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公开(公告)号:CA2951381A1
公开(公告)日:2015-12-17
申请号:CA2951381
申请日:2015-06-09
Applicant: GEN ELECTRIC
Inventor: SETLUR ANAUNT ACHYUT , WEAVER STANTON EARL , GORCZYCA THOMAS BERT , CHOWDHURY ASHFAQUL ISLAM , MURPHY JAMES EDWARD , GARCIA FLORENCIO
Abstract: A process for fabricating a LED lighting apparatus includes disposing a composite coating on a surafce of a LED chip, The composite coating comprises a first composite layer having a manganese doped phosphor of formula I and a first binder and a second composite layer comprising a second phosphor composition and a second binder. The first binder, the second binder or both include a poIy(meth)acrylate. Ax [MFy]:Mn4+.......... (I), wherein A is Li, Na. K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, AL Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7.
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公开(公告)号:AU2014239197A1
公开(公告)日:2015-10-01
申请号:AU2014239197
申请日:2014-03-14
Applicant: GEN ELECTRIC
Inventor: MURPHY JAMES EDWARD , NAMMALWAR PRASANTH KUMAR , KARKADA NAGAVENI , LYONS ROBERT JOSEPH , CHOWDHURY ASHFAQUL ISLAM , SETLUR ANANT ACHYUT , GARCIA FLORENCIO , BEERS WILLIAM WINDER , DU FANGMING
IPC: C09K11/61
Abstract: A process for synthesizing a color stable Mn
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公开(公告)号:CA2934249C
公开(公告)日:2022-11-01
申请号:CA2934249
申请日:2014-12-16
Applicant: GEN ELECTRIC
Inventor: SETLUR ANANT ACHYUT , LYONS ROBERT JOSEPH , NAMMALWAR PRASANTH KUMAR , HANUMANTHA RAVIKUMAR , MURPHY JAMES EDWARD , GARCIA FLORENCIO
Abstract: A phosphor composition is derived from combining K2SiF6:Mn4+ in solid form with a saturated solution of a manganese-free complex fluoride including a composition of formula (I): A3[MF6], where A is selected from Na, K, Rb, and combinations thereof; and M is selected from Al, Ga, In, Sc, Y, Gd, and combinations thereof. The composition of formula (I):A3[MF6] has a water solubility lower than a water solubility of K2SiF6. A lighting apparatus including the phosphor composition is also provided.
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公开(公告)号:CA3032757A1
公开(公告)日:2018-02-15
申请号:CA3032757
申请日:2017-09-15
Applicant: GEN ELECTRIC
Abstract: A lighting apparatus includes an LED light source radiationally coupled to a composite material including a phosphor of formula (I) and a thermally conductive material dispersed in at least a portion of a binder material. The thermally conductive material includes a material selected from the group consisting of indium oxide, tin oxide, indium tin oxide, calcium oxide, barium oxide, strontium oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, diamond, graphene, polyethylene nanofibers, carbon nanotubes, silver metal nanoparticles, copper metal nanoparticles, gold metal nanoparticles, aluminum metal nanoparticles, boron nitride, silicon nitride, an alkali metal halide, calcium fluoride, magnesium fluoride, a compound of formula (II), and combinations thereof.
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公开(公告)号:MX2016016390A
公开(公告)日:2017-10-12
申请号:MX2016016390
申请日:2015-06-09
Applicant: GEN ELECTRIC
Inventor: MURPHY JAMES EDWARD , SETLUR ANANT ACHYUT , CHOWDHURY ASHFAQUL ISLAM , GARCIA FLORENCIO , SRINIVAS PRASAD SISTA
Abstract: Un proceso para sintetizar un fósforo activado por Mn4+ el proceso comprende poner en contacto un precursor de fórmula I, Ax(M1-z, Mnz)Fy I a una temperatura elevada con un agente oxidante que contiene flúor en forma gaseosa para formar el fósforo activado por Mn4+; en donde A es Li, Na, K, Rb, Cs, o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd o una combinación de los mismos; x es el valor absoluto de la carga del ion [MFy]; y es 5, 6 o 7; y 0.03=z?0.10.
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公开(公告)号:MX2017006661A
公开(公告)日:2017-10-04
申请号:MX2017006661
申请日:2015-11-16
Applicant: GEN ELECTRIC
Inventor: MURPHY JAMES EDWARD , SETLUR ANANT ACHYUT , CHOWDHURY ASHFAQUL ISLAM , GARCIA FLORENCIO , SRINIVAS PRASAD SISTA
IPC: C09K11/61
Abstract: Un proceso para sintetizar un fósforo dopado con Mn4+ incluye poner en contacto un precursor de la fórmula I, AX [MFY]:Mn4+ I a una temperatura elevada con un agente oxidante que contiene flúor en forma gaseosa para formar el fósforo dopado con Mn4+ de color estable; en donde A es Li, Na, K, Rb, Cs, o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, o una combinación de los mismos; x es el valor absoluto de la carga del ion [MFY]; y es 5, 6 o 7; y la cantidad de Mn va desde aproximadamente 0.9 % en peso a aproximadamente 4 % en peso, con base en el peso total.
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公开(公告)号:MX2016016392A
公开(公告)日:2017-05-01
申请号:MX2016016392
申请日:2015-06-12
Applicant: GEN ELECTRIC
Inventor: MURPHY JAMES EDWARD , SETLUR ANANT ACHYUT , GARCIA FLORENCIO , SRINIVAS PRASAD SISTA
IPC: C09K11/61
Abstract: Un procedimiento para sintetizar un fósforo dopado con manganeso (Mn4+) que incluye moler partículas de un precursor de fósforo de la fórmula I, y poner en contacto las partículas molidas con un agente oxidante que contiene flúor a una temperatura elevada Ax[MFy]:Mn4+ .....(I) en donde A es Li, Na, K, Rb, Cs, o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, o una combinación de los mismos; x es el valor absoluto de la carga del ion de [MFy]; y es 5, 6 o 7.
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公开(公告)号:MX2015012735A
公开(公告)日:2016-05-31
申请号:MX2015012735
申请日:2014-03-14
Applicant: GEN ELECTRIC
Inventor: LYONS ROBERT JOSEPH , MURPHY JAMES EDWARD , SETLUR ANANT ACHYUT , NAMMALWAR PRASANTH KUMAR , KARKADA NAGAVENI , CHOWDHURY ASHFAQUL ISLAM , GARCIA FLORENCIO , BEERS WILLIAM WINDER , DU FANGMING
IPC: C09K11/61
Abstract: Un proceso para sintetizar un fósforo dopado con Mn4+ de color estable incluye poner en contacto un precursor de la fórmula I, en forma gaseosa a una temperatura elevada con un agente de oxidación con contenido de flúor para formar el fósforo dopado con Mn4+ de color estable Ax[MFy]:Mn4+ (I), en donde A es Li, Na, K, Rb, Cs, NR4 o una combinación de los mismos; M es Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd o una combinación de los mismos; R es H, alquilo inferior o una combinación de los mismos; x es el valor absoluto de la carga del ión [MFy]; y y es5,6o7.
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公开(公告)号:CA2967642A1
公开(公告)日:2016-05-26
申请号:CA2967642
申请日:2015-11-16
Applicant: GEN ELECTRIC
Inventor: MURPHY JAMES EDWARD , GARCIA FLORENCIO , CHOWDHURY ASHFAQUL ISLAM , SISTA SRINIVAS PRASAD , SETLUR ANANT ACHYUT
Abstract: A process for synthesizing a Mn doped phosphor includes contacting a precursor of formula I, Ax [MFy]:Mn4+ I at an elevated temperature with a fluorine-containing oxidizing agent in gaseous form to form the color stable Mn4+ doped phosphor; wherein A is Li, Na, K, Rb, Cs, or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; y is 5, 6 or 7; and amount of Mn ranges from about 0.9 wt% to about 4 wt%, based on total weight.
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公开(公告)号:CA2929037A1
公开(公告)日:2015-05-14
申请号:CA2929037
申请日:2014-09-26
Applicant: GEN ELECTRIC
Inventor: SETLUR ANANT ACHYUT , MURPHY JAMES EDWARD , GARCIA FLORENCIO
Abstract: A process for fabricating an LED lighting apparatus comprising a color stable Mn4+ doped phosphor of formula I includes forming on a surface of an LED chip a polymer composite layer comprising a first and a second population of particles of the phosphor of formula I having a graded composition varying in manganese concentration across a thickness thereof; Ax (M, Mn) Fy (I) wherein A is Li, Na, K, Rb, Cs, NR4 or a combination thereof; M is Si, Ge, Sn, Ti, Zr, Al, Ga, In, Sc, Hf, Y, La, Nb, Ta, Bi, Gd, or a combination thereof; R is H, lower alkyl, or a combination thereof; x is the absolute value of the charge of the [MFy] ion; and y is 5, 6 or 7. The first population of particles has a lower manganese concentration than the second population of particles, and the manganese concentration in the polymer composite layer ranges from a minimum value in a region of the polymer composite layer proximate to the LED chip to a maximum value in a region opposite to the LED chip.
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