公开(公告)号：KR820000922B1

公开(公告)日：1982-05-26

申请号：KR780001318

申请日：1978-05-01

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT K ,  BARTEK JOSEPH P

IPC: B01J21/02 ,  C07C15/46

Abstract: Catalysts for the title dehydrogenation had the formula AaMbMlcM"dBePyOx, where A = alkali metal and/or Tl; M = one or more of Ni, Co, Cu, Mn, Mg, An, Ca, Nb, Ta, Sn, Ba; M' = one or more of Fe, Cr, U, Th, V, Ti, La, rare earth; M" = one or more of An, B, Pb, Ge, Al, W, Mo; B = one or more of Bi, Te, As, Sb, Cd; a-y varied over a range, mostly from 0-20, were prepd. Data for 26 catalysts were given in terms of dehydrogenation of alkylaromatic compds. to alkenylaromatic compds.

公开(公告)号：WO2005000463A3

公开(公告)日：2005-03-03

申请号：PCT/US2004017837

申请日：2004-06-04

Applicant: STANDARD OIL CO ,  LUGMAIR CLAUS G ,  ZYSK JESSICA ,  GRASSELLI ROBERT K

Inventor： LUGMAIR CLAUS G ,  ZYSK JESSICA ,  GRASSELLI ROBERT K

IPC: B01J23/00 ,  B01J23/14 ,  B01J23/18 ,  B01J23/20 ,  B01J23/28 ,  B01J37/10 ,  C07C51/215 ,  C07C253/24 ,  C07C255/08

CPC classification number: C07C51/215 ,  B01J23/002 ,  B01J23/14 ,  B01J23/18 ,  B01J23/20 ,  B01J23/28 ,  B01J37/10 ,  B01J2523/00 ,  C07C253/24 ,  Y02P20/52 ,  C07C57/04 ,  C07C255/08 ,  B01J2523/42 ,  B01J2523/55 ,  B01J2523/56 ,  B01J2523/64 ,  B01J2523/68 ,  B01J2523/53

Abstract: Compositions of matter and catalyst compositions effective for gas-phase conversion of propane to acrylic acid (via oxidation) or to acrylonitrile (via ammoxidation) and isobutane to methacrylic acid (via oxidation) and isobutane to methacrylonitrile (via ammoxidation) are disclosed. Preferred catalyst compositions comprise molybdenum, vanadium, niobium, antimony and germanium and molybdenum, vanadium, tantalum, antimony, and germanium. Methods of preparing such compositions and related compositions, including hydrothermal synthesis methods are also disclosed. The preferred catalysts convert propane to acrylic acid and/or to acrylonitrile and isobutane to methacrylic acid/methacrylonitrile with a yield of at least about 50 %.

Abstract translation: 公开了对于丙烷到丙烯酸（通过氧化）或到丙烯腈（通过氨氧化）和异丁烷到甲基丙烯酸（通过氧化）和异丁烷到甲基丙烯腈（通过氨氧化）的气相转化有效的物质和催化剂组合物的组成。 优选的催化剂组合物包含钼，钒，铌，锑和锗以及钼，钒，钽，锑和锗。 还公开了制备这种组合物和相关组合物的方法，包括水热合成方法。 优选的催化剂以至少约50％的收率将丙烷转化成丙烯酸和/或转化成丙烯腈和异丁烷转化为甲基丙烯酸/甲基丙烯腈。

公开(公告)号：JPS5134107A

公开(公告)日：1976-03-23

申请号：JP8823475

申请日：1975-07-18

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV DHANARAJ ,  HARDMAN HARLEY FOCH

IPC: C07C27/14 ,  B01J23/00 ,  B01J23/88 ,  C07B61/00 ,  C07C27/00 ,  C07C45/00 ,  C07C47/20 ,  C07C47/22 ,  C07C57/05 ,  C07C67/00 ,  C07C45/04

公开(公告)号：EP0131040A4

公开(公告)日：1987-03-05

申请号：EP84900571

申请日：1983-12-21

Applicant: STANDARD OIL CO

Inventor： BURRINGTON JAMES D ,  PESA FRED A ,  MAHER ELIZABETH ,  GRASSELLI ROBERT K

IPC: C07C69/593 ,  B01J23/56 ,  B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  B01J31/24 ,  B01J31/28 ,  C07B61/00 ,  C07C45/00 ,  C07C45/69 ,  C07C45/72 ,  C07C45/73 ,  C07C47/12 ,  C07C57/13 ,  C07C67/00 ,  C07C231/00 ,  C07C231/12 ,  C07C233/04 ,  C07C233/09 ,  C07C253/00 ,  C07C55/02 ,  C07C67/465 ,  C07C121/00 ,  C07C121/20

CPC classification number: B01J31/2404 ,  B01J31/1625 ,  B01J31/1805 ,  B01J31/2234 ,  B01J31/30 ,  B01J2531/821 ,  B01J2531/845 ,  C07C45/72 ,  C07C45/73 ,  C07C255/00 ,  Y02P20/588 ,  C07C47/21

Abstract: A catalyst and a liquid phase process are provided for the dimerization of acrylic coumpounds. The process includes contacting an acrylic compound with the catalyst in the presence of hydrogen, wherein the catalyst comprises an inorganic oxide catalyst support, trivalent pendant atoms covalently bonded to the support and ruthenium complexed with said trivalent pendant atoms.

Abstract translation: 提供了用于丙烯酸类混合物二聚的催化剂和液相方法。 该方法包括使丙烯酸类化合物与催化剂在氢存在下接触，其中催化剂包含无机氧化物催化剂载体，共价键合至载体的三价侧基原子和与所述三价侧基原子配合的钌。

公开(公告)号：US3666822A

公开(公告)日：1972-05-30

申请号：US3666822D

申请日：1970-03-05

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J21/08 ,  B01J23/00 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/887 ,  B01J37/02 ,  B01J37/04 ,  C07C5/48 ,  C22B41/00 ,  C07C5/18

CPC classification number: B01J23/002 ,  B01J21/08 ,  B01J23/18 ,  B01J23/28 ,  B01J23/31 ,  B01J23/84 ,  B01J23/8871 ,  B01J23/8876 ,  B01J37/0201 ,  B01J37/04 ,  B01J2523/00 ,  C07C5/48 ,  C07C253/26 ,  C22B41/00 ,  Y02P20/52 ,  B01J2523/39 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/847 ,  B01J2523/43 ,  B01J2523/41 ,  B01J2523/842 ,  B01J2523/31 ,  B01J2523/52 ,  B01J2523/55 ,  B01J2523/845 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and molybdenum and the combined oxides of uranium and molybdenum in combination with arsenic, bismuth, tin, vanadium, iron, nickel and cobalt.

Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括铀和钼的组合氧化物以及铀和钼与砷，铋，锡，钒，铁，镍和钴组合的组合氧化物。

公开(公告)号：US3452032A

公开(公告)日：1969-06-24

申请号：US3452032D

申请日：1967-03-16

Applicant: STANDARD OIL CO

Inventor： GRASSELLI ROBERT K

IPC: C07C45/36 ,  C07D31/32 ,  B01J11/32

CPC classification number: C07C45/36

公开(公告)号：US3431292A

公开(公告)日：1969-03-04

申请号：US3431292D

申请日：1966-12-23

Applicant: STANDARD OIL CO

Inventor： CALLAHAN JAMES L ,  GRASSELLI ROBERT K ,  KNIPPLE WARREN R

IPC: B01J23/16 ,  B01J23/644 ,  B01J23/68 ,  B01J23/843 ,  C07C121/04 ,  C07C121/10

CPC classification number: C07C253/26 ,  B01J23/16 ,  B01J23/6445 ,  B01J23/681 ,  B01J23/8435 ,  Y02P20/52 ,  C07C255/08

公开(公告)号：US3427343A

公开(公告)日：1969-02-11

申请号：US3427343D

申请日：1964-11-04

Applicant: STANDARD OIL CO

Inventor： CALLAHAN JAMES L ,  MILBERGER ERNEST C ,  GRASSELLI ROBERT K

IPC: C07C47/22 ,  B01J8/26 ,  B01J21/08 ,  B01J23/00 ,  B01J23/12 ,  B01J23/18 ,  B01J35/00 ,  C07B61/00 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C45/04 ,  C07C121/02

CPC classification number: B01J8/26 ,  B01J21/08 ,  B01J23/12 ,  B01J23/18 ,  C07C45/34 ,  C07C45/35 ,  C07C253/26 ,  Y02P20/52 ,  C07C47/22 ,  C07C255/08

公开(公告)号：US3929899A

公开(公告)日：1975-12-30

申请号：US42349473

申请日：1973-12-10

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  FRIEDRICH MARIA S

IPC: B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/843 ,  C07C45/35 ,  C07C45/04

CPC classification number: C07C253/26 ,  B01J23/18 ,  B01J23/22 ,  B01J23/24 ,  B01J23/34 ,  B01J23/8432 ,  C07C45/35 ,  Y02P20/52 ,  C07C47/22 ,  C07C255/08

Abstract: Catalysts are provided which are useful in the oxidation of olefins to aldehydes and conjugated dienes and in ammoxidation of olefins to nitriles. The catalysts comprise the combined oxides of uranium and arsenic on a catalyst support and the combined oxides of uranium and arsenic promoted by molybdenum, boron, vanadium, tin, nickel, bismuth, chromium, iron, manganese, zinc, tungsten, antimony, cerium, cobalt or rhenium.

Abstract translation: 提供了可用于将烯烃氧化成醛和共轭二烯并且将烯烃氨氧化成腈的催化剂。 催化剂包括催化剂载体上的铀和砷的组合氧化物，以及由钼，硼，钒，锡，镍，铋，铬，铁，锰，锌，钨，锑，铈， 钴或铼。

公开(公告)号：US3907713A

公开(公告)日：1975-09-23

申请号：US32903473

申请日：1973-02-02

Applicant: STANDARD OIL CO OHIO

Inventor： GRASSELLI ROBERT K ,  SURESH DEV D ,  FRIEDRICH MARIA

IPC: C07C27/00 ,  B01J21/02 ,  B01J23/28 ,  B01J23/31 ,  B01J23/34 ,  B01J23/76 ,  B01J23/84 ,  B01J23/88 ,  B01J27/057 ,  B01J27/18 ,  B01J37/02 ,  C07B61/00 ,  C07C27/14 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  B01J23/10

CPC classification number: B01J23/8872 ,  B01J21/02 ,  B01J23/31 ,  B01J23/34 ,  B01J23/8871 ,  B01J23/8876 ,  B01J27/0576 ,  B01J2523/00 ,  C07C253/26 ,  Y02P20/52 ,  B01J2523/13 ,  B01J2523/22 ,  B01J2523/41 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/847 ,  B01J2523/845 ,  B01J2523/64 ,  B01J2523/72 ,  C07C255/08

Abstract: Very desirable oxidation catalysts are prepared by impregnating a catalytic oxide matrix containing at least cobalt and molybdenum, magnesium and molybdenum, nickel and mulybdenum, manganese and molybdenum with iron, bismuth, tellurium or a mixture thereof.

Abstract translation: 通过将含有至少钴和钼，镁和钼，镍和钼，锰和钼的催化氧化物基质浸渍在铁，铋，碲或其混合物中来制备非常理想的氧化催化剂。