Procedimiento para la preparación de elastómero termoplástico expandido

    公开(公告)号:ES2651851T3

    公开(公告)日:2018-01-30

    申请号:ES14786180

    申请日:2014-10-17

    Applicant: BASF SE

    Abstract: Procedimiento para la preparación de elastómero termoplástico expandido, que comprende las siguientes etapas: (a) adición de monómeros y/u oligómeros y dado el caso otros reactivos usados para preparación del elastómero termoplásticos, en una primera etapa de una máquina de procesamiento de polímeros, (b) mezcla de los monómeros y/u oligómeros así como los otros reactivos dado el caso añadidos y reacción de los monómeros y/u oligómeros hasta dar un fundido de polímero, en la primera etapa de la máquina de procesamiento de polímeros, (c) conducción del fundido de polímero a una segunda etapa de la máquina de procesamiento de polímeros y adición de un agente propelente físico así como dado el caso otros reactivos, para obtener un fundido de polímero que tiene agente propelente, (d) moldeo del fundido de polímero que tiene agente propelente hasta dar un elastómero termoplástico expandido.

    13.
    发明专利
    未知

    公开(公告)号:DE112006003193A5

    公开(公告)日:2009-05-07

    申请号:DE112006003193

    申请日:2006-12-05

    Applicant: BASF SE

    Abstract: Disclosed is a prepolymer based on the reaction of (a) diisocyanate with (b) polyether alcohol. The inventive prepolymer is characterized in that the (b) polyether alcohol is the product (i) of the reaction of isocyanate (ia) with polytetrahydrofuran (ib).

    14.
    发明专利
    未知

    公开(公告)号:AT416210T

    公开(公告)日:2008-12-15

    申请号:AT06743196

    申请日:2006-02-21

    Applicant: BASF SE

    Abstract: Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>, a tensile strength of >= 2 N/mm 2>, a breach extension of >= 200% and a tear resistance of >= 8 N/mm, where the cellular polyurethane elastomers are based on reaction of: (i) isocyanate groups of prepolymers based on methylenediphenyldiisocyanate and polyetherdiol; with (ii) cross linking components containing polyetheralcohol; diol with a molecular weight of 62-499 g/mol; water; and catalysts. Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>according to DIN EN ISO 845, a tensile strength of >= 2 N/mm 2>according to DIN EN ISO 1798, a breach extension of >= 200% according to DIN EN ISO 1798 and a tear resistance of >= 8 N/mm according to DIN ISO 34-1 B, where the cellular polyurethane elastomers are based on reaction of: (i) prepolymers exhibiting isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol with a molecular weight of 1500-3000 g/mol based on propylene oxide and/or ethyleneoxide; with (ii) cross linking components containing polyetheralcohol with a nominal functionality of 2-3 in relation to isocyanates and a molecular weight of 1500-6000 g/mol based on propylene oxide and/or ethyleneoxide; diol with a molecular weight of 62-499 g/mol; water; and catalysts, where the polyol exhibits an average molecular mass of smaller than 3900 g/mol, where the average polyol molecular mass (M(polyol)) is calculated by (M b11xm b11+...+M b1nxm b1n)xW p+(M b21xm b21+...+M b2nxm b2n)xW v/(m b11+...+m b1n)xW p+(m b21+...+m b2n)xW v, where M (polyol) is average polyol molecular mass in g/mol; M b11(and/or M b1n) is molecular mass of polyol b11 (and/or polyol b1n) in (i) in g/mol; m b11(and/or m b1n) is mass proportion of polyol b11 (and/or polyol b1n) in (i) in g/g; W pis mass proportion of (i) in the cylindrical molded article in g/g; M b21(and/or M b2n) is molecular mass of polyol b21 and/or (polyol b2n) in (ii) in g/mol; m b21(and/or m b2n) is mass proportion of polyol b21 (and/or polyol b2n) in (ii) in g/g; and W vis mass proportion of (ii) in the cylindrical molded article in g/g. Independent claims are included for: (1) automobile chassis containing shock absorbers, a hollow cylindrical molded bodies, which is placed on its piston rod; and (2) the preparation of (I).

    15.
    发明专利
    未知

    公开(公告)号:AT399805T

    公开(公告)日:2008-07-15

    申请号:AT06708423

    申请日:2006-02-21

    Applicant: BASF SE

    Abstract: Preparation of cylindrical molded bodies (I) based on cellular polyurethane elastomers with determined density, tensile strength, elongation and a tear resistance, comprises reaction of prepolymers (i) with cross linking components (ii) in a molded form, where (i) are isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol; and (ii) contains polyetheralcohol with a nominal functionality of 2-3; diol with a molecular weight of 62-499 g/mol; water; and catalysts. Preparation of cylindrical molded bodies (I) based on cellular polyurethane elastomers with a density of 350-900 kg/m 3> according to DIN EN ISO 1798, a tensile strength of >= 2 N/mm 2> according to DIN EN ISO 1798, elongation of >= 200% according to DIN EN ISO 1798 and a tear resistance of >= 8 N/mm according to DIN ISO 34-1 B, comprises reaction of prepolymers (i) with cross linking components (ii) in a molded form, where (i) are isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol with a molecular weight of 1500-3000 g/mol based on propylene oxide and/or ethyleneoxide; and (ii) contains polyetheralcohol with a nominal functionality of 2-3 in relation to isocyanates and a molecular weight of 1500-6000 g/mol based on propylene oxide and/or ethyleneoxide; diol with a molecular weight of 62-499 g/mol; water; and catalysts, where (i) and (ii) are filled in a molded form by means of a high pressure machine, which exhibits a mixing head, into which (i) and (ii) are mixed and obtained product amounts to 15-60 g/s.

    17.
    发明专利
    未知

    公开(公告)号:AT448260T

    公开(公告)日:2009-11-15

    申请号:AT06708694

    申请日:2006-03-08

    Applicant: BASF SE

    Abstract: A prepolymer having an NCO content of less than 10%, based on the reaction of (a) diisocyanate with (b) polyether alcohol, the (b) polyether alcohol comprising (b1) and (b2) and/or (b3) with the following meanings for (b1), (b2) and (b3): (b1) polytetrahydrofuran having a molecular weight of from 1800 to 2100 g/mol and (b2) polyether alcohol having a molecular weight of from 500 to 7000 g/mol, based on ethylene oxide and/or propylene oxide, and/or (b3) polytetrahydrofuran having a molecular weight of from 800 to 1200 g/mol.

    POLYURETHANELASTOMEREN
    18.
    发明专利

    公开(公告)号:DE502006002256D1

    公开(公告)日:2009-01-15

    申请号:DE502006002256

    申请日:2006-02-21

    Applicant: BASF SE

    Abstract: Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>, a tensile strength of >= 2 N/mm 2>, a breach extension of >= 200% and a tear resistance of >= 8 N/mm, where the cellular polyurethane elastomers are based on reaction of: (i) isocyanate groups of prepolymers based on methylenediphenyldiisocyanate and polyetherdiol; with (ii) cross linking components containing polyetheralcohol; diol with a molecular weight of 62-499 g/mol; water; and catalysts. Cylindrical molded bodies (I) comprises cellular polyurethane elastomers with a density of 300-900 kg/m 3>according to DIN EN ISO 845, a tensile strength of >= 2 N/mm 2>according to DIN EN ISO 1798, a breach extension of >= 200% according to DIN EN ISO 1798 and a tear resistance of >= 8 N/mm according to DIN ISO 34-1 B, where the cellular polyurethane elastomers are based on reaction of: (i) prepolymers exhibiting isocyanate groups based on methylenediphenyldiisocyanate and polyetherdiol with a molecular weight of 1500-3000 g/mol based on propylene oxide and/or ethyleneoxide; with (ii) cross linking components containing polyetheralcohol with a nominal functionality of 2-3 in relation to isocyanates and a molecular weight of 1500-6000 g/mol based on propylene oxide and/or ethyleneoxide; diol with a molecular weight of 62-499 g/mol; water; and catalysts, where the polyol exhibits an average molecular mass of smaller than 3900 g/mol, where the average polyol molecular mass (M(polyol)) is calculated by (M b11xm b11+...+M b1nxm b1n)xW p+(M b21xm b21+...+M b2nxm b2n)xW v/(m b11+...+m b1n)xW p+(m b21+...+m b2n)xW v, where M (polyol) is average polyol molecular mass in g/mol; M b11(and/or M b1n) is molecular mass of polyol b11 (and/or polyol b1n) in (i) in g/mol; m b11(and/or m b1n) is mass proportion of polyol b11 (and/or polyol b1n) in (i) in g/g; W pis mass proportion of (i) in the cylindrical molded article in g/g; M b21(and/or M b2n) is molecular mass of polyol b21 and/or (polyol b2n) in (ii) in g/mol; m b21(and/or m b2n) is mass proportion of polyol b21 (and/or polyol b2n) in (ii) in g/g; and W vis mass proportion of (ii) in the cylindrical molded article in g/g. Independent claims are included for: (1) automobile chassis containing shock absorbers, a hollow cylindrical molded bodies, which is placed on its piston rod; and (2) the preparation of (I).

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