公开(公告)号：DE2813464A1

公开(公告)日：1978-10-12

申请号：DE2813464

申请日：1978-03-29

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：NO781155L

公开(公告)日：1978-10-05

申请号：NO781155

申请日：1978-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07C

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：CA998059A

公开(公告)日：1976-10-05

申请号：CA212675

申请日：1974-10-30

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：BR9602791A

公开(公告)日：1998-09-08

申请号：BR9602791

申请日：1996-06-13

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  WOODBURY DAVID R ,  GOEDEN GARY V

IPC: C02F1/04 ,  C02F1/58

公开(公告)号：CA1183515A

公开(公告)日：1985-03-05

申请号：CA411955

申请日：1982-09-22

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  DRIA DENNIS E

IPC: C07D307/60 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  B01J27/14

Abstract: Vanadium phosphorus mixed oxide containing catalysts are prepared by sequentially forming an alpha-VOPO4 catalyst precursor in aqueous media, and thereafter partially reducing a portion of the vanadium to a valence state of +4 in an organic liquid reducing media, in the absence of corrosive reducing agents. The catalysts exhibit excellent activity for the production of maleic anhydride from 4 carbon atom hydrocarbons such as n-butane.

公开(公告)号：CA1099694A

公开(公告)日：1981-04-21

申请号：CA302918

申请日：1978-05-09

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/18 ,  B01J27/198 ,  C01B25/37 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25 ,  C07D307/89

Abstract: PRODUCTION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS USING CATALYSTS PREPARED BY HYDROTHERMAL TECHNIQUES Exceptionally reproducible catalysts comprising vanadium and phosphorus are obtained when an aqueous oxide slurry comprising vanadium, phosphorus and a mineral acidfree, inorganic reducing agent, which is capable or reducing the vanadium in the catalyst to a valence state below +5, is heated at an elevated temperature of at least 120.degree.C under autogenous pressure so that substantial evaporation of the water in said oxide slurry is prevented. Especially preferred catalysts comprise vanadium, phosphorus, uranium and oxygen. Catalysts prepared in accordance with the invention are especially desirable in the oxidation of n-butane, nbutenes, 1,3-butadiene or mixture thereof.

公开(公告)号：CA1089479A

公开(公告)日：1980-11-11

申请号：CA298352

申请日：1978-03-07

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: PREPARATION OF MALEIC ANHYDRIDE FROM FOUR-CARBON HYDROCARBONS Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：CA1055468A

公开(公告)日：1979-05-29

申请号：CA215156

申请日：1974-12-03

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C ,  BREMER NOEL J

IPC: C07C69/54 ,  B01J23/12 ,  B01J23/22 ,  B01J23/24 ,  B01J23/30 ,  B01J23/31 ,  B01J23/34 ,  B01J23/84 ,  B01J23/88 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07D307/60

Abstract: CATALYST COMPOSITIONS ESPECIALLY USEFUL FOR PREPARATION OF UNSATURATED ACIDS OF THE DI DISCLOSURE The present invention is a catalyst composition consisting of oxides or oxide complexes that contains catalytically significant amounts of uranium or thorium plus, tungsten, vanadium and molybdenum plus optionally one or more of Co, Fe, Ni, ZN, Cu, Mg, Mn, Bi, Ti, Zr, Sn, P an alkali metal, an alkaline earth metal, lanthanum or an element of the lantbanoid series. These catalysts are especially useful for producing acrylic acid from acrolein and for producing methacrylic acid from methacrolein.

公开(公告)号：DD135201A5

公开(公告)日：1979-04-18

申请号：DD20456678

申请日：1978-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：ZA9604252B

公开(公告)日：1996-12-04

申请号：ZA9604252

申请日：1996-05-27

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  GOEDEN GARY V ,  WOODBURY DAVID R

IPC: C02F20060101 ,  C02F

CPC classification number: B09B3/0091