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    12.
    发明专利
    未知

    公开(公告)号：DE19650563A1

    公开(公告)日：1998-06-10

    申请号：DE19650563

    申请日：1996-12-05

    Applicant: BASF AG

    Inventor： GOTTSCHALK AXEL DR ,  WEBER MARTIN DR ,  KOCH ANDREAS DR ,  AUMUELLER ALEXANDER DR

    IPC: C08J5/00 ,  C08K5/5399 ,  C08L25/02 ,  C08L33/06 ,  C08L51/00 ,  C08L51/04 ,  C08L67/02 ,  C08L69/00 ,  C08L77/00 ,  C08L101/00 ,  C08J5/18 ,  C08K5/16 ,  C08K5/49 ,  C08L23/00 ,  C08L33/10 ,  C08L67/00 ,  C09K21/14 ,  D01F6/66

    Abstract: The invention concerns flame-resistant thermoplastic moulding compounds containing: A) between 1 and 97 wt % of at least one polycarbonate, polyamide, polyester, polyolefin or polymethacrylate or a mixture of the above-mentioned thermoplastic polymers; B) between 1 and 97 wt % of at least one graft polymer consisting of: b1) between 40 and 80 wt % of a graft basis comprising a rubber-elastic polymer with a glass transition temperature of less than 0 DEG C; and b2) between 20 and 60 wt % of a graft overlay comprising: b21) between 50 and 95 wt % vinylaromatic monomers of general formula PHI , in which R designates a C1-C8 alkyl group or a hydrogen atom and R designates a C1-C8 alkyl group, and n has the value 0, 1, 2 or 3 or methylmethacrylate or mixtures thereof; and b22) between 5 and 50 wt % acrylonitrile, methacrylonitrile, methylmethacrylate, maleic acid anhydride or mixtures thereof; C) between 1 and 97 wt % of at least one thermoplastic copolymer comprising: c1) between 50 and 95 wt % vinylaromatic monomers of general formula PHI or methylmethacrylate or mixtures thereof; and c2) between 5 and 50 wt % acrylonitrile, methacrylonitrile, methylmethacrylate, maleic acid anhydride or mixtures thereof; D) between 1 and 50 wt % flame retardants containing iminophosphoranes; and E) between 0 and 50 wt % further additives.

    Polycarbonate moulding material with high processing stability
    15.
    发明专利
    Polycarbonate moulding material with high processing stability 未知

    公开(公告)号：DE19621733A1

    公开(公告)日：1997-12-04

    申请号：DE19621733

    申请日：1996-05-30

    Applicant: BASF AG

    Inventor： GUENTHERBERG NORBERT DR ,  WEBER MARTIN DR

    IPC: C08L25/02 ,  C08L25/08 ,  C08L33/06 ,  C08L51/04 ,  C08L69/00 ,  C08J3/20 ,  C08J5/00 ,  C08J5/18 ,  C08L25/12 ,  C08L33/08 ,  C08L33/10 ,  C08L33/12

    Abstract: Thermoplastic moulding materials contain: (A) 10-90.9 wt% aromatic polycarbonate, (B) 5-30 wt% graft copolymer comprising: (b1) 20-80 wt% rubber-elastic polymer base with a Tg of below 0 deg C; and (b2) 20-80 wt% grafted component with a Tg of above 50 deg C derived from 2 monomers (b2.1) and (b2.2), (C) 2-70 wt% thermoplastic copolymer of: (c1) 50-90 wt% styrene; and (c2) 10-50 wt% acrylonitrile and/or 1-8C alkyl (meth)acrylate, with a Tg of more than 50 deg C and a viscosity number of 40-160 cm /g, (D) 2-70 wt% thermoplastic copolymer other than (C), containing: (d1) 50-99 wt% styrene and/or substituted styrene of formula (I): R = 1-8C alkyl or H, R' = 1-8C alkyl, and n = 0, 1, 2 or 3, and (d2) 1-50 wt% (meth)acrylonitrile, maleic anhydride, maleimide (optionally N-substituted with 1-8C alkyl or 6-20 C aryl), 1-8C alkyl (meth)acrylate, (meth)acrylamide and/or 1-8C alkyl vinyl ether, (E) 0.1-25 wt% copolymer(s) of: (e1) 50-99 wt% of a mixture of: (e1.1) 80-100 wt% 1-10C alkyl (meth)acrylate and/or 5-8C cycloalkyl (meth)acrylate, and (e1.2) up to 20 wt% 1-10C alkyl acrylate, (e2) 0.5-20 wt% maleic acid or anhydride, fumaric acid, itaconic acid and/or maleimide (optionally N-substituted as above), and (e3) 0.5-40 wt% vinylaromatic(s) (optionally ring- substituted with one or two 1-4C alkyl groups), and (F) 0-50 wt% additives, auxiliary substances and/or fibrous and/or particulate fillers.

    THERMOPLASTIC MOULDING MATERIALS
    16.
    发明专利
    THERMOPLASTIC MOULDING MATERIALS 未知

    公开(公告)号：CZ266795A3

    公开(公告)日：1996-05-15

    申请号：CZ266795

    申请日：1995-10-12

    Applicant: BASF AG

    Inventor： GUNTHERBERG NORBERT DR ,  WEBER MARTIN DR ,  GRUBER FREDDY DR ,  LINDENSCHMIDT GERHARD DR

    IPC: B29C45/00 ,  B29C48/03 ,  B29C48/305 ,  C08F265/06 ,  C08L9/06 ,  C08L21/00 ,  C08L25/02 ,  C08L25/04 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L53/02 ,  C08L71/02 ,  B29C47/14

    Abstract: Thermoplastic moulding materials (I) contain: (A) 30-98 wt.% of a graft copolymer of: (ak) 30-90 wt.% rubber-elastic grafting core, obtd. by copolymerisation of: (ak1) 80-99.99 wt.% (1-10C alkyl) acrylate, (ak2) 0.01-20 wt.% crosslinking monomer, and (ak3) 0-40 wt.% other comonomer(s); and (as) 10-70 wt.% of a grafted shell derived from: (as1) 50-100 wt.% styrene cpd. of formula (a); and (as2) 0-50 wt.% other comonomer(s); (B) 1-50 wt.% of a thermoplastic polymer of: (b1) 50-100 wt.% styrene and/or alpha -methylstyrene (AMS), (b2) 0-50 wt.% acrylonitrile, and (b3) 0-50 wt.% other comonomer(s); and (C) 1-70 wt.% of a copolymer of: (c1) 30-90 wt.% styrene and AMS, (c2) 10-70 wt.% butadiene, and (c3) 0-30 wt.% other comonomer(s); comprising: (i) block X obtd. by polymerising (c2) and opt. (c3) and block Y by polymerising (c1) and opt. (c3), or (ii) a polymer with a butadiene-rich initial segment, increasing amts. of styrene along the chain, and a terminal segment of homo-polystyrene (PS); or (iii) a star-shaped polymer obtd. by linking several polymer chains contg. (c1)-(c3) with polyfunctional mols., and in which the olefinic double bonds are completely or almost completely hydrogenated. Also claimed are films and moulded prods. obtd. from (I). R , R = H or 1-8C alkyl, and/or (1-8C alkyl) (meth)acrylate.

    Moulding compsn. having reduced water absorption
    18.
    发明专利
    Moulding compsn. having reduced water absorption 未知

    公开(公告)号：DE4407485A1

    公开(公告)日：1995-09-14

    申请号：DE4407485

    申请日：1994-03-07

    Applicant: BASF AG

    Inventor： WEBER MARTIN DR ,  GUENTHERBERG NORBERT

    IPC: C08L35/06 ,  C08L71/00 ,  C08L81/06 ,  C08J3/00 ,  D01F6/94

    Abstract: A moulding compsn. contains (A) 1-99 wt.% of a polyarylene ether; (B) 1-99 wt.% of a copolymer contg. (b1) and aromatic vinyl cpd., (b2) and alpha,beta-unsatd. dicarboxylic acid, and (B3) an alpha,beta-unsatd. dicarboxylic acid imide; (C) 0-60 wt.% of a fibrous or particulate filler selected from carbon, glass quartz, aramid and alkali(ne earth) carbonate or silicate; (D) 0.45 wt.% of an impact modifying rubber; and (E) 0-40 wt.% of a flame retardant, pigment and stabiliser. Also claimed are the use of the compsn. to produce fibres, films or mouldings; to produce household or medical articles; for the prodn. of compatibility improvers; the films or mouldings produced from the compsn. and a process for the prepn. of the compatibility improver.

    Copolymers of 4-vinyl:phthalic acid, anhydride or ester(s) - are useful as components of polymer alloys
    19.
    发明专利
    Copolymers of 4-vinyl:phthalic acid, anhydride or ester(s) - are useful as components of polymer alloys 未知

    公开(公告)号：DE4316024A1

    公开(公告)日：1993-11-25

    申请号：DE4316024

    申请日：1993-05-13

    Applicant: BASF AG

    Inventor： GOTTSCHALK AXEL DR ,  SEITZ FRIEDRICH DR ,  MUEHLBACH KLAUS DR ,  RECTANUS SABINE ,  STADLER RAIMUND PROF DR ,  WEBER MARTIN DR

    IPC: C08F222/00 ,  C08L25/18

    Abstract: The use of copolymers (I) contg. 0.1-99.9 wt% 4-vinylphthalic anhydride, 4-vinyl-phthalic acid and/or dialkyl 4-vinylphthalate ester (II) and 99.9-0.1 wt% vinyl and/or diene comonomer(s) (III) as components of polymer alloys is claimed. ADVANTAGE - (I) have a desirable combination of properties as components of polymer alloys, e.g. markedly better heat distortion temp. than corresp. styrene homopolymers, together with the possibility of reactive phase coupling (via acid or anhydride gps.) (I) are therefore useful as compatibilisers in polymer alloys and for the prodn. of polymeric networks; copolymers contg. more than 50 wt% 4-vinylphthalic acid units are soluble in aq. alkali and are therefore also useful for the prodn. of resist materials. In an example, 4-Vinylphthalic acid was prepd. by bromination of phthalic acid with bromine in aq. NaOH soln., followed by reaction with ethylene for 16 hrs. at 100 deg. C and 40 bar in the presence of Et3N, Pd(OAc)2, tri-o-tolyl-phosphine and DMF, pptn. with CaCl2, soln. and acidifcation. The acid obtd. was sublimed at 90 deg. C and 0.03 mbar to give 4-vinylphthalic anhydride (VPA). A copolymer contg. 10.5 wt% VPA and 89.5 wt% styrene (by FT-IR analysis) was prepd. by radical polymerisation in acetonitrile with AIBN as initiator, followed by re-pptn. from THF/methanol. The prod. had Mn, 5700; Tg, 91 deg. C (cf. 4900, 74 deg. C for 100% styrene homopolymer); a copolymer of 67.4 wt% VPA and 32.6 wt% styrene was soluble in aq. NaOH soln., with Mn = 2200 and Tg = 160 deg. C.

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