公开(公告)号：WO2014199348A2

公开(公告)日：2014-12-18

申请号：PCT/IB2014/062202

申请日：2014-06-13

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： FEYEN, Mathias ,  SPANNHOFF, Kirsten ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  BILGE, Yilmaz

CPC classification number: C07C1/20 ,  B01J29/049 ,  B01J29/061 ,  B01J29/7049 ,  B01J29/7057 ,  B01J29/76 ,  B01J29/7615 ,  B01J29/78 ,  B01J29/7815 ,  B01J29/89 ,  B01J29/90 ,  B01J37/0201 ,  B01J38/12 ,  B01J2229/183 ,  B01J2229/186 ,  C01B39/08 ,  C01B39/085 ,  C07C2529/70 ,  C07C2529/89 ,  Y02P20/584 ,  C07C11/167

Abstract: The present invention relates to a process for the preparation of butadiene comprising (i) providing a gas stream G- comprising ethanol; (ii) contacting the gas stream G- provided in (i) with a catalyst, thereby obtaining a gas stream G-2 comprising butadiene; wherein the catalyst comprises a crystalline material supporting one or more catalytically active metals M, as well as to the use of the crystalline material supporting one or more catalytically active metals M.

Abstract translation: 本发明涉及一种制备丁二烯的方法，包括（i）提供包含乙醇的气流G-; （ii）使（i）中提供的气流G-与催化剂接触，从而获得包含丁二烯的气流G-2; 其中所述催化剂包含支撑一种或多种催化活性金属M的结晶物质，以及支持一种或多种催化活性金属M的结晶物质的用途。

公开(公告)号：WO2014174416A2

公开(公告)日：2014-10-30

申请号：PCT/IB2014/060805

申请日：2014-04-17

Applicant: BASF SE ,  TOKYO INSTITUTE OF TECHNOLOGY ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MüLLER, Ulrich ,  MAURER, Stefan ,  BOHN, Martin Alexander ,  YILMAZ, Bilge ,  TATSUMI, Takashi ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  BAO, Xinhe ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi

CPC classification number: B01J29/90 ,  B01J29/7057 ,  B01J35/002 ,  B01J37/06 ,  B01J38/02 ,  B01J2229/16 ,  B01J2229/37 ,  C01B39/026 ,  C01B39/06 ,  C01B39/46 ,  Y02P20/584

Abstract: A method of dehydration of at least one compound (A) comprising, in the chain form, -at least one hydroxyl group and -at least one carbonyl functionality selected from the group consisting of aldehyde (CHO), ke- tone (CO) and carboxylic acid (COOH) and mixtures thereof,in the presence of at least one zeolite which is (a) obtainable from an organotemplate-free synthetic process and (b) isomorphously substituted comprising silicon, aluminum and at least one further metal wherein the at least one further metal is selected from the group consisting of the elements of Group 3 to 14 in Period 4 to 6and mixtures thereof.

Abstract translation: 至少一种化合物（A）的脱水方法，其以链形式包含至少一个羟基和至少一种选自醛（CHO），酮基（CO）和 羧酸（COOH）及其混合物，在至少一种沸石存在下，其是（a）可从无有机无模板的合成方法获得，和（b）同晶取代，包括硅，铝和至少一种其它金属，其中至少 另外一种金属选自第4至6期的第3至14族的元素及其混合物。

公开(公告)号：WO2013182974A1

公开(公告)日：2013-12-12

申请号：PCT/IB2013/054569

申请日：2013-06-03

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MÜLLER, Ulrich ,  RUETZ, Roger ,  BEIN, Thomas ,  MÖLLER, Karin

IPC: C01B39/04 ,  C01B39/48 ,  B01J29/50

CPC classification number: B01D53/9427 ,  B01D53/9418 ,  B01D2255/50 ,  B01D2258/012 ,  B01J29/7015 ,  B01J29/723 ,  B01J29/763 ,  B01J29/783 ,  B01J37/0018 ,  B01J2229/186 ,  C01B39/06 ,  C01B39/48 ,  C10G11/18 ,  C10G2300/405 ,  Y02C20/10 ,  Y02P20/153

Abstract: The present invention relates to a process for the preparation of a zeolitic material having a CHA-type framework structure comprising YO 2 and X 2 O 3 , wherein said process comprises the steps of: (1) providing a mixture comprising one or more sources for YO 2 , one or more sources for X 2 O 3 , and one or more tetraalkylammonium cation R 1 R 2 R 3 R 4 N + -containing compounds as structure directing agent; (2) crystallizing the mixture obtained in step (1) for obtaining a zeolitic material having a CHA-type framework structure; wherein Y is a tetravalent element and X is a trivalent element, wherein R 1 , R 2 , and R 3 independently from one another stand for alkyl, wherein R 4 stands for cycloalkyl, and wherein the mixture provided in step (1) does not contain any substantial amount of a source for Z 2 O 5 , wherein Z is P, as well as to zeolitic materials which may be obtained ac- cording to the inventive process and to their use.

Abstract translation: 本发明涉及一种制备具有包含YO 2和X 2 O 3的CHA型骨架结构的沸石材料的方法，其中所述方法包括以下步骤：（1）提供包含一种或多种YO 2， 更多的X2O3源和一种或多种四烷基铵阳离子R1R2R3R4N +的化合物作为结构导向剂; （2）使步骤（1）中得到的混合物结晶得到具有CHA型骨架结构的沸石材料; 其中Y是四价元素，X是三价元素，其中R1，R2和R3彼此独立地代表烷基，其中R4代表环烷基，并且其中步骤（1）中提供的混合物不含任何实质的量 的Z2O5的来源，其中Z是P，以及可以根据本发明方法获得的沸石材料及其用途。

公开(公告)号：WO2023073059A1

公开(公告)日：2023-05-04

申请号：PCT/EP2022/080004

申请日：2022-10-26

Applicant: BASF SE

Inventor： LANGE DE OLIVEIRA, Armin ,  HIEBER, Gisela ,  PILARSKI, Oliver ,  LOEBNITZ, Lisa ,  KOEPKE, Daniel ,  MEYER-KIRSCHNER, Julian ,  MUELLER, Christian ,  HAAG, Monica ,  SCHREIBER, Michael ,  FEYEN, Mathias ,  VITYUK, Artem D ,  KARWACKI, Lukasz ,  REESINK, Bernard

IPC: C10G45/12 ,  C10G45/10 ,  C10G45/06 ,  C10G25/00 ,  C10G45/36 ,  C10G45/40 ,  C10G45/48 ,  C10G45/52 ,  C10G45/54 ,  C10G65/06 ,  C10G65/08 ,  C10G1/10 ,  C10G1/00

Abstract: The present invention relates to a process for purifying a pyrolysis oil comprising providing a stream S0 comprising a pyrolysis oil, the pyrolysis oil comprising one or more halogenated organic compounds and one or more organic compounds comprising conjugated double bonds; subjecting the stream S0 to hydrogenation in at least one reaction zone Z1 containing a heterogeneous hydrogenation catalyst, obtaining a stream S1 being depleted, compared to S0, in the one or more organic compounds comprising conjugated double bonds; subjecting the stream S1 to dehalogenation in at least one dehalogenation zone Z2 downstream of Z1, obtaining a stream S2 being depleted, compared to S1, in the one or more halogenated organic compounds.

公开(公告)号：WO2019100947A1

公开(公告)日：2019-05-31

申请号：PCT/CN2018/114590

申请日：2018-11-08

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Yong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  MENG, Xiangju ,  PAN, Xiulian

IPC: C01B39/48 ,  B01J29/76

Abstract: Provided are a process for the preparation of an iron containing zeolitic material having an AEI framework structure using a quaternary phosphonium cation, as well as an iron containing zeolitic material per se as obtainable or obtained according to the process. Furthermore, an exhaust gas treatment system comprising the iron containing zeolitic material and the use of the iron containing zeolitic material as a catalyst are provided.

公开(公告)号：WO2018113566A1

公开(公告)日：2018-06-28

申请号：PCT/CN2017/115938

申请日：2017-12-13

Applicant: BASF SE ,  XIAO, Fengshou

Inventor： XIAO, Fengshou ,  MCGUIRE, Robert ,  FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  TOSHIYUKI, Yokoi ,  KOLB, Ute ,  MARLER, Bernd ,  SHI, Chuan ,  PAN, Xiulian ,  MENG, Xiangju ,  MAURER, Stefan ,  DAI, Yu ,  WANG, Yong ,  DE BAERDEMAEKER, Trees

IPC: C01B39/04 ,  B01J29/06

Abstract: A process for the preparation of a zeolitic material comprising YO 2 and X 2 O 3 in its framework structure is provided, wherein Y stands for a tetravalent element and X stands for a trivalent element. The process comprises steps of (1) preparing a mixture comprising one or more structure directing agents, seed crystals, and a first zeolitic material comprising YO 2 and X 2 O 3 in its framework structure, wherein the first zeolitic material has a framework structure selected from the group consisting of FAU-, GIS-, MOR-, and LTA-type framework structures, including mixtures of two or more thereof; (2) heating the mixture obtained in (1) for obtaining a second zeolitic material comprising YO 2 and X 2 O 3 in its framework structure, wherein the second zeolitic material obtained in (2) has a different type of framework structure than the first zeolitic material contained in the mixture obtained in (1); wherein the mixture prepared in (1) and heated in (2) contains 1000 wt.% or less of H 2 O based on 100 wt.% of YO 2 in the framework structure of the first zeolitic material. As well as a zeolitic material obtainable and/or obtained according to the process and its use are provided.

公开(公告)号：WO2014199349A2

公开(公告)日：2014-12-18

申请号：PCT/IB2014/062203

申请日：2014-06-13

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED ,  TOKYO INSTITUTE OF TECHNOLOGY

Inventor： FEYEN, Mathias ,  SPANNHOFF, Kirsten ,  MÜLLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  TATSUMI, Takashi ,  XIAO, Feng-Shou ,  TOSHIYUKI, Yokoi ,  BILGE, Yilmaz

CPC classification number: C07C1/20 ,  B01J23/80 ,  B01J23/94 ,  B01J38/02 ,  C07C2521/06 ,  C07C2521/14 ,  C07C2523/06 ,  C07C2523/72 ,  Y02P20/584 ,  C07C11/167

Abstract: The present invention relates to a catalyst for the preparation of butadiene comprising Hf and two or more further catalytically active metals M1 and M2, wherein the two or more fur- ther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2; as well as to a process for the preparation of butadiene comprising (i) providing a gas stream G-1 comprising ethanol; (ii) contacting the gas stream G-1 provided in (i) with theinventive catalyst, thereby obtaining a gas stream G-2 comprising butadiene; wherein the catalyst comprises Hf and two or more further catalytically active metals M and M2, wherein the twoor morefurther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2, as well as to the use of the catalyst comprises Hf and two or more further catalytically active 1 metals M1 and M2, wherein the twoor morefurther catalytically active metals M1 and M2 are selected from the group consisting of Zr, Zn, Cu and combinations of two or more thereof, and wherein M1 is different from M2.

Abstract translation: 本发明涉及一种用于制备丁二烯的催化剂，其包含Hf和两种或更多种其它催化活性金属M1和M2，其中两种或多种其它催化活性金属M1和M2选自Zr，Zn ，Cu及其两种或更多种的组合，并且其中M1不同于M2; 以及制备丁二烯的方法，包括（i）提供包含乙醇的气流G-1; （ii）使（i）中提供的气流G-1与所述催化剂接触，从而获得包含丁二烯的气流G-2; 其中所述催化剂包含Hf和两种或更多种其它催化活性金属M和M2，其中所述更多的另外的催化活性金属M1和M2选自Zr，Zn，Cu及其两种或更多种的组合，并且其中M1 与M2不同，以及催化剂的使用包括Hf和两种或更多种其它催化活性的金属M1和M2，其中所述更多的另外的催化活性金属M1和M2选自Zr，Zn， Cu及其两种或更多种的组合，并且其中M1不同于M2。

公开(公告)号：WO2014154509A1

公开(公告)日：2014-10-02

申请号：PCT/EP2014/055266

申请日：2014-03-17

Applicant: BASF SE

Inventor： FEYEN, Mathias ,  SCHAACK, Bernd Bastian ,  MÜLLER, Ulrich ,  HEIDEMANN, Thomas ,  WILL, Veronika ,  SENK, Rainer

IPC: B01J37/02 ,  B01J37/18 ,  B01J29/48 ,  C07C2/76 ,  C07C15/04

CPC classification number: C07C2/76 ,  B01J27/22 ,  B01J29/061 ,  B01J29/405 ,  B01J29/46 ,  B01J29/48 ,  B01J29/90 ,  B01J35/023 ,  B01J37/0018 ,  B01J37/0045 ,  B01J37/0205 ,  B01J38/02 ,  B01J38/10 ,  B01J2229/20 ,  B01J2229/32 ,  B01J2229/42 ,  C07C2521/08 ,  C07C2529/40 ,  C07C2529/46 ,  C07C2529/48 ,  C10G45/64 ,  C10G45/66 ,  C10G45/68 ,  C10G2400/30 ,  Y02P20/52 ,  Y02P20/584 ,  C07C15/04

Abstract: Verfahren zur Herstellung eines Katalysators für die Dehydroaromatisierung, dadurch gekennzeichnet, dass a) ein Katalysator, der ein Zeolith und mindestens ein katalytisch aktives Metalle enthält, b) mit einer Silicium enthaltenden Verbindung passiviert wird und c) anschließend gegebenenfalls calciniert wird.

Abstract translation: 一种制备用于脱氢芳构化的催化剂，其特征在于，a）一种催化剂，其包含沸石和至少一种催化活性金属的方法，b）的钝化用含硅化合物和c）随后煅烧，如果必要的话。

公开(公告)号：WO2020156506A1

公开(公告)日：2020-08-06

申请号：PCT/CN2020/074094

申请日：2020-01-31

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Yong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  MENG, Xiangju ,  PAN, Xiulian

IPC: B01J29/86 ,  B01J29/70 ,  C01B39/02 ,  C01B39/04

Abstract: A process for preparing a zeolitic material having framework type CHA and having a framework structure which comprises a tetravalent element Y, B, and O, comprising preparing a synthesis mixture comprising water, a source of the tetravalent element Y, a source of B, and a CHA framework structure directing agent, and heating the synthesis mixture to a temperature in the range of from 100 to 200°C and keeping the synthesis mixture at a temperature in this range under autogenous pressure, and subjecting the zeolitic material obtained to an acid treatment.

公开(公告)号：WO2019001380A1

公开(公告)日：2019-01-03

申请号：PCT/CN2018/092580

申请日：2018-06-25

Applicant: BASF SE ,  BASF (CHINA) COMPANY LIMITED

Inventor： FEYEN, Mathias ,  MUELLER, Ulrich ,  BAO, Xinhe ,  ZHANG, Weiping ,  DE VOS, Dirk ,  GIES, Hermann ,  XIAO, Feng-Shou ,  YOKOI, Toshiyuki ,  KOLB, Ute ,  MARLER, Bernd ,  WANG, Yong ,  DE BAERDEMAEKER, Trees ,  SHI, Chuan ,  PAN, Xiulian ,  MENG, Xiangju

IPC: C01B39/04 ,  C01B39/48 ,  B01D53/94 ,  B01J29/072

Abstract: A composition comprising a support material which comprises silicon carbide on the surface of which a zeolitic material of the AEI/CHA family is supported, wherein at least 99 weight-% of the framework structure of the zeolitic material consist of a tetravalent element Y which is one or more of Si, Ge, Ti, Sn and V; a trivalent element X which is one or more of Al, Ga, In, and B; O; and H.