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公开(公告)号：SG176838A1
公开(公告)日：2012-02-28
申请号：SG2011092467
申请日：2010-06-22
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号：CA2765894A1
公开(公告)日：2010-12-29
申请号：CA2765894
申请日：2010-06-22
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号：ES2980498T3
公开(公告)日：2024-10-01
申请号：ES19720574
申请日：2019-04-29
Applicant: BASF SE
Inventor： DETERING JUERGEN , TUERK HOLGER , GUTOWSKI KEITH E , WEBER HEIKE , TUERKOGLU GAZI
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公开(公告)号：CA2960541A1
公开(公告)日：2016-03-24
申请号：CA2960541
申请日：2015-07-29
Applicant: BASF SE
Inventor： CAIRES CHRISTOPHER C , HAWKER DUSTIN , GUTOWSKI KEITH E , BREFFA CATHERINE , ESPER CLAUDIA , GARCIA MARCOS ALEJANDRA , MILLER REBECCA L , SPANGENBERG OLIVER
Abstract: The present invention is directed towards a detergent composition comprising (a) in total in the range of from 4.0 % to 25.0 % by weight of at least one organic chelating agent selected from methyl glycine diacetic acid (MGDA), glutamic acid diacetic acid (GLDA),the alkali metal salts of methyl glycine diacetic acid (MGDA) and of glutamic acid diacetic acid (GLDA),referring to the total solids content of the respective detergent composition, and (b) at least one enzyme selected from proteases. Additionally, the present invention is directed towards the use of the inventive detergent composition for laundry care and for automatic dish washing, and to a process for manufacture of the inventive detergent compositions.
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公开(公告)号：ES2562104T3
公开(公告)日：2016-03-02
申请号：ES10726101
申请日：2010-06-24
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , CRANFILL DAVID
Abstract: Un procedimiento de formación de una composición de revestimiento, comprendiendo dicho procedimiento las etapas de: A. introducir un complejo organoborano-amina, un compuesto polimerizable por radicales y opcionalmente una amina sobre un sustrato para formar una composición de revestimiento; B. introducir dióxido de carbono en la composición de revestimiento en una relación molar de al menos 1:1 del dióxido de carbono a los grupos amina libres presentes en la composición de revestimiento; C. hacer reaccionar el dióxido de carbono y los grupos amina libres para formar in-situ un zwitterión carbámico y para disociar el complejo organoborano-amina formando de esta manera un radical; y D. polimerizar el compuesto polimerizable por radicales usando el radical, opcionalmente en ausencia de calentamiento externo, u opcionalmente a una temperatura de 20ºC a 30ºC.
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Patent Agency Ranking
公开(公告)号：AU2010264760B2
公开(公告)日：2014-10-23
申请号：AU2010264760
申请日：2010-06-22
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号：AU2010264760A1
公开(公告)日：2012-02-09
申请号：AU2010264760
申请日：2010-06-22
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , OHRBOM WALTER H , CRANFILL DAVID , CAMPBELL DONALD H
IPC: C09D4/00 , C08J3/24 , C08K5/00 , C08K5/55 , C09D133/08
Abstract: A method of curing a coating composition and a method of forming a cured coating on an automobile component are provided. The coating composition comprises a radical polymerizable compound and an organoborane-amine complex having an organoborane initiator, an amine blocking agent, and water. The method of curing the coating composition comprises the steps of combining the organoborane-amine complex, the radical polymerizable compound, and water to form the coating composition. Carbon dioxide is introduced into the coating composition or into a composition including at least one of the organoborane-amine complex, the radical polymerizable compound, and water prior to forming the coating composition. Carbonic acid is formed in situ within the coating composition through reaction of the water and carbon dioxide. The organoborane-amine complex is decomplexed with the carbonic acid thereby separating the organoborane initiator and the amine blocking agent. The radical polymerizable compound is polymerized using the organoborane initiator in the presence of oxygen.
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公开(公告)号：CA2765133A1
公开(公告)日：2010-12-29
申请号：CA2765133
申请日：2010-06-24
Applicant: BASF SE
Inventor： GUTOWSKI KEITH E , CRANFILL DAVID
Abstract: A method of dissociating an organoborane-amine complex in a coating composition is provided. The method includes the step of introducing the organoborane-amine complex, the radical polymerizable compound, and optionally an amine, onto a substrate to form the coating composition. The method also includes the step of introducing carbon dioxide into the coating composition in a molar ratio of at least 1 : 1 of the carbon dioxide to free amine groups present in the coating composition. More specifically, a carbamic zwitterion is formed in-situ from reaction of the carbon dioxide and the free amine groups. The formation of the carbamic zwitterion leads to dissociation of the organoborane-amine complex and formation of a radical. The radical is then used to polymerize the radical polymerizable compound.
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公开(公告)号：PL3788125T3
公开(公告)日：2024-07-22
申请号：PL19720574
申请日：2019-04-29
Applicant: BASF SE
Inventor： DETERING JUERGEN , TUERK HOLGER , GUTOWSKI KEITH E , WEBER HEIKE , TUERKOGLU GAZI
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公开(公告)号：AU2010264690B2
公开(公告)日：2015-12-24
申请号：AU2010264690
申请日：2010-06-24
Applicant: BASF SE
Inventor： CRANFILL DAVID , GUTOWSKI KEITH E
Abstract: A method of forming a cured coating composition on an automobile component is provided. The method utilizes a coating compound including a radical polymerizable compound and an organoborane initiator and includes the step of applying the coating composition to the automobile component. The organoborane initiator is complexed with a bi-functional noncyclic blocking agent that has a carbon backbone and two organoborane complexing moieties. The two moieties are different from each other and are selected from the group of an amine moiety, a thiol moiety, and a phosphine moiety. In addition, the two moieties are separated from each other by two to four carbon atoms to increase the nucleophilicity of the blocking agent towards the organoborane initiator. The organoborane initiator is decomplexed from the blocking agent thereby forming a radical that is used to polymerize the radical polymerizable compound and cure the coating composition on the automobile component.
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