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公开(公告)号：US3890246A
公开(公告)日：1975-06-17
申请号：US20570671
申请日：1971-12-07
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , FRIEDRICH MARIA S
IPC: B01J21/08 , B01J23/00 , B01J23/18 , B01J23/28 , B01J23/84 , B01J23/843 , B01J23/88 , B01J37/02 , B01J37/04 , C22B41/00 , B01J11/82 , B01J11/06
CPC classification number: B01J23/002 , B01J21/08 , B01J23/18 , B01J23/28 , B01J23/84 , B01J23/8432 , B01J23/88 , B01J37/0201 , B01J37/04 , B01J2523/00 , C07C253/26 , C22B41/00 , Y02P20/52 , B01J2523/39 , B01J2523/43 , B01J2523/52 , B01J2523/53 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/54 , B01J2523/55 , C07C255/08
Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and arsenic on a catalyst support and the combined oxides of uranium and arsenic promoted by molybdenum, boron, vanadium, tin, nickel, bismuth, chromium, iron, manganese, zinc, tungsten, antimony, cerium, cobalt or rhenium.
Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括催化剂载体上的铀和砷的组合氧化物，以及由钼，硼，钒，锡，镍，铋，铬，铁，锰，锌，钨，锑，铈， 钴或铼。
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公开(公告)号：US3445521A
公开(公告)日：1969-05-20
申请号：US3445521D
申请日：1966-11-17
Applicant: STANDARD OIL CO
Inventor： CALLAHAN JAMES L , GRASSELLI ROBERT K , KNIPPLE WARREN R
CPC classification number: C07C253/26 , B01J23/84 , B01J23/8973 , C07C5/48 , C07C45/35 , Y02P20/52 , C07C11/167 , C07C47/22 , C07C255/08
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公开(公告)号：US3414631A
公开(公告)日：1968-12-03
申请号：US46303665
申请日：1965-06-10
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , CALLAHAN JAMES L
IPC: B01J27/192 , C07C5/48
CPC classification number: C07C5/48 , B01J27/192 , C07C11/18 , C07C11/167
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公开(公告)号：US3409697A
公开(公告)日：1968-11-05
申请号：US59498466
申请日：1966-11-17
Applicant: STANDARD OIL CO
Inventor： CALLAHAN JAMES L , GRASSELLI ROBERT K , KNIPPLE WARREN R
IPC: B01J23/84 , B01J23/843 , C07C5/48 , C07C45/34 , C07C45/35
CPC classification number: B01J23/8437 , B01J23/84 , B01J23/843 , B01J23/8435 , B01J23/888 , B01J23/8892 , C07C5/48 , C07C45/34 , C07C45/35 , C07C253/26 , Y02P20/52 , C07C11/167 , C07C47/22 , C07C255/08
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公开(公告)号：US3819685A
公开(公告)日：1974-06-25
申请号：US20532171
申请日：1971-12-06
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , SURESH DEV D
IPC: C07C69/65 , B01J23/00 , B01J23/30 , B01J25/00 , B01J27/00 , C07B61/00 , C07C51/04 , C07C57/04 , C07C67/05 , C07C67/39 , C07C67/44 , C07C69/54 , C07C69/653
Abstract: ACRYLIC ESTERS AND METHACRYLIC ESTERS ARE FORMED DIRECTLY FROM THE ALDEHYDE BY REACTING ACROLIEN OR METHACROLEIN WITH MOLECULAR OXYGEN AND AN ALCOHOL IN THE PRESENCE OF AN OXIDATION CATALYST UNDER THE CONDITIONS NORMALLY ASSOCIATED WITH THE REACTION OF THE ALDEHYDE TO THE ACID.
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Patent Agency Ranking16.发明授权Catalytic conversion of saturated hydrocarbons to unsaturated products by oxidation in the presence of a halogen 失效通过在卤化物存在下通过氧化将饱和烃转化为不饱和产物的催化转化
公开(公告)号：US3686295A
公开(公告)日：1972-08-22
申请号：US3686295D
申请日：1970-06-01
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , MILLER ROBERT C
CPC classification number: C07C45/36 , C07C45/33 , C07C45/34 , C07C253/24 , C07C253/28 , C07C47/22 , C07C255/08 , C07C255/34
Abstract: The instant application is related to a process for the oxidation of saturated hydrocarbons and substituted saturated hydrocarbons in a vapor phase reaction over an antimonycontaining oxidation catalyst in which the hydrocarbon in the presence of a minor quantity of an inorganic or organic halide, hydrogen chloride, hydrogen bromide or hydrogen iodide or of a halogen other than fluorine, is reacted with (a) oxygen, to form unsaturated aldehydes and acids or (b) oxygen and ammonia, to form unsaturated nitriles.
Abstract translation: 本申请涉及在含锑氧化催化剂的气相反应中氧化饱和烃和取代饱和烃的方法，其中烃在少量无机或有机卤化物，氯化氢存在下 ，溴化氢或碘化氢或氟以外的卤素与（a）氧反应，形成不饱和醛和酸或（b）氧和氨，形成不饱和腈。
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公开(公告)号：US3666823A
公开(公告)日：1972-05-30
申请号：US3666823D
申请日：1970-03-05
Applicant: STANDARD OIL CO OHIO
Inventor： GRASSELLI ROBERT K , FRIEDRICH MARIA S
IPC: B01J21/08 , B01J23/00 , B01J23/16 , B01J23/18 , B01J23/28 , B01J23/843 , B01J23/88 , B01J23/887 , B01J37/02 , B01J37/04 , C07C5/48 , C22B41/00 , C07C5/18
CPC classification number: B01J23/002 , B01J21/08 , B01J23/16 , B01J23/18 , B01J23/28 , B01J23/8432 , B01J23/88 , B01J23/8876 , B01J37/0201 , B01J37/04 , B01J2523/00 , C07C5/48 , C07C253/26 , C22B41/00 , Y02P20/52 , B01J2523/39 , B01J2523/52 , B01J2523/54 , B01J2523/69 , B01J2523/842 , B01J2523/72 , B01J2523/30 , B01J2523/43 , B01J2523/68 , B01J2523/27 , B01J2523/847 , B01J2523/67 , B01J2523/55 , B01J2523/53 , C07C255/08
Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and arsenic on a catalyst support and the combined oxides of uranium and arsenic promoted by molybdenum, boron, vanadium, tin, nickel, bismuth, chromium, iron, manganese, zinc, tungsten, antimony, cerium, cobalt or rhenium.
Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括催化剂载体上的铀和砷的组合氧化物，以及由钼，硼，钒，锡，镍，铋，铬，铁，锰，锌，钨，锑，铈， 钴或铼。
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18.发明授权Ammoxidation of propylene or isobutylene to acrylonitrile or methacrylonitrile 失效丙烯或异丁烯对丙烯腈或甲基丙烯酸甲酯的氧化
公开(公告)号：US3542842A
公开(公告)日：1970-11-24
申请号：US3542842D
申请日：1967-12-20
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , FRIEDRICH MARIA S
IPC: B01J21/08 , B01J23/00 , B01J23/18 , B01J23/28 , B01J23/31 , B01J23/84 , B01J23/88 , B01J23/887 , B01J37/02 , B01J37/04 , C07C5/48 , C07C45/35 , C22B41/00 , C07C121/02
CPC classification number: B01J23/002 , B01J21/08 , B01J23/18 , B01J23/28 , B01J23/31 , B01J23/84 , B01J23/88 , B01J23/8876 , B01J37/0201 , B01J37/04 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C45/35 , C07C253/26 , C22B41/00 , Y02P20/52 , C07C47/22 , B01J2523/39 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , B01J2523/55 , B01J2523/41 , B01J2523/52 , B01J2523/845 , B01J2523/43 , C07C255/08
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公开(公告)号：US3501470A
公开(公告)日：1970-03-17
申请号：US3501470D
申请日：1966-09-30
Applicant: STANDARD OIL CO
Inventor： GRASSELLI ROBERT K , CALLAHAN JAMES L
IPC: C07D251/18 , C07D55/20
CPC classification number: C07D251/18
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公开(公告)号：US3390202A
公开(公告)日：1968-06-25
申请号：US63857767
申请日：1967-05-15
Applicant: STANDARD OIL CO
Inventor： CALLAHAN JAMES L , GRASSELLI ROBERT K , KNIPPLE WARREN R
IPC: B01J21/00 , B01J23/16 , B01J23/18 , B01J23/644 , B01J23/68 , B01J23/843 , B01J27/18 , B01J37/00 , C07C5/48 , C07C45/35
CPC classification number: B01J21/00 , B01J23/16 , B01J23/18 , B01J23/6445 , B01J23/681 , B01J23/8435 , B01J27/1815 , B01J37/0009 , C07C5/48 , C07C45/35 , C07C253/26 , Y02P20/52 , Y10S502/503 , Y10S502/504 , Y10S585/906 , C07C11/167 , C07C47/22 , C07C255/08
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