/00 , C10L1/18 , C10L1/22 , C10L1/232 , C10M133/44 , C10M133/54 , G01N33/28
Abstract: The invention relates to the use of special phthalocyanines carrying substituents bound by methylene groups on the skeletal structure thereof, as marking substances for liquids, especially mineral oils and liquids, and especially mineral oils containing at least one such phthalocyanine as a marking substance. The invention also relates to novel special phthalocyanin es carrying substituents bound by methylene groups on the skeletal structure thereof.
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公开(公告)号:AU2005206266A1
公开(公告)日:2005-08-04
申请号:AU2005206266
申请日:2005-01-14
Applicant: BASF AG
Inventor: VAMVAKARIS CHRISTOS , GESSNER THOMAS , EBERT SOPHIA , SENS RUDIGER
IPC: C07D487/22 , C09B47/067 , C09B47/08 , C09B47/12 , C09B47/30 , C10L1/00 , C10L1/18 , C10L1/22 , C10L1/232 , C10M133/44 , C10M133/54 , G01N33/28
Abstract: The present invention relates to the use of specific phthalocyanines which bear substituents on the basic phthalocyanine structure bonded via methylene groups as markers for liquids, especially mineral oils, to liquids, especially mineral oils which comprise at least one such phthalocyanine as a marker, and also to novel specific phthalocyanines which bear substituents on the basic phthalocyanine structure bonded via methylene groups.
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公开(公告)号:ES2205503T3
公开(公告)日:2004-05-01
申请号:ES98928259
申请日:1998-05-13
Applicant: BASF AG
Inventor: MEYER FRANK , VAMVAKARIS CHRISTOS , BECK KARIN HEIDRUN , WAGENBLAST GERHARD , ALBERT BERNHARD
IPC: C07D487/22 , C07D209/00 , C07D259/00 , C07D487/00 , C07D491/107 , C07D519/00 , C09B47/04 , C09B47/067 , C09B47/22 , C09B47/30 , C09K11/06 , C10L1/00 , C10L1/22 , C10L1/232 , C10L1/28 , C10L1/30 , C10M101/02 , C10M133/44 , C10N30/20
Abstract: Phthalocyanines of the formulawhereMe is twice hydrogen, twice lithium, magnesium, zinc, copper, nickel, VO, TiO, AlCl, AlOH, AlOCOCH3, AlOCOCF3, SiCl2 or Si(OH)2,at least four of the radicals R1 to R16 are each independently of the others a five- or six-membered saturated nitrogen-containing heterocyclic radical which is bonded to the phthalocyanine structure via a ring nitrogen atom and which can additionally contain further hetero atoms, andany remaining radicals R1 to R16 are each hydrogen, halogen, hydroxysulfonyl or C1-C4-dialkylsulfamoyl,subject to the proviso that tetrakispiperidinylphthalocyanine shall be excluded,and heterocyclyl-substituted phthalocyanines are useful for marking liquids, in particular mineral oils.
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公开(公告)号:PT983274E
公开(公告)日:2003-12-31
申请号:PT98928259
申请日:1998-05-13
Applicant: BASF AG
Inventor: VAMVAKARIS CHRISTOS , WAGENBLAST GERHARD , ALBERT BERNHARD , BECK KARIN HEIDRUN , MEYER FRANK
IPC: C07D487/22 , C07D209/00 , C07D259/00 , C07D487/00 , C07D491/107 , C07D519/00 , C09B47/04 , C09B47/067 , C09B47/22 , C09B47/30 , C09K11/06 , C10L1/00 , C10L1/22 , C10L1/232 , C10L1/28 , C10L1/30 , C10M101/02 , C10M133/44 , C10N30/20
Abstract: Phthalocyanines of the formulawhereMe is twice hydrogen, twice lithium, magnesium, zinc, copper, nickel, VO, TiO, AlCl, AlOH, AlOCOCH3, AlOCOCF3, SiCl2 or Si(OH)2,at least four of the radicals R1 to R16 are each independently of the others a five- or six-membered saturated nitrogen-containing heterocyclic radical which is bonded to the phthalocyanine structure via a ring nitrogen atom and which can additionally contain further hetero atoms, andany remaining radicals R1 to R16 are each hydrogen, halogen, hydroxysulfonyl or C1-C4-dialkylsulfamoyl,subject to the proviso that tetrakispiperidinylphthalocyanine shall be excluded,and heterocyclyl-substituted phthalocyanines are useful for marking liquids, in particular mineral oils.
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公开(公告)号:UA60336C2
公开(公告)日:2003-10-15
申请号:UA99126999
申请日:1998-05-13
Applicant: BASF AG
Inventor: VAMVAKARIS CHRISTOS
IPC: C07D487/22 , C07D209/00 , C07D259/00 , C07D487/00 , C07D491/107 , C07D519/00 , C09B47/04 , C09B47/067 , C09B47/22 , C09B47/30 , C09K11/06 , C10L1/00 , C10L1/22 , C10L1/232 , C10L1/28 , C10L1/30 , C10M101/02 , C10M133/44 , C10N30/20
Abstract: ФталоціаніниформулиІ , (I) вякій Me означаєдваатомиводню, дваатомилітію, магній, цинк, мідь, нікель, VO, ТіО, АlСl, АlОН, АlОСОСН3, АlOСОСF3, SiCl2 або Si(OH)2, принаймнічотириз радикалів R1 - R16 незалежноодинвідодногоозначаютьгетероциклічнийрадикал, щоміститьазот, зв'язанийізфталоціаніновимскелетомчерезатомазотукільцяі якийміститьможливоодинабодваіншихатомиазотуабоатомкиснюабосірки, іприпотребііншірадикали R1 - R16 означаютьводень, галоген, оксисульфонілабоС1-С4-діалкілсульфамоїл, завиключеннямтетракиспіперидинілфталоціаніну, якзасібмаркуваннярідин, зокрема, мінеральнихмасел.
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19.
公开(公告)号:AU754193B2
公开(公告)日:2002-11-07
申请号:AU3815299
申请日:1999-04-12
Applicant: BASF AG
Inventor: MEYER FRANK , WAGENBLAST GERHARD , BECK KARIN HEIDRUN , VAMVAKARIS CHRISTOS
Abstract: The present invention relates to a method of marking liquids using at least two markers, wherein said markers absorb in the 600-1200 nm region of the spectrum and reemit fluorescent light and the absorption range of at least one marker overlaps with the absorption range of at least one other marker.The present invention further relates to a method for detecting markers in liquids marked by the method of the invention, which comprises using light sources which emit radiation in the absorption ranges of said markers and detecting the fluorescent light reemitted by said markers, at least one of said light sources emitting radiation in the overlapping absorption range of at least one marker with that of at least one other marker and the number of light sources being less than or equal to the number of markers.The present invention further relates to liquids marked by the method of the invention.
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公开(公告)号:CA2431120A1
公开(公告)日:2002-06-27
申请号:CA2431120
申请日:2001-12-19
Applicant: BASF AG
Inventor: KRAH CLAUDIA , VAMVAKARIS CHRISTOS , SCHNEIDER PATRIK , MERGER ROLAND , WAGENBLAST GERHARD
IPC: C10L1/183 , C10L1/00 , C10L1/14 , C10L1/18 , C10L1/182 , C10L1/19 , C10L1/22 , C10L1/224 , G01N33/28
Abstract: The invention relates to a method for the marking of hydrocarbons, by additi on of at least one first marking agent( subsequently referred to as first marki ng agent), characterised in that, in addition, at least one further second marking agent is added to the hydrocarbon, which, under conditions for remov al of the first marking agent, is not completely removable from the hydrocarbon . The invention further relates to hydrocarbons which are to be marked by said method, solutions for marking hydrocarbons, containing at least one first marking agent and at least one second marking agent as defined by the method according to the invention and optionally containing further additives.
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