公开(公告)号：JPH0832761B2

公开(公告)日：1996-03-29

申请号：JP31248191

申请日：1991-11-27

Applicant: KAO CORP

Inventor： FUKUSHIMA TETSURO ,  ISAYAMA YASUTOSHI ,  MORII MASAYOSHI ,  ABE YUTAKA

IPC: C08G18/32 ,  C08G18/50

公开(公告)号：JPH05295066A

公开(公告)日：1993-11-09

申请号：JP9799992

申请日：1992-04-17

Applicant: KAO CORP

Inventor： FUKUSHIMA TETSURO ,  ISAYAMA YASUTOSHI ,  MORII MASAYOSHI ,  HARADA SHOICHIRO ,  KITAGAWA HIROSHI

IPC: C08G18/18 ,  C08G18/30 ,  C08G18/32 ,  C08G18/34 ,  C08G18/50 ,  C08G101/00 ,  C08J9/02

Abstract: PURPOSE:To produce the subject polymer excellent in packability without using a remarkably irritating catalyst such as a tert-amine by using a specified tert- amino alcohol in combination with a specified carboxylic acid as the polyol components. CONSTITUTION:A tert-amino alcohol of the formula (R1 is a 2 to 24C chain alkylene, or arylene, etc.; R2 is a 1 to 24C chain alkyl, or aryl, etc.; n is average polymerization degree and 1 to 50) is blended with a carboxylic acid (preferably formic acid) of formula R3COOH (R3 is H, or a 1 to 25C chain alcohol, etc.) in a molar ratio of (the former/the latter) = (1/0.01) to (1/37.5). The resultant mixture is used as a polyol component and the polyol component is reacted with a polyisocyanate component. The tert-amino alcohol of the formula is obtained recommendably by reacting a diol such as 1,3-butanediol with a primary amine such as dimethylamine with stirring in the presence of a catalyst having a composition of copper-Ni-VIII group platinum family element, etc., at 150 to 250 deg.C while removing generated water out of the system.

公开(公告)号：JPH0597955A

公开(公告)日：1993-04-20

申请号：JP31248391

申请日：1991-11-27

Applicant: KAO CORP

Inventor： ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSURO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  HARADA SHOICHIRO

IPC: C08G18/28 ,  C08G18/00 ,  C08G18/30 ,  C08G18/32 ,  C08G18/50 ,  C08G18/64 ,  C08G18/65 ,  C08G18/66 ,  C08G101/00 ,  C08J9/02 ,  C08L75/04

Abstract: PURPOSE:To obtain the subject foam excellent in heat insulating performance and low-temperature dimensional stability by using a specific tertiary amino- alcohol with a compound such as a polyfunctional alcohol having >=1000 hydroxyl value in combination as a polyol component. CONSTITUTION:A rigid polyurethane foam is obtained by reacting (A) a polyisocyanate component with (B) a polyol component using (i) one or more tertiary amino-alcohols expressed by the formula [R1 is 2-24C alicyclic, alkylene alkylene, cycloalkylene, arylene, aralkylene or (CH2CH2O)p-(CH2CH2)q [(p) is O or a positive number; (q) is a positive number]; R2 is 1-24C alkyl, aryl or aralkyl; n is a positive number of 1-50) and (ii) one or more compounds selected from polyfunctional alcohols having 1000 hydroxyl value, aliphatic amines and aromatic amines in combination in the presence of a foaming agent.

公开(公告)号：JPS644613A

公开(公告)日：1989-01-09

申请号：JP15908887

申请日：1987-06-26

Applicant: KAO CORP

Inventor： MORII MASAYOSHI

IPC: C08G18/18

Abstract: PURPOSE:To obtain the title catalyst of a relatively large MW which is lowly irritating and excellent in catalytic activity, comprising a propylene oxide adduct of a specific dimethylpropylamine. CONSTITUTION:A catalyst for preparing polyurethane of the formula (wherein m and n are each 0-6; m+n is 1-6) is obtd. by adding propylene oxide to dimethylaminopropylamine. A polyurethane is obtd. by compounding 100pts.wt. polyol (e.g., polyetherpolyol), 0.01-10pts.wt. above-described catalyst, water, a surface active agent and a polyisocyanate (e.g., 2,4-tolylene diisocyanate) and foaming them.

公开(公告)号：JP2001172352A

公开(公告)日：2001-06-26

申请号：JP35981999

申请日：1999-12-17

Applicant: KAO CORP

Inventor： ISHIKAWA ATSUSHI ,  SAKAI MITSURU ,  MORII MASAYOSHI

IPC: C08G18/18 ,  C08G18/42 ,  C08G18/48 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method for rapidly manufacturing a polyurethane foam showing an excellent dimensional stability even under a low temperature circumference with hardly generating a smell based on a catalyst. SOLUTION: This method for manufacturing a polyurethane foam includes a process of reacting a polyol component with an isocyanate component in the presence of a catalyst and a foaming agent, the catalyst containing a dialkylaminoalkyl alcohol represented by formula (I) (wherein R1 and R2 are each independently a 1 to 4C alkyl group; and X is a 4 to 8C branched alkylene group) and a compound containing a primary amine and a tertiary amine in the molecule.

公开(公告)号：JP2000319435A

公开(公告)日：2000-11-21

申请号：JP24313699

申请日：1999-08-30

Applicant: KAO CORP

Inventor： SAKAI MITSURU ,  ISHIKAWA ATSUSHI ,  MORII MASAYOSHI

IPC: C08J9/02 ,  C08G18/18 ,  C08G18/48 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a semi-rigid polyurethane foam hardly causing fogging even in a high temperature state and suitably employed as an interior material for an automobile or the like. SOLUTION: A polyol mixture comprising a polyol, water and a catalyst is mixed with a polyisocyanate with agitation and is foamed to give the objective foam, which has a retention of strength, when left at a high temperature (120 deg.C×24 hr) of at least 70% and a haze value of not more than 2 in a fogging test.

公开(公告)号：JPH10182780A

公开(公告)日：1998-07-07

申请号：JP34811496

申请日：1996-12-26

Applicant: KAO CORP

Inventor： OKUBO MAKOTO ,  NOMURA TAKAYUKI ,  MORII MASAYOSHI ,  ISAYAMA YASUTOSHI

IPC: C08G18/32 ,  C08G18/60 ,  C08G101/00

Abstract: PROBLEM TO BE SOLVED: To provide a method by which a rigid polyurethane foam excellent in dimensional stability at low temperatures can be produced. SOLUTION: A tertiary amino-alcohol represented by formula I [R1 denotes a 1-24C straight-chain or branched alkyl group, etc.; (m) denotes a number of 3-50 on the weight average; R2 denotes a 2-20C straight-chain or branched alkylene group, etc.] is used as at least a part of an active hydrogen-containing compound and a reaction is carried out in the presence of a compound represented by formula II R3 (X)n [R3 is an (n)-valent hydrocarbon group; X denotes the same or different anionic eliminable group; (n) is an integer of >=2] when reacting an isocyanate compound with the active hydrogen-containing compound and producing a rigid polyurethane resin.

公开(公告)号：JPH0597957A

公开(公告)日：1993-04-20

申请号：JP31248591

申请日：1991-11-27

Applicant: KAO CORP

Inventor： ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSURO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  HARADA SHOICHIRO

IPC: C08G18/28 ,  C08G18/30 ,  C08G18/32 ,  C08G18/50 ,  C08G101/00 ,  C08J9/02 ,  C08L75/04

Abstract: PURPOSE:To obtain the subject foam having excellent physical properties even when a metallic mold is heated at a high temperature by reacting a polyol component containing a specific tertiary amino-alcohol with a polyisocyanate component in the presence of water. CONSTITUTION:The objective low-density polyurethane foam is obtained by reacting (A) a polyisocyanate component such as polylene diisocyanate with (B) a polyol component containing a tertiary amino-alcohol expressed by the formula [R1 is 2-24C alkylene, aryl or aralkyl; the average polymerization degree n is a positive number; (q) is a positive number 11; R2 is 1-24C alkyl, aryl or aralkyl; the average polymerization degree n is a positive number of 1-50} as an essential component in the presence of water in an amount of 2-8 pts.wt. based on 100 pts.wt. total amount of the component (B).

公开(公告)号：JPH0539338A

公开(公告)日：1993-02-19

申请号：JP31248191

申请日：1991-11-27

Applicant: KAO CORP

Inventor： FUKUSHIMA TETSURO ,  ISAYAMA YASUTOSHI ,  MORII MASAYOSHI ,  ABE YUTAKA

IPC: C08G18/32 ,  C08G18/50

Abstract: PURPOSE:To improve the mold-filling properties of a polyurethane by mixing a polyisocyanate component with a polyol component consisting partly or wholly of at least one specific t-amino alcohol. CONSTITUTION:A polyisocyanate or a mixture of two or more polyisocyanates is mixed with a polyol component consisting of 99-60wt.% generally used polyol and 1-40wt.% t-amino alcohol of formula I and/or III [wherein R1 and R3 are each 2-24C linear or branched alkylene, alicyclic alkylene, cycloalkylene, arylene, aralkylene, or a group of formula II (wherein (p) is 0 or a positive integer; and (q) is a positive integer); R2 and R4 are each 1-24C linear or branched alkyl, aryl, or aralkyl; and (n) is a degree of polymn. being 1-4] in a molar ratio of NCO/OH of 1.0-1.2 and with other additives to give the objective polyurethane having improved mold-filling properties.

公开(公告)号：JPH02189320A

公开(公告)日：1990-07-25

申请号：JP1048789

申请日：1989-01-19

Applicant: KAO CORP

Inventor： MORII MASAYOSHI ,  HARADA SHOICHIRO ,  ISAYAMA YASUTOSHI

IPC: C08G18/18

Abstract: PURPOSE:To obtain a catalyst which is odorless, can be easily handled and can give a polyurethane having good air permeability and compression set by using a specified compound having a specified dimethylamino structure. CONSTITUTION:A catalyst for producing a polyurethane comprising a compound of the formula (wherein n is 1-3; R1 is H or CH3; and R2 is an isocyanate residue). Although a morpholine catalyst such as N-methylmorpholine is conventionally used as a catalyst for producing a polyurethane, it is difficult to work because of its low b.p. and strong irritating odor. Further, the obtained polyurethane product emits a strong irritating odor. Although an organotin compound which is a commonly used organometallic compound is lowly odorous, it is a resinification catalyst having a strong catalytic activity and therefore cannot be used alone. Because the compound of the above formula which is a reaction product of dimethylaminopolyalkanolamine with an isocyanate has a moderate catalystic activity, is odorless and gives a foam which has excellent properties, it is suitable as a catalyst for producing polyurethane.