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公开(公告)号:AT178581T
公开(公告)日:1999-04-15
申请号:AT96900560
申请日:1996-01-04
Applicant: BASF AG
Inventor: MERKLE HANS RUPERT , FRETSCHNER ERICH , HANSEN HANSPETER , ZIPPERER BERNHARD
IPC: C07B57/00 , C07C51/09 , C07C51/487 , C07C53/19
Abstract: PCT No. PCT/EP96/00012 Sec. 371 Date Jan. 7, 1997 Sec. 102(e) Date Jan. 7, 1997 PCT Filed Jan. 4, 1996 PCT Pub. No. WO96/22272 PCT Pub. Date Jul. 25, 1996The present invention relates to a process for the preparation of optically active 2-halopropionic acids, in which the corresponding optically active alkyl 2-halopropionates are caused to react with a carboxylic acid at elevated temperature in a transacylation reaction with the formation of the optically active 2-halopropionic acid and the alkyl carboxylate, and the optically active 2-halopropionic acid obtained is separated from the reaction mixture. The optically active products produced are important intermediates for the preparation of plant protectants and pharmaceuticals.
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公开(公告)号:DK0714447T3
公开(公告)日:1998-10-07
申请号:DK94925459
申请日:1994-08-17
Applicant: BASF AG
Inventor: LADNER WOLFGANG , RETTENMAIER HANSJOERG , ZIPPERER BERNHARD , HANSEN HANSPETER
Abstract: PCT No. PCT/EP94/02738 Sec. 371 Date Feb. 15, 1996 Sec. 102(e) Date Feb. 15, 1996 PCT Filed Aug. 17, 1994 PCT Pub. No. WO95/06130 PCT Pub. Date Mar. 2, 1995A process for the preparation of (L)-2-chloropropionic acid and its alkali metal, alkaline earth metal or ammonium salts which comprises hydrolyzing isobutyl L-chloropropionate at a pH of from 4 to 8 in the presence of a lipase from Pseudomonas spec. DSM 8246 and isolating the optically active reaction product from the reaction mixture either directly or after conversion of the salt into the acid in a conventional way, or further reacting it in situ. The optically active products are important intermediates for preparing crop protection agents.\!
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公开(公告)号:HU208227B
公开(公告)日:1993-09-28
申请号:HU849390
申请日:1990-12-28
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , AMMERMANN EBERHARD , LORENZ GISELA , ZIERKE THOMAS , SAUTER HUBERT
IPC: A01N43/40 , C07D213/30 , C07D213/50 , C07D405/04 , A01N43/90
Abstract: 3-Substituted pyridines I … …… … (X = OH; Y = -O-CHO, -O-CO-W R , -O-SO2-W R or X + Y = -O-CH(W R )-O-, O CH(O W R )-O-, -O-C-(W R )(O-W R )-O-; W -W = direct bond, -CH2-, -CH2-CH2, -CH(CH3)-, -CH2O-, -CH2S-; R -R = optionally cycloalkyl-substituted C1-C6-alkyl, C1-C6-haloalkyl, C3-C8-cycloalkyl which is optionally substituted by 1-3 alkyl radicals, or C1-C4-alkoxy-C1-C4-alkyl, C1-C4-alkylthio-C1-C4-alkyl, C2-C6-alkenyl, C2-C6-alkynyl, optionally substituted phenyl or naphthyl, optionally substituted 5-/6-membered heteroaryl having 1 to 3 hetero atoms; … R is additionally H when X + Y = -O-CH(W R )-O-, -O-CH(O-W R )-O- or -O-C(W R )(O-W R )-O- and W2 = direct bond), … with the exception of cis-1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxypropane, trans-1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxypropane, 1-(2,4-dichlorophenyl)-2-(pyrid-3-yl)- 1,2-epoxybutane and 2,4-dichloro- alpha -[1-hydroxy-1-(pyrid-3-yl)ethyl]- benzyl methanesulphonate … and the N-oxides and phytophysiologically acceptable salts with mineral acids, and metal complexes of I. … The compounds I are suitable as fungicides.
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公开(公告)号:ZA9101588B
公开(公告)日:1992-11-25
申请号:ZA9101588
申请日:1991-03-05
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , BERNHARD ZIPPERER , AMMERMANN EBERHARD , EBERHARD AMMERMANN , LORENZ GISELA , GISELA LORENZ
IPC: A01N33/04 , A01N33/06 , A01N33/10 , A01N33/12 , C07C45/69 , C07C49/613 , C07C49/657 , C07C209/24 , C07C211/40 , C07C211/48 , C07C211/52 , C07C211/62 , C07C211/63 , C07C211/64 , C07C215/08 , C07C215/40 , C07C215/48 , C07C215/76 , C07C217/56 , C07C217/58 , C07C217/60 , C07C217/82 , C07C217/84 , C07C255/58 , C07C , A01N
CPC classification number: C07C255/58 , A01N33/04 , A01N33/06 , A01N33/10 , A01N33/12 , C07C45/69 , C07C49/657 , C07C211/40 , C07C211/48 , C07C211/52 , C07C211/63 , C07C211/64 , C07C217/58 , C07C217/60 , C07C217/84 , C07C2601/08 , C07C2601/14 , C07C2601/18 , C07C2601/20 , C07C2602/42
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公开(公告)号:AU620244B2
公开(公告)日:1992-02-13
申请号:AU5467890
申请日:1990-05-04
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , SAUTER HUBERT , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N43/10 , A01N43/40 , C07D213/30 , C07D213/89 , C07D405/06 , C07D409/06
Abstract: Pyridines of the formula 1 where R1 is hydrogen, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or an acyl radical COR2; R2 is C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-haloalkyl or substituted or unsubstituted aryl; A is one of the groups where R3 and R4 are identical or differ and each is C1-C6-alkyl, with the proviso that R3 and R4 are not simultaneously methyl; R5 is one of the groups (CH2)n, CH2OCH2, CH2S(O)mCH2, CH2CH2O or CH2CH2 S(O)m, n denoting 1, 2, 3, 4 or 5, and m being 0, 1 or 2; Ar is aryl which is unsubstituted or bears from one to five substituents selected from the group consisting of C1-C6-alkyl, phenyl, halogen, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxyiminocarbyl, phenoxy, halophenoxy and benzyloxy, and the N-oxides and plant-tolerated acid addition salts thereof, and fungicides containing these compounds.
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公开(公告)号:AU7820991A
公开(公告)日:1991-12-12
申请号:AU7820991
申请日:1991-06-06
Applicant: BASF AG
Inventor: WAGNER OLIVER , ZIPPERER BERNHARD , GOETZ NORBERT , KEIL MICHAEL , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N43/40 , C07D213/26 , C07D213/30 , C07D213/48 , C07D213/50 , C07D213/53 , C07D213/06
Abstract: Beta-picoline derivs. (I) and their N-oxides and addn. salts are new. In (I), A = CR1R2; R1, R2 = H, 1-6C alkyl, 2-6C alkenyl or 2-6C alkynyl; or R1+R2 = 2-6C n-alkylene; B = CH2, CHOR3, CHR4 or C=NOR5; R3 = H, 1-6C alkyl, 1-6C haloalkyl, 3-8C cycloalkyl, 3-6C alkenyl, 2-6C acyl or phenyl, benzyl or benzoyl opt. mono-, di- or tri-substd. in the ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, halogen, cyano or nitro; R4 = H, F, Cl, Br or I; R5 = H, 1-6C alkyl, 1-6C haloalkyl, 3-7C cycloalkyl, 3-6C alkenyl or aryl-1-4C alkyl opt. mono-, di- or tri-substd. in the aryl ring by 1-4C alkyl, 1-4C alkoxy, 1-4C haloalkyl, halogen, cyano or nitro; Ar = phenyl or naphthyl opt. mono-, di- or tri-substd. by halogen, 1-6C alkyl, 1-4C alkoxy, 1-4C haloalkyl, 1-4C haloalkoxy, phenyl, phenoxy, halophenyl, halophenoxy or benzyloxy; except 1-phenyl-3-(3-pyridyl) propan-1-one (IA). The use of cpd. (IA), which is known from J. Org. Chem. 43 (1978), 3396 and Arch. Pharm. 307 (1974), 550, for the control of fungi is also claimed. Further, intermediates (II) are claimed except where A = CH2 or CH(CH3). 3 Cpds. (I), e.g., 2-ethyl-1-(4-fluorophenyl) -2-(pyridyl-3-methyl)butan-1-ol, are specifically claimed.
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公开(公告)号:HU910709D0
公开(公告)日:1991-09-30
申请号:HU70991
申请日:1991-03-05
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N33/04 , A01N33/06 , A01N33/10 , A01N33/12 , C07C45/69 , C07C49/613 , C07C49/657 , C07C209/24 , C07C211/40 , C07C211/48 , C07C211/52 , C07C211/62 , C07C211/63 , C07C211/64 , C07C215/08 , C07C215/40 , C07C215/48 , C07C215/76 , C07C217/56 , C07C217/58 , C07C217/60 , C07C217/82 , C07C217/84 , C07C255/58
Abstract: 4-(4-Tert.-butylphenyl)cyclohexylamines and their quaternary ammonium salts of the formulae in which R is hydrogen, alkyl or alkenyl, R is alkyl, haloalkyl, hydroxyalkyl, cycloalkyl, alkylcycloalkyl, bicycloalkyl, alkenyl, phenyl which is unsubstituted or optionally monosubstituted to trisubstituted or phenylalkyl which is unsubstituted or optionally monosubstituted to trisubstituted, and X is an acid anion which is tolerated by plants, and their acid addition salts which are tolerated by plants, and fungicides containing these compounds.
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公开(公告)号:NZ233547A
公开(公告)日:1991-09-25
申请号:NZ23354790
申请日:1990-05-03
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , SAUTER HUBERT , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N43/10 , A01N43/40 , C07D213/30 , C07D213/89 , C07D405/06 , C07D409/06
Abstract: Pyridines of the formula 1 where R1 is hydrogen, C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl or an acyl radical COR2; R2 is C1-C6-alkyl, C3-C6-alkenyl, C3-C6-alkynyl, C1-C6-haloalkyl or substituted or unsubstituted aryl; A is one of the groups where R3 and R4 are identical or differ and each is C1-C6-alkyl, with the proviso that R3 and R4 are not simultaneously methyl; R5 is one of the groups (CH2)n, CH2OCH2, CH2S(O)mCH2, CH2CH2O or CH2CH2 S(O)m, n denoting 1, 2, 3, 4 or 5, and m being 0, 1 or 2; Ar is aryl which is unsubstituted or bears from one to five substituents selected from the group consisting of C1-C6-alkyl, phenyl, halogen, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, C1-C6-alkoxyiminocarbyl, phenoxy, halophenoxy and benzyloxy, and the N-oxides and plant-tolerated acid addition salts thereof, and fungicides containing these compounds.
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公开(公告)号:AU611209B2
公开(公告)日:1991-06-06
申请号:AU2371288
申请日:1988-10-13
Applicant: BASF AG
Inventor: ZIPPERER BERNHARD , GOETZ NORBERT , BUSCHMANN ERNST , SPROESSER LINHARD , AMMERMANN EBERHARD , LORENZ GISELA
IPC: A01N43/40 , C07D213/30 , C07D213/89
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公开(公告)号:HUT55007A
公开(公告)日:1991-04-29
申请号:HU624990
申请日:1990-09-27
Applicant: BASF AG
Inventor: SEELE RAINER , ROHR WOLFGANG , ZIPPERER BERNHARD , KARBACH STEFAN , RUEB LOTHAR , AMMERMANN EBERHARD , LORENZ GISELA , RADEMACHER WILHELM , JUNG JOHANN
IPC: A01N43/50 , A01N43/653 , C07D233/56 , C07D233/60 , C07D249/08 , C07D401/06 , C07D401/14 , C07D405/06 , C07D405/14 , C07D521/00
Abstract: Vinylazoles of the general formula I I where R1 and R2 are alkyl, cycloalkyl, tetrahydropyranyl, pyridyl, naphthyl, biphenyl or phenyl, these radicals being substituted or unsubstituted, X is CH or N, and plant-tolerated acid addition salts and metal complexes thereof, and crop protection agents containing these compounds.
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