公开(公告)号：DE3210513A1

公开(公告)日：1982-12-09

申请号：DE3210513

申请日：1982-03-23

Applicant: KAO CORP

Inventor： YAMASAKI HARUMASA ,  HARADA SHOICHIRO

IPC: C08F2/00 ,  C08F2/08 ,  C08F2/14 ,  C08F2/20 ,  C08F2/32 ,  C08F20/06 ,  C08F20/38 ,  C08F20/56 ,  C08F20/58

公开(公告)号：DE69709969T2

公开(公告)日：2002-09-12

申请号：DE69709969

申请日：1997-03-12

Applicant: KAO CORP

Inventor： HARADA SHOICHIRO ,  SAKAI MITSURU ,  TAKEMURA KAZUNARI ,  ITOI AKITO ,  OKUBO MAKOTO

IPC: C08G18/08 ,  C08G18/42 ,  C08G63/183 ,  C08G63/181

Abstract: A polyester-polyol obtainable by polycondensation of an acid component comprising terephthalic acid and adipic acid, and a polyhydric alcohol component, wherein the molar ratio of the terephthalic acid/ adipic acid is 0.05 to 0.3; a process for preparing a polyurethane foam comprising reacting a polyisocyanate component and a polyol component, wherein the polyol component contains the above polyester-polyol; and a process for preparing a polyurethane foam comprising reacting an isocyanate prepolymer made of a polyisocyanate component and a polyol component (I) with a polyol component (II), wherein the polyol component (I) comprises the above polyester-polyol. The invention also describes the use of this polyurethane foam for shoe soles.

公开(公告)号：DE69709969D1

公开(公告)日：2002-03-14

申请号：DE69709969

申请日：1997-03-12

Applicant: KAO CORP

Inventor： HARADA SHOICHIRO ,  SAKAI MITSURU ,  TAKEMURA KAZUNARI ,  ITOI AKITO ,  OKUBO MAKOTO

IPC: C08G18/08 ,  C08G18/42 ,  C08G63/183 ,  C08G63/181

Abstract: A polyester-polyol obtainable by polycondensation of an acid component comprising terephthalic acid and adipic acid, and a polyhydric alcohol component, wherein the molar ratio of the terephthalic acid/ adipic acid is 0.05 to 0.3; a process for preparing a polyurethane foam comprising reacting a polyisocyanate component and a polyol component, wherein the polyol component contains the above polyester-polyol; and a process for preparing a polyurethane foam comprising reacting an isocyanate prepolymer made of a polyisocyanate component and a polyol component (I) with a polyol component (II), wherein the polyol component (I) comprises the above polyester-polyol. The invention also describes the use of this polyurethane foam for shoe soles.

公开(公告)号：DE69702244T2

公开(公告)日：2000-12-21

申请号：DE69702244

申请日：1997-02-28

Applicant: KAO CORP

Inventor： SAKAI MITSURU ,  HARADA SHOICHIRO ,  TAKEMURA KAZUNARI ,  ITOI AKITO ,  OKUBO MAKOTO

IPC: C08J9/08

公开(公告)号：DE69125102T2

公开(公告)日：1997-07-31

申请号：DE69125102

申请日：1991-11-27

Applicant: KAO CORP

Inventor： HARADA SHOICHIRO ,  ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSUAKI ,  MORII MASAYOSHI ,  KITAGAWA HIROSHI ,  ABE HIROSHI

IPC: C08G18/18 ,  C08G18/28 ,  C08G18/32 ,  C08G18/50 ,  C08G18/66

Abstract: Processes for producing a polyurethane, a rigid polyurethane foam, a flexible polyurethane foam and a spray type rigid polyurethane foam are disclosed. In these processes, a specified tertiary aminoalcohol is used as a polyol component and a catalyst.

公开(公告)号：CA1190914A

公开(公告)日：1985-07-23

申请号：CA409729

申请日：1982-08-19

Applicant: KAO CORP

Inventor： YAMASAKI HARUMASA ,  SUMIDA YUZO ,  HARADA SHOICHIRO

IPC: C08F2/00 ,  A61L15/60 ,  C08F2/32 ,  C08F20/00 ,  C08F20/02 ,  C08F220/00 ,  C08F220/04 ,  B01J20/26

Abstract: \\\\ PROCESS FOR PRODUCING WATER-ABSORBENT MATERIALS HAVING EXCELLENT WATER ABSORPTION PROPERTIES A process is disclosed for producing a waterabsorbent material by dispersing and suspending an aqueous solution of a water-soluble, ethylenically unsaturated monomer in a hydrocarbon or halogenated aromatic hydrocarbon in the presence of an oil-soluble cellulose ester or cellulose ether and then carrying out the polymerization using a water-soluble radical-poly-merization initiator, characterized by the feature that one or more water-soluble or water-dispersible surfactants is(are) added to the system during or after the polymerization reaction.

公开(公告)号：FR2511687A1

公开(公告)日：1983-02-25

申请号：FR8214278

申请日：1982-08-18

Applicant: KAO CORP

Inventor： YAMASAKI HARUMASA ,  SUMIDA YUZO ,  HARADA SHOICHIRO

IPC: C08F2/00 ,  A61L15/60 ,  C08F2/32 ,  C08F20/00 ,  C08F20/02 ,  C08F220/00 ,  C08F220/04 ,  C08F2/24 ,  C08F12/04 ,  A61F13/00

Abstract: A process is disclosed for producing a water-absorbent material by dispersing and suspending an aqueous solution of a water-soluble, ethylenically unsaturated monomer in a hydrocarbon or halogenated aromatic hydrocarbon in the presence of an oil-soluble cellulose ester or cellulose ether and then carrying out the polymerization using a water-soluble radical-polymerization initiator, characterized by the feature that one or more water-soluble or water-dispersible surfactants is (are) added to the system during or after the polymerization reaction.

公开(公告)号：DE69702244D1

公开(公告)日：2000-07-13

申请号：DE69702244

申请日：1997-02-28

Applicant: KAO CORP

Inventor： SAKAI MITSURU ,  HARADA SHOICHIRO ,  TAKEMURA KAZUNARI ,  ITOI AKITO ,  OKUBO MAKOTO

IPC: C08J9/08

公开(公告)号：ES2098303T3

公开(公告)日：1997-05-01

申请号：ES91120280

申请日：1991-11-27

Applicant: KAO CORP

Inventor： HARADA SHOICHIRO ,  ISAYAMA YASUTOSHI ,  FUKUSHIMA TETSUAKI ,  MORII MASAYOSHI ,  KITAGAWA HIROSHI ,  ABE HIROSHI

IPC: C08G18/18 ,  C08G18/28 ,  C08G18/32 ,  C08G18/50 ,  C08G18/66

Abstract: Processes for producing a polyurethane, a rigid polyurethane foam, a flexible polyurethane foam and a spray type rigid polyurethane foam are disclosed. In these processes, a specified tertiary aminoalcohol is used as a polyol component and a catalyst.

公开(公告)号：CA2062269A1

公开(公告)日：1992-09-06

申请号：CA2062269

申请日：1992-03-04

Applicant: KAO CORP

Inventor： ABE HIROSHI ,  FUKUSHIMA TETSUAKI ,  SOTOYA KOHSHIRO ,  HARADA SHOICHIRO ,  KITAGAWA HIROSHI ,  MORII MASAYOSHI ,  ISAYAMA YASUTOSHI

IPC: C07C215/14 ,  C07C217/08 ,  C08G18/32 ,  C08G18/64 ,  C08G18/66 ,  C08G73/02 ,  C07C215/04 ,  C08J9/00 ,  C07C217/42 ,  C07C215/80

Abstract: A tertiary aminoalcohol having a tert-amino group(s) in the main chain and hydroxyl groups at the terminals. The use of this compound for purposes different from that of ordinary amines and amine derivatives is expected. A process for producing the tertiary aminoalcohol wherein a catalyst comprising copper, a transition metal element of the fourth period and a platinum group element of the group VIII, and further optionally containing an alkali metal or an alkaline earth metal is used. A process for producing polyurethane using the above-mentioned tertiary aminoalcohol which can solve the problems occurring in the production of a polyurethane using a tertiary amine which has a strong irritating odor and is highly irritant to the skin as a catalyst, for example, deteriorations of working atmosphere and sales appeal of the polyurethane. The chemical structure of the above-described tertiary aminoalcohol is as follows: (I)