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    PROCESS FOR PRODUCING POLYALKYL-1-OXA-DIAZA-SPIRODECANE DERIVATIVES
    3.
    发明专利
    PROCESS FOR PRODUCING POLYALKYL-1-OXA-DIAZA-SPIRODECANE DERIVATIVES 未知

    公开(公告)号：HUT71255A

    公开(公告)日：1995-11-28

    申请号：HU9500472

    申请日：1995-02-17

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  NOWY GUENTER ,  SCHMAILZL GEORG

    IPC: C07D498/10 ,  C07D519/00 ,  C08G73/06

    Abstract: The prodn. of polyalkyl-1-oxa-diazaspirodecane cpds. of formula (I) comprises reacting a cpd. of formula (VI) with an epihalohydrin of formula (V) in the mole ratio of (1:1)-(1:10), in organic solvent and in the presence of alkali hydroxide (AOH) as the soln. catalyst and then (for n > 1) heating the resulting epoxide (VI) at 100-240 degrees C. The AOH consists of 1-20 moles solid alkali metal hydroxide or a mixt. thereof with water in the wt. ratio of (1:9)-(9:1) and the solvent comprises alcohol(s) and opt. an inert organic solvent. n = 1-50; Y = a gp. of formula (II) or (III) (indices 3 and 4 indicate ring positions in I, with the N atom attached to a CH2 gp. in the propylene-2-oxy gp.); R = H, O, NO gp., 1-12 C alkyl or alkoxy, allyl, 1-22 C acyl, benzyl or 3-12 C cycloalkoxy; R = R = H or 1-5 C alkyl and R = Me; or R = H or 1-5 C alkyl and R + R + attached C atoms = 5-6 C cycloalkyl gp. or a gp. of formula; R , R = H, 1-30 C alkyl or 7-12 C phenylalkyl (opt. substd. with Cl or 1-4 C alkyl); or R + R + attached C atom = 5-18 C cycloalkyl (opt. substd. with up to four 1-4 C alkyl gps.) or a gp. of formula; if n = 1, R is absent, i.e. the O and the terminal CH2 gp. form an oxirane ring; if n > 1, R = H or 1-22 C acyl; or R may be absent in the terminal monomer unit with an oxirane ring present as above; HX = acid residue or a salt thereof with a protic acid; Hal = Cl, Br or I.

    Storage-stable plastics additives
    4.
    发明专利
    Storage-stable plastics additives 未知

    公开(公告)号：ZA969283B

    公开(公告)日：1997-05-06

    申请号：ZA969283

    申请日：1996-11-05

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  NOWY GUENTER ,  PFAHLER GERHARD ,  ZAEH MATTHIAS

    IPC: C08J3/20 ,  B29B9/00 ,  B29B9/10 ,  C08J3/12 ,  C08J3/18 ,  C08K5/00 ,  C09C1/00 ,  C08K ,  C08J ,  B29B

    Abstract: Plastic additives (I), obtained by cooling a mixture of (a) 99.9-10 wt% additive material in the molten state and (b) 0.1-90 wt% additive material in the crystalline state in a moulding process. Preferably, mixtures (I) contain 99.5-25 (preferably 90-30, especially preferred 70-50) wt% (a) and 0.5-75 (preferably 10-70, especially preferred 30-50) wt% (b). Suitable additives comprise UV stabilisers, antioxidants, thermal stabilisers, lubricants, antistatics, coupling agents, compatibilisers, dispersants, acid interceptors, metal deactivators, peroxide decomposing agents, processing stabilisers, nucleating agents, optical brighteners, slip additives, anti-dew additives and fire retardants.

    PROCESS FOR THE PREPARATION OF POLYALKYL-1-OXA- DIAZASPIRODECANE COMPOUNDS
    6.
    发明专利
    PROCESS FOR THE PREPARATION OF POLYALKYL-1-OXA- DIAZASPIRODECANE COMPOUNDS 未知

    公开(公告)号：CA2142779A1

    公开(公告)日：1995-08-20

    申请号：CA2142779

    申请日：1995-02-17

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  NOWY GUENTER ,  SCHMAILZL GEORG

    IPC: C07D498/10 ,  C07D519/00 ,  C08G73/06 ,  C07D498/20

    Abstract: The invention relates to a process for the preparation of polyalkyl-1-oxa-diazaspirodecane compounds, which can be used as highly active light stabilizers for polymers. The action is carried out in a solvent mixture of at least one alcohol and if appropriate an inert organic solvent in the presence of solid alkali metal hydroxide or a corresponding amount of a mixture of solid alkali metal hydroxide and water as the sole catalyst. The process offers the advantage that, by using a solvent mixture and dispensing with a phase transfer catalyst, a higher rate of reaction and therefore higher product quality with the same yield are achieved. By dispensing with a phase transfer catalyst, which remains in the waste water and must be disposed of expensively, and by the reusability of the solvent mixture, the process is more environmentfriendly and more economical than processes known to date.

    PROCESS FOR PRODUCING POLYALKYL-1-OXA-DIAZA-SPIRODECANE DERIVATIVES
    7.
    发明专利
    PROCESS FOR PRODUCING POLYALKYL-1-OXA-DIAZA-SPIRODECANE DERIVATIVES 未知

    公开(公告)号：HU214962B

    公开(公告)日：1998-08-28

    申请号：HU9500472

    申请日：1995-02-17

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  NOWY GUENTER ,  SCHMAILZL GEORG

    IPC: C07D498/10 ,  C07D519/00 ,  C08G73/06

    Abstract: The prodn. of polyalkyl-1-oxa-diazaspirodecane cpds. of formula (I) comprises reacting a cpd. of formula (VI) with an epihalohydrin of formula (V) in the mole ratio of (1:1)-(1:10), in organic solvent and in the presence of alkali hydroxide (AOH) as the soln. catalyst and then (for n > 1) heating the resulting epoxide (VI) at 100-240 degrees C. The AOH consists of 1-20 moles solid alkali metal hydroxide or a mixt. thereof with water in the wt. ratio of (1:9)-(9:1) and the solvent comprises alcohol(s) and opt. an inert organic solvent. n = 1-50; Y = a gp. of formula (II) or (III) (indices 3 and 4 indicate ring positions in I, with the N atom attached to a CH2 gp. in the propylene-2-oxy gp.); R = H, O, NO gp., 1-12 C alkyl or alkoxy, allyl, 1-22 C acyl, benzyl or 3-12 C cycloalkoxy; R = R = H or 1-5 C alkyl and R = Me; or R = H or 1-5 C alkyl and R + R + attached C atoms = 5-6 C cycloalkyl gp. or a gp. of formula; R , R = H, 1-30 C alkyl or 7-12 C phenylalkyl (opt. substd. with Cl or 1-4 C alkyl); or R + R + attached C atom = 5-18 C cycloalkyl (opt. substd. with up to four 1-4 C alkyl gps.) or a gp. of formula; if n = 1, R is absent, i.e. the O and the terminal CH2 gp. form an oxirane ring; if n > 1, R = H or 1-22 C acyl; or R may be absent in the terminal monomer unit with an oxirane ring present as above; HX = acid residue or a salt thereof with a protic acid; Hal = Cl, Br or I.

    METHOD OF OBTAINING POLYALKYL-1-OXA-DIAZASPIRODECANE COMPOUNDS
    9.
    发明专利
    METHOD OF OBTAINING POLYALKYL-1-OXA-DIAZASPIRODECANE COMPOUNDS 未知

    公开(公告)号：PL307323A1

    公开(公告)日：1995-08-21

    申请号：PL30732395

    申请日：1995-02-17

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  NOWY GUENTER ,  SCHMAILZL GEORG

    IPC: C07D498/10 ,  C07D519/00 ,  C08G73/06 ,  C07D491/12

    Abstract: The prodn. of polyalkyl-1-oxa-diazaspirodecane cpds. of formula (I) comprises reacting a cpd. of formula (VI) with an epihalohydrin of formula (V) in the mole ratio of (1:1)-(1:10), in organic solvent and in the presence of alkali hydroxide (AOH) as the soln. catalyst and then (for n > 1) heating the resulting epoxide (VI) at 100-240 degrees C. The AOH consists of 1-20 moles solid alkali metal hydroxide or a mixt. thereof with water in the wt. ratio of (1:9)-(9:1) and the solvent comprises alcohol(s) and opt. an inert organic solvent. n = 1-50; Y = a gp. of formula (II) or (III) (indices 3 and 4 indicate ring positions in I, with the N atom attached to a CH2 gp. in the propylene-2-oxy gp.); R = H, O, NO gp., 1-12 C alkyl or alkoxy, allyl, 1-22 C acyl, benzyl or 3-12 C cycloalkoxy; R = R = H or 1-5 C alkyl and R = Me; or R = H or 1-5 C alkyl and R + R + attached C atoms = 5-6 C cycloalkyl gp. or a gp. of formula; R , R = H, 1-30 C alkyl or 7-12 C phenylalkyl (opt. substd. with Cl or 1-4 C alkyl); or R + R + attached C atom = 5-18 C cycloalkyl (opt. substd. with up to four 1-4 C alkyl gps.) or a gp. of formula; if n = 1, R is absent, i.e. the O and the terminal CH2 gp. form an oxirane ring; if n > 1, R = H or 1-22 C acyl; or R may be absent in the terminal monomer unit with an oxirane ring present as above; HX = acid residue or a salt thereof with a protic acid; Hal = Cl, Br or I.

    10.
    发明专利
    未知

    公开(公告)号：BR9605431A

    公开(公告)日：1998-08-11

    申请号：BR9605431

    申请日：1996-11-05

    Applicant: HOECHST AG

    Inventor： GAA KARL ,  PFAHLER GERHARD ,  ZAEH MATTHIAS ,  NOWY GUENTER

    IPC: C08J3/20 ,  B29B9/00 ,  B29B9/10 ,  C08J3/12 ,  C08J3/18 ,  C08K5/00 ,  C09C1/00

    Abstract: Plastic additives (I), obtained by cooling a mixture of (a) 99.9-10 wt% additive material in the molten state and (b) 0.1-90 wt% additive material in the crystalline state in a moulding process. Preferably, mixtures (I) contain 99.5-25 (preferably 90-30, especially preferred 70-50) wt% (a) and 0.5-75 (preferably 10-70, especially preferred 30-50) wt% (b). Suitable additives comprise UV stabilisers, antioxidants, thermal stabilisers, lubricants, antistatics, coupling agents, compatibilisers, dispersants, acid interceptors, metal deactivators, peroxide decomposing agents, processing stabilisers, nucleating agents, optical brighteners, slip additives, anti-dew additives and fire retardants.

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