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公开(公告)号:ZA9501321B
公开(公告)日:1995-10-23
申请号:ZA9501321
申请日:1995-02-17
Applicant: HOECHST AG
Inventor: GAA KARL , NOWY GUENTER , SCHMAILZL GEORG
IPC: C07D498/10 , C07D519/00 , C08G73/06 , C07D , C08G , C08K , C08L , C09K
CPC classification number: C07D498/10 , C07D519/00 , C08G73/06 , C08G73/0688
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公开(公告)号:PL307323A1
公开(公告)日:1995-08-21
申请号:PL30732395
申请日:1995-02-17
Applicant: HOECHST AG
Inventor: GAA KARL , NOWY GUENTER , SCHMAILZL GEORG
IPC: C07D498/10 , C07D519/00 , C08G73/06 , C07D491/12
Abstract: The prodn. of polyalkyl-1-oxa-diazaspirodecane cpds. of formula (I) comprises reacting a cpd. of formula (VI) with an epihalohydrin of formula (V) in the mole ratio of (1:1)-(1:10), in organic solvent and in the presence of alkali hydroxide (AOH) as the soln. catalyst and then (for n > 1) heating the resulting epoxide (VI) at 100-240 degrees C. The AOH consists of 1-20 moles solid alkali metal hydroxide or a mixt. thereof with water in the wt. ratio of (1:9)-(9:1) and the solvent comprises alcohol(s) and opt. an inert organic solvent. n = 1-50; Y = a gp. of formula (II) or (III) (indices 3 and 4 indicate ring positions in I, with the N atom attached to a CH2 gp. in the propylene-2-oxy gp.); R = H, O, NO gp., 1-12 C alkyl or alkoxy, allyl, 1-22 C acyl, benzyl or 3-12 C cycloalkoxy; R = R = H or 1-5 C alkyl and R = Me; or R = H or 1-5 C alkyl and R + R + attached C atoms = 5-6 C cycloalkyl gp. or a gp. of formula; R , R = H, 1-30 C alkyl or 7-12 C phenylalkyl (opt. substd. with Cl or 1-4 C alkyl); or R + R + attached C atom = 5-18 C cycloalkyl (opt. substd. with up to four 1-4 C alkyl gps.) or a gp. of formula; if n = 1, R is absent, i.e. the O and the terminal CH2 gp. form an oxirane ring; if n > 1, R = H or 1-22 C acyl; or R may be absent in the terminal monomer unit with an oxirane ring present as above; HX = acid residue or a salt thereof with a protic acid; Hal = Cl, Br or I.
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公开(公告)号:HU209722B
公开(公告)日:1994-10-28
申请号:HU354891
申请日:1991-11-13
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , SCHMAILZL GEORG
IPC: C08F6/02 , C08K5/04 , C08K5/06 , C08L101/00 , C08L23/02
Abstract: In synthetic moulding compositions, especially those based on olefin polymers, which contain phenolic stabilisers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced when they contain triglycerol or ditrimethylolpropane as catalyst inactivators.
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公开(公告)号:AU626086B2
公开(公告)日:1992-07-23
申请号:AU5711490
申请日:1990-06-15
Applicant: HOECHST AG
Inventor: SCHMAILZL GEORG , PFAHLER GERHARD , NOWY GUNTHER
IPC: C07D498/10 , C07D519/00 , C08G73/06 , C08K5/34 , C08K5/3432 , C08K5/3435 , C08K5/35 , C08K5/353 , C08L23/00 , C08L87/00 , C08L101/00 , C08K5/3412 , C08L23/02 , C08L25/04 , C08L27/06 , C08L33/06 , C07D498/20 , C07D498/22
Abstract: Novel polymeric polyalkyl-1-oxa-diazaspirodecanes of the formula I (I) are very effective stabilizers for natural any synthetic polymers. They have very low volatility, high migration resistance and high thermal stability.
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公开(公告)号:NO304075B1
公开(公告)日:1998-10-19
申请号:NO914461
申请日:1991-11-14
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , SCHMAILZL GEORG
IPC: C08F6/02 , C08K5/04 , C08K5/06 , C08L101/00
Abstract: In synthetic moulding compositions, especially those based on olefin polymers, which contain phenolic stabilisers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced when they contain triglycerol or ditrimethylolpropane as catalyst inactivators.
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公开(公告)号:ZA9109019B
公开(公告)日:1992-07-29
申请号:ZA9109019
申请日:1991-11-14
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , GERHARD PFAHLER , SCHMAILZL GEORG , GEORG SCHMAILZL
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公开(公告)号:HUT59434A
公开(公告)日:1992-05-28
申请号:HU354891
申请日:1991-11-13
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , SCHMAILZL GEORG
IPC: C08F6/02 , C08K5/04 , C08K5/06 , C08L101/00 , C08L23/02
Abstract: In synthetic moulding compositions, especially those based on olefin polymers, which contain phenolic stabilisers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced when they contain triglycerol or ditrimethylolpropane as catalyst inactivators.
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公开(公告)号:NO914461L
公开(公告)日:1992-05-18
申请号:NO914461
申请日:1991-11-14
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , SCHMAILZL GEORG
IPC: C08F6/02 , C08K5/04 , C08K5/06 , C08L101/00 , C08L23/02
Abstract: In synthetic moulding compositions, especially those based on olefin polymers, which contain phenolic stabilisers and metal ions as catalyst residues, the discoloration at the processing temperature is reduced when they contain triglycerol or ditrimethylolpropane as catalyst inactivators.
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公开(公告)号:NO914461A
公开(公告)日:1992-05-18
申请号:NO914461
申请日:1991-11-14
Applicant: HOECHST AG
Inventor: PFAHLER GERHARD , SCHMAILZL GEORG
IPC: C08F6/02 , C08K5/04 , C08K5/06 , C08L101/00 , C08L23/02
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公开(公告)号:ZA916017B
公开(公告)日:1992-04-29
申请号:ZA916017
申请日:1991-07-31
Applicant: HOECHST AG
Inventor: SCHMAILZL GEORG , GEORG SCHMAILZL
IPC: B01J31/02 , C07D221/00 , C07D263/00 , C07D498/10 , C07D498/20 , C07D519/00 , C08K5/35 , C07D
Abstract: The invention relates to an environment-friendly process for the preparation of compounds of the following formula in which R and R are preferably H or alkyl, R and R are preferably alkyl or cycloalkyl, R and R are preferably hydrogen or methyl, and R is, in particular, alkyl. In this process, the additional use of a phase transfer catalyst can be dispensed with without suffering yield losses.
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