COMPOSITE MATERIALS HAVING RED EMITTING PHOSPHORS

    公开(公告)号:CA3032757A1

    公开(公告)日:2018-02-15

    申请号:CA3032757

    申请日:2017-09-15

    Applicant: GEN ELECTRIC

    Abstract: A lighting apparatus includes an LED light source radiationally coupled to a composite material including a phosphor of formula (I) and a thermally conductive material dispersed in at least a portion of a binder material. The thermally conductive material includes a material selected from the group consisting of indium oxide, tin oxide, indium tin oxide, calcium oxide, barium oxide, strontium oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, diamond, graphene, polyethylene nanofibers, carbon nanotubes, silver metal nanoparticles, copper metal nanoparticles, gold metal nanoparticles, aluminum metal nanoparticles, boron nitride, silicon nitride, an alkali metal halide, calcium fluoride, magnesium fluoride, a compound of formula (II), and combinations thereof.

    FOSFOROS EMISORES DE COLOR ROJO ESTABLE.

    公开(公告)号:MX2017006661A

    公开(公告)日:2017-10-04

    申请号:MX2017006661

    申请日:2015-11-16

    Applicant: GEN ELECTRIC

    Abstract: Un proceso para sintetizar un fósforo dopado con Mn4+ incluye poner en contacto un precursor de la fórmula I, AX [MFY]:Mn4+ I a una temperatura elevada con un agente oxidante que contiene flúor en forma gaseosa para formar el fósforo dopado con Mn4+ de color estable; en donde A es Li, Na, K, Rb, Cs, o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, o una combinación de los mismos; x es el valor absoluto de la carga del ion [MFY]; y es 5, 6 o 7; y la cantidad de Mn va desde aproximadamente 0.9 % en peso a aproximadamente 4 % en peso, con base en el peso total.

    FOSFOROS EMISORES DE ROJO Y DISPOSITIVOS ASOCIADOS.

    公开(公告)号:MX2016016392A

    公开(公告)日:2017-05-01

    申请号:MX2016016392

    申请日:2015-06-12

    Applicant: GEN ELECTRIC

    Abstract: Un procedimiento para sintetizar un fósforo dopado con manganeso (Mn4+) que incluye moler partículas de un precursor de fósforo de la fórmula I, y poner en contacto las partículas molidas con un agente oxidante que contiene flúor a una temperatura elevada Ax[MFy]:Mn4+ .....(I) en donde A es Li, Na, K, Rb, Cs, o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, o una combinación de los mismos; x es el valor absoluto de la carga del ion de [MFy]; y es 5, 6 o 7.

    COLOR STABLE RED-EMITTING PHOSPHORS

    公开(公告)号:CA2967642A1

    公开(公告)日:2016-05-26

    申请号:CA2967642

    申请日:2015-11-16

    Applicant: GEN ELECTRIC

    Abstract: A process for synthesizing a Mn doped phosphor includes contacting a precursor of formula I, Ax [MFy]:Mn4+ I at an elevated temperature with a fluorine-containing oxidizing agent in gaseous form to form the color stable Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and amount of Mn ranges from about 0.9 wt% to about 4 wt%, based on total weight.

    LED PACKAGE WITH RED-EMITTING PHOSPHORS

    公开(公告)号:CA2929037A1

    公开(公告)日:2015-05-14

    申请号:CA2929037

    申请日:2014-09-26

    Applicant: GEN ELECTRIC

    Abstract: A process for fabricating an LED lighting apparatus comprising a color stable Mn4+ doped phosphor of formula I includes forming on a surface of an LED chip a polymer composite layer comprising a first and a second population of particles of the phosphor of formula I having a graded composition varying in manganese concentration across a thickness thereof; Ax (M, Mn) Fy (I) wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7. The first population of particles has a lower manganese concentration than the second population of particles, and the manganese concentration in the polymer composite layer ranges from a minimum value in a region of the polymer composite layer proximate to the LED chip to a maximum value in a region opposite to the LED chip.

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