公开(公告)号：AU1690288A

公开(公告)日：1988-12-08

申请号：AU1690288

申请日：1988-05-31

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OHTA MASAHIRO ,  KAWASHIMA SABURO ,  IIYAMA KATSUAKI ,  TAMAI SHOJI ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08L79/08 ,  C08L81/02

Abstract: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength. The polyimide resin composition of this invention consists of 99.9 to 50% by weight of the polyimide and 0.1 to 50% by weight of high temperature engineering polymer. The polyimide consists of recurring units of the following formula: wherein X is a sulfonyl radical or a carbonyl radical and R is a tetravalent radical selected from an aliphatic radical, alicyclic radical, monoaromatic radical, condensed aromatic radical and non-condensed aromatic radical. R is, for example, The high temperature engineering polymer is, for example, polyphenylene sulfide consisting of recurring units of the formula: aromatic polysulfone consisting of recurring units of the formula: or aromatic polyetherimide consisting of recurring units of the formula: l

公开(公告)号：IN156483B

公开(公告)日：1985-08-10

申请号：IN194CA1983

申请日：1983-02-17

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI KEIZABURO ,  SUGIMOTO KENICHI ,  TANABE YOSHIMITSU ,  YAMAGUCHI AKIHIRO ,  KAWASHIMA SABURO

IPC: C07C147/00

公开(公告)号：GB2137194A

公开(公告)日：1984-10-03

申请号：GB8313529

申请日：1983-05-17

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI KEIZABURO ,  SUGIMOTO KENICHI ,  TANABE YOSHIMITSU ,  KAWASHIMA SABURO ,  YAMAGUCHI AKIHIRO

IPC: C07B61/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/70 ,  B01J25/02 ,  B01J27/00 ,  B01J27/02 ,  B01J27/08 ,  C07C20060101 ,  C07C67/00 ,  C07C201/00 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C07C97/10

Abstract: Preparation of 3,3'- or 3,4'-diaminobenzophenone by nitrating a chloronitrobenzophenone mixture obtained by the Friedel-Crafts reaction between 3- or 4-nitrobenzoyl chloride and chlorobenzene, and catalytically reducing and dechlorinating the resulting chlorodinitrobenzophenone mixture in the presence of a reduction catalyst and a dehydrochlorinating agent.

公开(公告)号：FR2543136A1

公开(公告)日：1984-09-28

申请号：FR8308316

申请日：1983-05-19

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI KEIZABURO ,  SUGIMOTO KENICHI ,  TANABE YOSHIMITSU ,  KAWASHIMA SABURO ,  YAMAGUCHI AKIHIRO

IPC: C07B61/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/70 ,  B01J25/02 ,  B01J27/00 ,  B01J27/02 ,  B01J27/08 ,  C07C20060101 ,  C07C67/00 ,  C07C201/00 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C07C97/10

Abstract: Preparation of 3,3'- or 3,4'-diaminobenzophenone by nitrating a chloronitrobenzophenone mixture obtained by the Friedel-Crafts reaction between 3- or 4-nitrobenzoyl chloride and chlorobenzene, and catalytically reducing and dechlorinating the resulting chlorodinitrobenzophenone mixture in the presence of a reduction catalyst and a dehydrochlorinating agent.

公开(公告)号：GB2116168A

公开(公告)日：1983-09-21

申请号：GB8300598

申请日：1983-01-11

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI KEIZEBURO ,  SUHIMOTO KENICHI ,  YANABE YOSHIMITU ,  KAWASHIMA SABURO ,  YAMAGUCHI AKIHIRO

IPC: C07C309/40 ,  C07C97/10

Abstract: 3,3'- or 3,4'-diamino benzophenone is prepared by catalytically reducing and dehalogenating, in the presence of a reduction catalyst and a dehydrohalogenation agent, a benzophenone compound or benzophenone compounds of the general formula in which X is a halogen atom at position 2 or 4 of the benzene ring and Y is hydrogen or a halogen atom and in which the nitro group is at position 3' or 4' of the benzene ring if Y is hydrogen, while Y is at position 4' and the nitro group is at position 3' of the benzene ring if Y is a halogen atom.

公开(公告)号：IT8321578D0

公开(公告)日：1983-06-13

申请号：IT2157883

申请日：1983-06-13

Applicant: MITSUI TOATSU CHEMICALS

Inventor： YAMAGUCHI KEIZABUTO ,  SUGIMOTO KENICHI ,  TANABE YOSHIMITSU ,  KAWASHIMA SABURO ,  YAMAGUCHI AKIHIRO

IPC: C07B61/00 ,  B01J23/00 ,  B01J23/40 ,  B01J23/70 ,  B01J25/02 ,  B01J27/00 ,  B01J27/02 ,  B01J27/08 ,  C07C20060101 ,  C07C67/00 ,  C07C201/00 ,  C07C205/45 ,  C07C221/00 ,  C07C225/22 ,  C07C

Abstract: Preparation of 3,3'- or 3,4'-diaminobenzophenone by nitrating a chloronitrobenzophenone mixture obtained by the Friedel-Crafts reaction between 3- or 4-nitrobenzoyl chloride and chlorobenzene, and catalytically reducing and dechlorinating the resulting chlorodinitrobenzophenone mixture in the presence of a reduction catalyst and a dehydrochlorinating agent.

公开(公告)号：DE2911945A1

公开(公告)日：1979-10-04

申请号：DE2911945

申请日：1979-03-27

Applicant: MITSUI TOATSU CHEMICALS

Inventor： ASANO MAKOTO ,  KOBAYASHI TADASHI ,  KAWASHIMA SABURO ,  SUGIMOTO KENICHI ,  MURAKAMI HISAMICHI

IPC: B41M5/155 ,  C08K5/13 ,  C08K5/3475 ,  C08K5/372 ,  B41M5/12

公开(公告)号：AU4535479A

公开(公告)日：1979-10-04

申请号：AU4535479

申请日：1979-03-20

Applicant: MITSUI TOATSU CHEMICALS

Inventor： ASANO MAKOTO ,  KOBAYASHI TADASHI ,  KAWASHIMA SABURO ,  SUGIMOTO KENICHI ,  MURAKAMI HISAMICHI

IPC: B41M5/155 ,  C08K5/13 ,  C08K5/3475 ,  C08K5/372 ,  B41M5/22 ,  B41M5/16 ,  C08G8/28

公开(公告)号：CA1339823C

公开(公告)日：1998-04-14

申请号：CA568192

申请日：1988-05-31

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OHTA MASAHIRO ,  KAWASHIMA SABURO ,  IIYAMA KATSUAKI ,  TAMAI SHOJI ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO

IPC: C08L79/08 ,  C08L81/04

Abstract: This invention relates to molding resin compositions, and more particularly relates to polyimide resin compositions having markedly improved molding ability in addition to excellent high temperature stability, chemical resistance and mechanical strength. The polyimide resin compositions of this invention consist of 99.9 to 50% by weight of the polyimide and 0.1 to 50% by weight of high-temperature engineering polymer. The polyimide consists of recurring units of the following formula: (see fig. I) wherein X is direct bond, thio radical, or o- or p-phenylene dicarbonyl radical and R is a tetravalent radical selected from an aliphatic radical, alicyclic radical, monoaromatic radical, condensed aromatic radical and non-condensed aromatic radical. R is, for example, (see figs. II, III, IV and V) The high-temperature engineering polymer is, for example, polyphenylene sulfide consisting of recurring units of the formula: (see fig. I) aromatic polysulfone consisting of recurring units of the formula: (see fig. II) or aromatic polyetherimide consisting of recurring units of the formula: (see fig. III)

公开(公告)号：DE3855276D1

公开(公告)日：1996-06-13

申请号：DE3855276

申请日：1988-10-21

Applicant: MITSUI TOATSU CHEMICALS

Inventor： OHTA MASAHIRO ,  TAMAI SHOJI ,  KAWASHIMA SABURO ,  OIKAWA HIDEAKI ,  YAMAGUCHI AKIHIRO ,  NAKAKURA TOSHIYUKI ,  MASUDA MISAO ,  MARUKO CHIAKI ,  KOBA TOMOHITO ,  SAKAI HIDEO ,  KISHI SATORU

IPC: C08G73/10 ,  C08K7/04 ,  C08L79/08 ,  C08K7/02

Abstract: This invention relates to a method for preparing polyimide having good heat-stability and excellent flowability in a molten state. The polymide is prepared by reacting aromatic diamines such as 4,4 min -bis(3-aminophenoxy)biphenyl, bis[4-(3-aminophenoxy)phenyl] ketone and bis [4-(3-aminophenoxy)phenyl] sulfone; tetracarboxylic dianhydrides such as pyromellitic dianhydride, 3,3 min ,4,4 min -benzophenonetetracarboxylic dianhydride and bis(3,4-dicarboxyphenyl) ether dianhydride; and dicarboxylic anhydrides such as glutaric anhydride, 1,2-hexanedicarboxylic anhydride, phthalic anhydride and 3,4-benzophenonedicarboxylic anhydride. The molar ratio of aromatic diamine : tetracarboxylic dianhydride : dicarboxylic anhydride is 1:(0.9 to 1.0):(0.001 to 1.0). Another invention relates to polyimide composite materials which are excellent in mechanical strengths and processability. The materials contain the polyimide and fibrous reinforcing materials such as yarn, roving, tow, fabrics, mats and felts of glass fiber, carbon fibers or aromatic polyamide fibers.