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公开(公告)号：DE3752037D1
公开(公告)日：1997-04-30
申请号：DE3752037
申请日：1987-10-24
Applicant: KAO CORP
Inventor： YAMAUCHI MICHIHIDE , NAGAMORI HIROYUKI , WAKASA MASANOBU , ISHIKAWA ATSUSHI
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公开(公告)号：DE3780912D1
公开(公告)日：1992-09-10
申请号：DE3780912
申请日：1987-10-24
Applicant: KAO CORP
Inventor： YAMAUCHI MICHIHIDE , NAGAMORI HIROYUKI , WAKASA MASANOBU , ISHIKAWA ATSUSHI
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公开(公告)号：DE69804507T3
公开(公告)日：2006-03-16
申请号：DE69804507
申请日：1998-12-24
Applicant: KAO CORP
Inventor： OKUBO MAKOTO , ISHIKAWA ATSUSHI , KITAGAWA HIROSHI
Abstract: Microcellular polyurethane elastomer shoe sole components having exceptional physical properties may be prepared from isocyanate-terminated prepolymers derived from polyoxypropylene diols having a molecular weight of from about 2000 Da to 8000 Da, an unsaturation less than about 0.02 meq/g, and a random oxyethylene content of from about 5 to about 15 weight percent. The shoe sole components exhibit high tensile strength, elongation, resilience, and in addition have excellent tear strength, particularly 90° angle tear.
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公开(公告)号：ID28836A
公开(公告)日：2001-07-05
申请号：ID20002592
申请日：1999-06-21
Applicant: KAO CORP
Inventor： ITOI AKITO , HOSOKAWA KOEI , ISAYAMA YASUTOSHI , ISHIKAWA ATSUSHI
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公开(公告)号：JP2007238667A
公开(公告)日：2007-09-20
申请号：JP2006059428
申请日：2006-03-06
Inventor： ISHIKAWA ATSUSHI
IPC: C08G18/18 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a manufacturing method of a rigid polyurethane foam excellent in dimensional stability and adhesion and little in the generation of voids and the disorder of cells.
SOLUTION: The manufacturing method of the rigid polyurethane foam comprises reacting a polyol component and a polyisocyanate component in the presence of water using a polyuretahne manufacturing catalyst containing an amine compound represented by formula (I): (CH
3 )
2 NCH
2 CH
2 ACH
2 CHROH (I) and an amine compound represented by formula (II): (CH
3 )
2 N(CH
2 )
m B(CH
2 )
n NH
2 (II). In formula (I), A indicates an oxygen atom, -OCH
2 CH
2 O- group, -N(CH
3 )- group, -OCH
2 CH
2 N(CH
3 )- group or -N(CH
3 )CH
2 CH
2 N(CH
3 )- group and R indicates a hydrogen atom or a methyl group. In formula (II), B indicates an oxygen atom or a single bond provided that, if B is an oxygen atom, m and n indicate each independently an integer of 2-6 and, if B is a single bond, m and n indicate integers satisfying the relationship of m+n=2-8.
COPYRIGHT: (C)2007,JPO&INPITAbstract translation: 要解决的问题：提供尺寸稳定性和粘附性优异的刚性聚氨酯泡沫的制造方法，并且几乎没有空隙的产生和细胞的紊乱。 解决方案：硬质聚氨酯泡沫的制造方法包括使用含有由式（I）表示的胺化合物的聚脲制造催化剂在水存在下使多元醇组分和多异氰酸酯组分反应：（CH
3 < / SB>） NCH 2 CH 2 SBR 2 CH 2 OCH 2（CH 2） （II）：（CH 3 N（CH 2 ）B ） 名词 NH 2 （II）。 在式（I）中，A表示氧原子，-OCH 2 SB 2，-S（CH 3 SB）O-基团，-N（CH 3 SB 3） ，-OCH 2，CH 2，N（CH 3 SB 3） - 或-N（CH 3 SB 3）CH 2， SB> 2 N（CH 3 SB 3） - 基团，R表示氢原子或甲基。 在式（II）中，B表示氧原子或单键，条件是如果B是氧原子，则m和n各自独立地表示2-6的整数，并且如果B是单键，则m和n表示 满足m + n = 2-8的关系的整数。 版权所有（C）2007，JPO＆INPIT -
Patent Agency Ranking
公开(公告)号：JP2007197532A
公开(公告)日：2007-08-09
申请号：JP2006016301
申请日：2006-01-25
Inventor： ISHIKAWA ATSUSHI
IPC: C08G18/30 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a polyol mixture which is uniform and transparent, even when mixed with a large amount of water as a foaming agent, can save a complicated process for stirring and mixing the polyol mixture, when used for application at a site, can thereby enhance the production efficacy of polyurethane foam, can enhance reactivity on the production of the polyurethane foam, has hence excellent applicability, and can quickly produce the polyurethane foam, to provide a method for producing a polyurethane foam with the same, and to provide a heat-resistant material comprising the polyurethane foam. SOLUTION: This polyol mixture for producing the polyurethane foam comprises a polyol component, water in an amount of ≥4 pts.wt. per 100 pts.wt. of the polyol component, and a 10 to 24C fatty acid amine salt. The method for producing the polyurethane foam comprises reacting the polyol mixture with an isocyanate component. And a heat-resistant material comprising the polyurethane foam obtained by the production method. COPYRIGHT: (C)2007,JPO&INPIT
Abstract translation: 要解决的问题：为了提供均匀透明的多元醇混合物，即使当与作为发泡剂的大量水混合时，可以节省用于搅拌和混合多元醇混合物的复杂工艺，当用于应用时 在一个场合，可以提高聚氨酯泡沫的生产效率，可以提高聚氨酯泡沫的生产反应性，因此具有优异的适用性，并能快速生产聚氨酯泡沫，以提供一种生产聚氨酯泡沫的方法 并且提供包含聚氨酯泡沫的耐热材料。 解决方案：用于制备聚氨酯泡沫的多元醇混合物包括多元醇组分，重量为≥4重量份的水。 每100 pts.wt 的多元醇组分和10至24℃的脂肪酸胺盐。 制备聚氨酯泡沫的方法包括使多元醇混合物与异氰酸酯组分反应。 以及包含通过该制造方法获得的聚氨酯泡沫的耐热材料。 版权所有（C）2007，JPO＆INPIT
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公开(公告)号：JP2006045435A
公开(公告)日：2006-02-16
申请号：JP2004231296
申请日：2004-08-06
Inventor： ISHIKAWA ATSUSHI
IPC: C08G18/42 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a rigid polyurethane foam using a phthalic acid based polyester polyol as a polyol component, excellent in adhesiveness with an adherend such as a steel plate, concrete, a synthetic resin and the like even in the case using a hydrofluorocarbon as a foaming agent and having reduced voids.
SOLUTION: A manufacturing method of a rigid polyurethane foam comprises reacting a polyol component comprising a phthalic acid based polyester polyol having the hydroxy value of 150-550 mgKOH/g and an isocyanate component comprising an adipic acid based polyester polyol having the hydroxy value of 40-80 mgKOH/g under the presence of a foaming agent comprising the hydrofluorocarbon and catalysts, and the above manufacturing method can obtain the rigid polyurethane foam.
COPYRIGHT: (C)2006,JPO&NCIPIAbstract translation: 要解决的问题：为了提供一种使用邻苯二甲酸类聚酯多元醇作为多元醇成分的硬质聚氨酯泡沫塑料，即使在钢板，混凝土，合成树脂等中的被粘物也具有优异的粘合性 使用氢氟烃作为发泡剂并具有减小的空隙。 解决方案：硬质聚氨酯泡沫的制造方法包括使包含羟值为150-550mgKOH / g的邻苯二甲酸基聚酯多元醇的多元醇组分与包含具有羟基的己二酸基聚酯多元醇的异氰酸酯组分 在含有氢氟烃和催化剂的发泡剂的存在下，40-80mgKOH / g的值，以及上述制造方法可以获得硬质聚氨酯泡沫。 版权所有（C）2006，JPO＆NCIPI
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公开(公告)号：JP2005171047A
公开(公告)日：2005-06-30
申请号：JP2003411593
申请日：2003-12-10
Inventor： ISHIKAWA ATSUSHI , ISAYAMA YASUTOSHI
IPC: C08G18/20 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing polyurethane foam in which the amount of VOC (volatile organic compounds) generated from polyurethane foam on the basis of an amine-based catalyst is reduced even in a high-temperature state and fogging hardly occurs and which has excellent heat resistance, excellent hardness properties and small residual compressive strain.
SOLUTION: The method for producing a polyurethane foam comprises reacting a polyol component with an isocyanate component in the presence of a catalyst containing a compound represented by formula (I): (CH
3 )
2 N(CH
2 )
p OH (1) (p is an integer of 4-9) and a compound represented by formula (II) (R
1 is a 2 or 3C straight-chain or branched-chain aminoalkyl group or hydroxyalkyl group; R
2 is a hydrogen atom or a 1-4C straight-chain or branched-chain alkyl group) and a blowing agent. The polyurethane foam is obtained by the production method.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 要解决的问题：提供一种聚氨酯泡沫的制造方法，其中，即使在高温状态下，基于胺系催化剂的聚氨酯泡沫产生的VOC（挥发性有机化合物）的量也降低， 几乎不发生起雾，具有优异的耐热性，优异的硬度特性和较小的残余压缩应变。 解决方案：聚氨酯泡沫的制造方法包括在含有式（I）表示的化合物的催化剂存在下使多元醇组分与异氰酸酯组分反应：（CH 3 SB 3）SB （2）表示的化合物（Ⅱ）表示的化合物（式中，R 1，R 2，R 3，R 5， R
1 是2或3C直链或支链氨基烷基或羟烷基; R 2 SP 2是氢原子或1-4C直链或支链 链烷基）和发泡剂。 通过制造方法得到聚氨酯泡沫。 版权所有（C）2005，JPO＆NCIPI -
公开(公告)号：JP2005068172A
公开(公告)日：2005-03-17
申请号：JP2003208216
申请日：2003-08-21
Inventor： ISHIKAWA ATSUSHI , YAMASHITA OSAMU , HIRABAYASHI TADASHI
IPC: C08G18/20
Abstract: PROBLEM TO BE SOLVED: To provide a catalyst having a nitrogen-containing heterocyclic structure for manufacturing a polyurethane which exhibits excellent catalytic activities for both a reaction of a hydroxyl group of a polyol with an isocyanate group and a reaction of water with an isocyanate group and promotes the reaction of the polyol component with the isocyanate component, and a method for promptly manufacturing the polyurethane exhibiting excellent moldability using the catalyst for manufacturing the polyurethane.
SOLUTION: The catalyst for manufacturing the polyurethane comprises a heteroatom-containing cyclic compound bearing 2-6 nitrogen atoms and 0-2 oxygen atoms in the main chain of the molecule constituting the cyclic structure, where the total number of the nitrogen atom and the oxygen atom is 3-6. The method for manufacturing the polyurethane comprises reacting the polyol component with the isocyanate component in the presence of the catalyst for manufacturing the polyurethane.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 要解决的问题：提供具有用于制备聚氨酯的含氮杂环结构的催化剂，其对于多元醇的羟基与异氰酸酯基团的反应和水与 异氰酸酯基，促进多元醇成分与异氰酸酯成分的反应，以及使用该聚氨酯的制造用催化剂及时制造显示优异的成形性的聚氨酯的方法。 解决方案：用于制造聚氨酯的催化剂包含在构成环状结构的分子的主链中带有2-6个氮原子和0-2个氧原子的含杂原子的环状化合物，其中氮原子的总数 氧原子为3-6。 制备聚氨酯的方法包括在制备聚氨酯的催化剂的存在下使多元醇组分与异氰酸酯组分反应。 版权所有（C）2005，JPO＆NCIPI
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公开(公告)号：JP2004339468A
公开(公告)日：2004-12-02
申请号：JP2003427561
申请日：2003-12-24
Inventor： ISHIKAWA ATSUSHI
IPC: C08G18/22 , C08G18/18 , C08G101/00
Abstract: PROBLEM TO BE SOLVED: To provide a method for producing a polyisocyanulate foam excellent in dimensional stability, flame retardant property and bonding property by using a potassium aliphatic carboxylate having hydroxy group as a catalyst without using potassium 2-ethyl hexenoate obtained by using 2-ethyl hexenoic acid as a raw material, and further using a blowing agent containing water and a hydrofluoroalkane to reduce a load for environment.
SOLUTION: This method for producing the polyisocyanuate foam is provided by performing the reaction of a polyol component with an isocyanate component in the presence of the catalyst of the potassium aliphatic carboxylate having hydroxy group and the blowing agent containing water and the hydrofluoroalkane. The polyisocyanulate foam is obtained by the above method. Construction materials consist of the polyisocyanulate foam. The catalyst for producing the polyisocyanulate foam contains the potassium aliphatic carboxylate having hydroxy group.
COPYRIGHT: (C)2005,JPO&NCIPIAbstract translation: 待解决的问题：提供一种通过使用具有羟基的脂族羧酸钾作为催化剂而不使用通过使用得到的2-乙基己酸乙酯的尺寸稳定性，阻燃性和接合性优异的多异氰酸酯泡沫的制造方法 2-乙基己烯酸为原料，进一步使用含有水和氢氟烷烃的发泡剂，减轻环境负荷。 解决方案：通过在具有羟基的脂族羧酸钾的催化剂和含水发泡剂和氢氟烷烃的催化剂的存在下进行多元醇组分与异氰酸酯组分的反应来提供该聚异氰酸酯泡沫的制造方法。 通过上述方法得到聚异氰酸酯泡沫。 建筑材料由聚异氰酸酯泡沫制成。 用于制备多异氰酸酯泡沫的催化剂含有具有羟基的脂族羧酸钾。 版权所有（C）2005，JPO＆NCIPI
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