Process for preparing a poly-1-olefin

    公开(公告)号:SG52626A1

    公开(公告)日:1998-09-28

    申请号:SG1996006996

    申请日:1994-02-24

    Applicant: HOECHST AG

    Abstract: Bead-form polymers can be obtained in the polymerisation of alpha-olefins by using a highly active, spherical Ziegler catalyst based on a dialkylmagnesium compound. A further advantage of the novel catalyst is the high catalyst activity, meaning that only very small amounts of the catalyst are necessary for the polymerisation. The residual content of titanium and/or zirconium in the polymers prepared according to the invention is less than 10 ppm. Its very good hydrogen sensitivity means that the catalyst is particularly suitable in two-step processes for the preparation of polymers having a broad, bimodal molecular weight distribution. The replacement of sulphur-containing electron donors, such as diethyl sulphite, by alcohols, such as ethanol, results in lower odour nuisance and a broadened range of possible applications of the polymer. The spherical shape of the particles and the consequent very good flow properties of the polymers and copolymers mean considerable simplification and advantages during handling, drying and processing.

    Polyethylene molding composition
    18.
    发明专利

    公开(公告)号:SG52612A1

    公开(公告)日:1998-09-28

    申请号:SG1996006722

    申请日:1992-06-04

    Applicant: HOECHST AG

    Abstract: A polyethylene moulding composition which comprises from 50 to 80% by weight of a HD polyethylene having a very broad bimodal molecular weight distribution and from 20 to 50% by weight of an LLD polyethylene or LD polyethylene, gives pipes, sheets and films having very good long-term and low-temperature properties.

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