PROCESS FOR MAKING AN ACRYLONITRILE/METHACRYLONITRILE COPOLYMER

    公开(公告)号:CA2134825A1

    公开(公告)日:1995-05-11

    申请号:CA2134825

    申请日:1994-11-01

    Abstract: Title: A PROCESS FOR MAKING AN ACRYLONITRILE/METHACRYLONITRILE COPOLYMER A process for making acrylonitrile/methacrylonitrile copolymer, comprising polymerizing a mixture of acrylonitrile monomer and methacrylonitrilemonomer in which the rate of addition of the comonomers is at by the sate of polymerization so that the concentration of unreacted acrylonitrile monomer and unreacted methacrylonitrile monomer is low and the polymerization process is in a starved condition.

    CATALYSTS USEFUL FOR PREPARING POLYAMIDES

    公开(公告)号:CA1189243A

    公开(公告)日:1985-06-18

    申请号:CA418656

    申请日:1982-12-29

    Abstract: CATALYSTS USEFUL FOR PREPARING POLYAMIDES A polyamide is produced by polymerizing at least one of an alpha, beta unsaturated carboxylic acid and ammonia, an ammonium salt of an alpha, beta unsaturated carboxylic acid, an alpha, beta unsaturated nitrite and water, a beta-amino propionic acid or alkyl derivative thereof and an alpha, beta unsaturated amide and ammoniua in the presence of a catalyst comprising a pentaammine cobalt (III) complex.

    POLYMERIC COMPOSITIONS
    20.
    发明专利

    公开(公告)号:CA961192A

    公开(公告)日:1975-01-14

    申请号:CA121406

    申请日:1971-08-26

    Abstract: 1360685 Graft polymers STANDARD OIL CO 21 Oct 1971 [13 Nov 1970] 48958/71 Heading C3G A graft polymer is produced by polymerization of (A) from 70 to 85% by weight of an olefinically unsaturated nitrile, (B) 2 to 13% of an alpha-olefin of structure wherein R 1 and R 11 are C 1 to C 7 -alkyl groups, (C) 2 to 30% of a monomer selected from a vinyl ester, acrylate ester, an acrylamide or a methacrylate ester, and (D) up to 17% of a vinyl or vinylidene aromatic monomer, wherein the combined amount of (A)+(B)+(C)+(D) is 100%, in the presence of from 1 to 30 parts by weight per 100 parts of (A) + (B) + (C)+(D) of (E) a rubbery polymer of 50 to 100% by weight of polymerized conjugated diene monomer and 50 to 0% of a polymerized vinyl or vinylidene aromatic monomer. In the examples, graft polymers are prepared in aqueous emulsion from (a) butadiene-styrene rubber or polybutadiene, acrylonitrile, isobutylene, styrene and methyl acrylate, N-t-octyl acrylamide, N-t-butyl acrylamide or vinyl acetate and (b) polybutadiene, acrylonitrile, diisobutylene, styrene and methyl acrylate.

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