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公开(公告)号:JPH11193287A
公开(公告)日:1999-07-21
申请号:JP28404098
申请日:1998-10-06
Applicant: BASF AG
Inventor: MEYER FRANK , ISHIDA HIROKI , SCHUHMACHER PETER
IPC: G02F1/13 , C07D307/20 , C07D493/04 , C09K19/34 , C09K19/38
Abstract: PROBLEM TO BE SOLVED: To obtain a new compound useful as an agent of dope with a high torsional strength for a cholesteric liquid crystal and capable of shifting a reflected wave length of a cholesteric compound into the visible spectrum by using an extremely slight amount thereof. SOLUTION: This compound is shown by formula I [a group A is a spacer e.g. (CH2 )p ((P) is 1 to 12) or (CH2 CH2 O)q CH2 CH2 ((q) is 1 to 3); M is a mesogenic group having 2 phenylenes bound to each other through e.g. O, CO or OCO and unsubstituted or substituted with e.g. an 1-4C alkyl or methoxy group; Y is a polymerizable group e.g. a direct bond O, S; (m) is 0 or 1; (n) is 2 to 6; and X is a chiral group e.g. of formula II], e.g. a compound of formula III obtained by reacting bis(4'-hydroxylbenzoyl)-1,4:3,6-dianhydrosobbitol with 4-acryloxybutyloxycarbonyloxybenoyl chloride. A compound of formula I is pref. used in the copolymerized form with a known nematic compound.
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公开(公告)号:JPH11116538A
公开(公告)日:1999-04-27
申请号:JP23157098
申请日:1998-08-18
Applicant: BASF AG
Inventor: SCHUHMACHER PETER , MEYER FRANK , SIEMENSMEYER KARL
IPC: C07C69/96 , C09B67/08 , C09B67/20 , C09B69/10 , C09D4/02 , C09D17/00 , C09K19/00 , C09K19/20 , C09K19/38 , C09K19/42 , C09K19/46 , C09K19/58
Abstract: PROBLEM TO BE SOLVED: To obtain a new liquid crystal compound useful as printed product, coated product, liquid crystal coloring agent, aqueous emulsion, aqueous dispersion, pigment, and so on, all of which have liquid crystal order state in the products. SOLUTION: The compound shown by formula I (P and P are each H, a 1-4C alkyl, or a reactive group capable of causing polymerization; Y and Y are each single bond such as O, S, and OCO; A and A are each a 1-30C spacer whose carbon chain can be intermitted with oxygen in the form of an ether bond or with sulfur in the form of a thioether bond; M is a mesogen) (e.g. formula II) is obtained by reacting at least one compound shown by the formula; HO-M-OH [M is a mesogen shown by formula III (T is a bivalent homocyclic or heterocyclic group; Y is a single bond such as O, S, and OCO; (r) is 0-3) or a mesogen shown by formula IV (ring Z is H, a 1-20C alkyl, a 1-20C alkoxy, a 1-20C alkoxycarbonyl, or the like] with at least one compound shown by formula V or VI (Y is an eliminable).
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公开(公告)号:JP2001158788A
公开(公告)日:2001-06-12
申请号:JP2000309586
申请日:2000-10-10
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE DR , MEYER FRANK , PARKER ROBERT , VILL VOLKMAR , GESEKUS GUNNAR
IPC: C09K19/30 , A61K8/00 , A61K8/02 , A61K8/49 , A61K47/32 , A61Q1/00 , A61Q1/04 , A61Q5/00 , A61Q17/04 , C07D493/04 , C07H9/04 , C07H15/04 , C07H15/20 , C09K19/34 , C09K19/58 , A61K7/025
Abstract: PROBLEM TO BE SOLVED: To obtain a chiral compound suitable for producing a chloesteric liquid crystal composition. SOLUTION: This composition uses a compound expressed by general formula I. The cholesteric liquid crystal composition is usable as cosmetics for protecting human skin or hair from sunbeam or a UV filter in medicinal preparation.
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公开(公告)号:JP2001328985A
公开(公告)日:2001-11-27
申请号:JP2001079296
申请日:2001-03-19
Applicant: BASF AG
Inventor: PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , PARKER ROBERT , KUERSCHNER KATHRIN , VILL VOLKMAR , PAUL MATHIAS
Abstract: PROBLEM TO BE SOLVED: To provide a chiral 1,3-dioxane compound and a diastereomer thereof, and to use the above compound as a chiral dopant for liquid crystalline system. SOLUTION: This chiral 1,3-dioxane compound is shown by the general formula I. This compound is suitable for producing cholesteric liquid-crystalline compositions, having relatively high torsional ability, and according thereto, exerting significant impact on the optical properties of liquid-crystalline host systems even in relatively small quantities.
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5.
公开(公告)号:JP2001172329A
公开(公告)日:2001-06-26
申请号:JP2000255434
申请日:2000-08-25
Applicant: BASF AG
Inventor: MEYER FRANK , PRECHTL FRANK , SCHNEIDER NORBERT , HEILMANN PETER , KOCH VOLKER , PARKER ROBERT , RICHTER VOLKER , SCHUMACHER PETER
IPC: G02B5/30 , C08F2/46 , C08F20/26 , C09B67/00 , C09B67/02 , C09B67/08 , C09B67/20 , C09D5/29 , C09D5/36 , C09D201/00 , C09K19/00 , G02F1/1335
Abstract: PROBLEM TO BE SOLVED: To obtain a cholesteric layer material with improved color impression and to provide a method for manufacturing the same. SOLUTION: In this material, the crosslinked cholesteric layer exhibits an interference fringe pattern which is homogeneous across the whole range of thickness. The cholesteric layer material of this invention and products derived from the same are superb in that their color does not go out of registration in a visually detectable way.
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6.
公开(公告)号:JP2001154024A
公开(公告)日:2001-06-08
申请号:JP2000255435
申请日:2000-08-25
Applicant: BASF AG
Inventor: PRECHTL FRANK , SCHNEIDER NORBERT , MEYER FRANK , BLASCHKA PETER , HAREMZA SYLKE DR , HEZEL TILMANN , PARKER ROBERT , RICHTER VOLKER
IPC: G02B5/30 , C08F2/46 , C08F20/26 , C09B67/00 , C09B67/02 , C09B67/08 , C09B67/20 , C09D5/29 , C09D5/36 , C09D201/00 , C09K19/00 , G02F1/1335
Abstract: PROBLEM TO BE SOLVED: To provide a cholesteric layer material having improved color stability, and a method for manufacturing it and its use. SOLUTION: A cholesteric layer material, having at least one kind of cholesteric layer three-dimensionally cross-linked and aligned, is used. The cholesteric layer cross-linked will not show visible color slippages.
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公开(公告)号:JP2000044451A
公开(公告)日:2000-02-15
申请号:JP15677699
申请日:1999-06-03
Applicant: BASF AG
Inventor: SCHUMACHER PETER , SCHNEIDER NORBERT , WESTENFELDER HORST , HAREMZA SYLKE DR , HABECK THORSTEN , MEYER FRANK
IPC: A61K8/00 , A61K8/02 , A61K8/23 , A61K8/25 , A61K8/29 , A61K8/31 , A61K8/33 , A61K8/34 , A61K8/36 , A61K8/37 , A61K8/41 , A61K8/46 , A61K8/49 , A61K8/73 , A61K8/86 , A61K8/89 , A61K8/97 , A61K8/98 , A61K31/255 , A61K31/34 , A61P17/16 , A61Q1/00 , A61Q1/04 , A61Q1/10 , A61Q5/00 , A61Q17/04 , A61Q19/00 , C09B67/20 , C09C3/08 , C09K3/00 , A61K7/42
Abstract: PROBLEM TO BE SOLVED: To protect human epidermis or human hair against sunrays by using a specific cholesteric liquid crystal composition as a filter in a UV-A and a UV-B regions of a cosmetic and a medicine. SOLUTION: A cholesteric liquid crystal composition is obtained by including (A) a polymerizable chiral liquid crystal monomer capable of providing a cholesteric liquid crystal phase having
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公开(公告)号:WO9700600A2
公开(公告)日:1997-01-09
申请号:PCT/EP9603756
申请日:1996-08-26
Applicant: BASF AG , MEYER FRANK , SIEMENSMEYER KARL , ETZBACH KARL HEINZ , SCHUHMACHER PETER
Inventor: MEYER FRANK , SIEMENSMEYER KARL , ETZBACH KARL-HEINZ , SCHUHMACHER PETER
CPC classification number: C09K19/2014 , C07C69/96 , C09K19/00 , C09K19/2007 , C09K19/3405 , C09K19/3411 , C09K19/3483 , C09K19/3491 , C09K19/38 , C09K2019/0448 , C09K2019/323 , C09K2019/3408 , C09K2019/3422 , C09K2019/3425
Abstract: The invention concerns polymerizable liquid-crystalline compounds of the general formula (I) Z -Y -A -Y -M-Y -A -Y -Z in which the variables have the following meanings: Z , Z are radicals with reactive groups which can bring about polymerization; Y - Y are a chemical single bond, oxygen, sulphur, -O-CO-, -CO-O-, -O-CO-O-, -CO-NR-, -NR-CO-, -O-CO-NR-, -NR-CO-O- or -NR-CO-NR-, at least one of the groups Y and Y meaning -O-CO-O-, -O-CO-NR-, -NR-CO-O- or -NR-CO-NR-; A , A are C2-C30 spacers in which the carbon chain can be interrupted by oxygen in the ether function, sulphur in the thioetherfunction or by non-adjacent imino or C1-C4 alkylimino groups; M is a mesogenic group; and R is C1-C4 alkyl. The compounds and compositions containing them are distinguished by advantageous liquid-crystalline phase temperature ranges and can be used in optical display units and cholesteric liquid-crystalline colouring agents.
Abstract translation: 聚合液晶通式(I)的化合物,位:Z <1> -Y <1> -A <1> -Y <3> -MY <4> -A <2> -Y <2> -Z <2>, 其中各变量具有以下含义位:Z <1>,含有反应性基团Z <2>的基团,通过该聚合可以带来,Y <1> - ý<4>化学键,氧,硫,-O-CO - , - CO-O-,-O-CO-O-,-CO-NR - , - NR-CO-,-O-CO-NR-,-NR-CO-O-或-NR-CO-NR - 其中,所述基团中至少一个Y是<3>和Y <4> -O-CO-O-,-O-CO-NR-,-NR-CO-O或-NR-CO-NR-。 A <1>,A <2>具有其中碳链被醚氧间隔2至30个碳原子的间隔基,硫可以以硫醚功能或不相邻的亚氨基或C 1 -C 4烷基亚氨基中断,M是介晶基团, [R C1-C4烷基。 的化合物和含有它们的组合物,是通过有利液晶相的温度范围来区分,并且可以在光学显示装置和在胆甾型液晶的着色剂一起使用。
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公开(公告)号:WO2004002979A3
公开(公告)日:2004-04-22
申请号:PCT/EP0306885
申请日:2003-06-30
Applicant: BASF AG , PARKER ROBERT , PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , VILL VOLKMAR , GESEKUS GUNNAR
Inventor: PARKER ROBERT , PRECHTL FRANK , HAREMZA SYLKE , MEYER FRANK , VILL VOLKMAR , GESEKUS GUNNAR
IPC: C07D309/30 , C09K19/54 , C09K19/34 , C09K19/58
CPC classification number: C07D309/30 , Y10T428/10 , Y10T428/1036 , Y10T428/1041
Abstract: The invention relates to chiral 3,4-dihydro-2H-pyran compounds, to diastereomers thereof, and to the use of these compounds as chiral dopants for liquid crystal systems. The invention also relates to non-polymerizable or polymerizable liquid crystal compositions, which contain at least one inventive chiral 3,4-dihydro-2H-pyran compound, to the use of these non-polymerizable or polymerizable liquid crystal compositions for producing optical components, to the use of the polymerizable liquid crystal compositions for imprinting or coating substrates, for producing dispersions and emulsions, films or pigments, and to these optical elements, imprinted or coated substrates, dispersions and emulsions, films and pigments.
Abstract translation: 本发明涉及手性3,4-二氢-2H-吡喃化合物及其非对映体以及使用这些化合物作为用于液晶Systeme.Weiter本发明手性掺杂剂的涉及包含至少一个手性3,4-二氢发明非聚合或聚合的液晶组合物 -2H-吡喃化合物,涉及使用这些非聚合或聚合的液晶组合物的用于生产光学元件的,使用用于印刷或涂布的基材的聚合性液晶性组合物中,用于制备分散体和乳液,薄膜或颜料,并且这种光学部件,印刷或 涂布的基材,分散体和乳液,膜和颜料。
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公开(公告)号:WO9602597A3
公开(公告)日:1996-05-23
申请号:PCT/EP9504576
申请日:1995-11-21
Applicant: BASF AG , BECK ERICH , MEYER FRANK , POTH ULRICH , SIEMENSMEYER KARL , SIERAKOWSKI CLAUDIA , GREIF NORBERT , OSTERTAG WERNER , ZIRNSTEIN MICHAEL , LEYRER REINHOLD , JAHNS EKKEHARD , ETZBACH KARL HEINZ , SCHUHMACHER PETER
Inventor: BECK ERICH , MEYER FRANK , POTH ULRICH , SIEMENSMEYER KARL , SIERAKOWSKI CLAUDIA , GREIF NORBERT , OSTERTAG WERNER , ZIRNSTEIN MICHAEL , LEYRER REINHOLD , JAHNS EKKEHARD , ETZBACH KARL-HEINZ , SCHUHMACHER PETER
IPC: C09K19/38 , C08F20/28 , C09B67/00 , C09D4/00 , C09D4/06 , C09D5/29 , C09D5/36 , C09D11/02 , C09D11/10 , C09D11/16 , C09K19/00 , C09K19/54 , C09K19/58
CPC classification number: C09K19/586 , C08F20/28 , C09B67/0098 , C09D4/06 , C09D5/36 , C09D11/101 , C09D11/106 , C09D11/16 , C09K19/00 , C09K19/542 , C08F290/06
Abstract: The process for coating or printing substrates with a coating or printing agent is characterized by the application to the substrate of a polymerizable substance containing liquid crystal, polymerizable monomers which for coating carry at least two polymerizable groups and for printing carry at least one polymerizable group, followed by polymerization, wherein the coating or printing agent contains a1) a chiral liquid crystal monomer and b) a polymer binder and/or monomer compounds that can be converted into the polymer binder by polymerization or, in the case of dispersion coatings and printing inks, a dispersing aid d), or the coating or printing agent contains a2) an achiral liquid crystal monomer, b) a polymer binder and/or monomer compounds that can be converted into the polymer binder by polymerization or, in the case of dispersion coatings and printing inks, a dispersing aid d), and c) a chiral compound that is not a liquid crystal.
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