公开(公告)号：US3928240A

公开(公告)日：1975-12-23

申请号：US39177573

申请日：1973-08-27

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/883 ,  B01J37/16 ,  C07C51/25 ,  C07C51/31 ,  B01J23/16 ,  B01J23/18 ,  B01J23/24

CPC classification number: C07C51/252 ,  B01J23/28 ,  B01J23/30 ,  B01J23/883 ,  B01J37/16 ,  B01J2523/00 ,  C07C51/25 ,  C07C51/313 ,  C07C57/145 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/41 ,  B01J2523/55 ,  B01J2523/51

Abstract: Molybdenum containing oxidation catalysts are prepared by reducing hexavalent molybdenum to a valence state below +6 prior to or during the catalyst preparation. Reproducible catalysts with superior catalytic activity are conveniently made by this process.

Abstract translation: 含钼氧化催化剂通过在催化剂制备之前或期间将六价钼还原成低于+6的价态来制备。 通过该方法可方便地制备具有优异催化活性的可再现催化剂。

公开(公告)号：US3907834A

公开(公告)日：1975-09-23

申请号：US17710571

申请日：1971-09-01

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  HARDMAN HARLEY F

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/887 ,  B01J37/16 ,  C07B61/00 ,  C07C51/25 ,  C07C51/31 ,  C07C57/14

CPC classification number: C07C51/252 ,  B01J23/28 ,  B01J23/30 ,  B01J23/8876 ,  B01J37/16 ,  B01J2523/00 ,  C07C51/25 ,  C07C51/313 ,  C07C57/145 ,  B01J2523/53 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/847

Abstract: The process in this invention relates to the conversion of organic compounds selected from the group consisting of the nbutylenes, butadiene, crotonaldehyde and furan in a selective manner to maleic anhydride in the presence of a catalyst comprising the mixed oxides of antimony and molybdenum.

Abstract translation: 本发明的方法涉及在包含锑和钼的混合氧化物的催化剂存在下，将选自正丁烯，丁二烯，巴豆醛和呋喃的有机化合物以选择性方式转化为马来酸酐。

公开(公告)号：US3657015A

公开(公告)日：1972-04-18

申请号：US3657015D

申请日：1960-05-02

Applicant: STANDARD OIL CO OHIO

Inventor： VEATCH FRANKLIN ,  MILBERGER ERNEST C ,  PRESSON ROBERT D

IPC: H01M8/22 ,  H01M27/26 ,  H01M27/30

CPC classification number: H01M8/222

Abstract: 1. A process for conversion of chemical energy directly into electrical energy which comprises the steps of supplying an aqueous solution of hydrazine to the interface between an anode and an aqueous electrolyte in a fuel cell, supplying an oxidizing agent to the interface between a cathode and an aqueous electrolyte in said fuel cell said anode and cathode being ionically connected, and electrically connecting said anode and cathode through an electrical load.

Abstract translation: 1.一种用于将化学能直接转化为电能的方法，其包括以下步骤：在燃料电池中向阳极和含水电解质之间的界面供应肼水溶液，将氧化剂供应到阴极和 所述燃料电池中的水性电解质，所述阳极和阴极离子连接，并通过电负载电连接所述阳极和阴极。

公开(公告)号：US3919257A

公开(公告)日：1975-11-11

申请号：US33108873

申请日：1973-02-09

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  MIKO STEVEN J

IPC: B01J8/06 ,  B01J23/887 ,  B01J27/057 ,  B01J27/186 ,  C07C5/48 ,  C07C51/215 ,  C07C51/25 ,  C07D307/60

CPC classification number: C07C51/25 ,  B01J8/06 ,  B01J23/8876 ,  B01J27/0576 ,  B01J27/186 ,  B01J2208/00212 ,  B01J2208/00256 ,  B01J2208/00876 ,  B01J2523/00 ,  C07C5/48 ,  C07C51/215 ,  C07C51/252 ,  Y02P20/582 ,  C07C11/167 ,  C07C57/145 ,  B01J2523/13 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/52 ,  B01J2523/34 ,  B01J2523/64 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/43

Abstract: Maleic anhydride is made from n-butane or n-butene in a tubular reactor having an undivided reaction zone which contains two different catalysts-the first catalyst converts at least part of the n-butane or n-butene to butadiene and the second catalyst converts at least part of this product to maleic anhydride.

Abstract translation: 马来酸酐在具有不同的反应区的管式反应器中由正丁烷或正丁烯制成，该反应区包含两种不同的催化剂 - 第一催化剂将至少部分正丁烷或正丁烯转化为丁二烯，第二催化剂转化为 该产物的至少一部分与马来酸酐反应。

公开(公告)号：US3578695A

公开(公告)日：1971-05-11

申请号：US3578695D

申请日：1967-07-26

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  SHAW WILFRID G

IPC: C07C121/32 ,  C07C121/00

CPC classification number: C07C253/10 ,  C07C255/08

Abstract: THE INSTANT APPLICATION DEALS WITH A PROCESS FOR THE MANUFACTURE OF MONOOLEFINICALLY UNSATURATED ALIPHATIC NITRILES BY THE CATALYTIC OXIDATION OF OLEFIN USING CYANIDE AND A MOLECULAR OXYGEN-CONTAINING GAS, BUT NO AMMONIA.

公开(公告)号：US3904653A

公开(公告)日：1975-09-09

申请号：US25066072

申请日：1972-05-05

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  C07C51/23 ,  C07C51/25 ,  C07C51/31 ,  C07D307/60

CPC classification number: B01J23/8876 ,  B01J23/28 ,  B01J23/30 ,  B01J23/8877 ,  B01J2523/00 ,  C07C51/23 ,  C07C51/25 ,  C07C51/252 ,  C07C51/313 ,  C07C57/145 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/22

Abstract: Catalysts containing antimony and molybdenum are promoted by the addition of iron or vanadium or mixture thereof to give very desirable catalysts for the preparation of maleic anhydride from 1,3-butadiene, n-butylenes, crotonaldehyde and furan.

公开(公告)号：CA1172235A

公开(公告)日：1984-08-07

申请号：CA388839

申请日：1981-10-27

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  LEMANSKI MICHAEL F ,  SPITNALE GREGORY G

IPC: C07D307/60 ,  B01J27/18 ,  B01J27/198 ,  C01B25/37 ,  C01B25/45 ,  C07B61/00 ,  C07C51/215 ,  B01J23/22

Abstract: (5246) A process is provided for the preparation of fluid bed oxidation catalysts containing the mixed oxides of vanadium and phosphorus, comprising the steps of preparing the catalyst precursor, comminuting the precursor, introducing the precursor into water to form an aqueous slurry and spray drying the slurry. The resulting microspheroidal particles are excellent fluid, bed catalysts for the preparation of maleic anhydride from 4-carbon atom hydrocarbons. 23.

公开(公告)号：CA1090815A

公开(公告)日：1980-12-02

申请号：CA278087

申请日：1977-05-10

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C ,  EVANS SANDRA R

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/22 ,  B01J23/28 ,  B01J27/00 ,  B01J27/199 ,  B01J37/02 ,  C07B61/00 ,  C07C51/31

Abstract: THE USE OF COATED CATALYSTS IN TEE PREPARATION OF MALEIC ANHYDRIDE Very desirable temperature control and selectivity are obtained in the oxidation of benzene to maleic anhydride using an oxidation catalyst of an essentially inert support of at least 20 microns containing on its outer surface a coating of a catalytically active oxide material or a catalytically active oxide material and an oxide support.

公开(公告)号：ATA220378A

公开(公告)日：1980-01-15

申请号：AT220378

申请日：1978-03-29

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  BREMER NOEL J ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J21/06 ,  B01J27/00 ,  B01J27/18 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Vanadium-free catalysts consisting essentially of oxides of titanium and phosphorus have been found to be especially effective in the oxidation of n-butane, n-butenes and 1,3-butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in good yield and selectivity.

公开(公告)号：DD138209A5

公开(公告)日：1979-10-17

申请号：DD20456778

申请日：1978-04-03

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  WONG EUNICE K T

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  B01J31/00 ,  C07B61/00 ,  C07C51/25 ,  C07C51/31

Abstract: Maleic anhydride is produced by the oxidation of 1,3-butadiene, n-butylenes, crotonaldehyde and furan with molecular oxygen in the vapor phase in the presence of catalytic oxides of antimony, molybdenum, at least one element selected from the group consisting of niobium, zirconium, titanium and tantalum and optionally a reducing agent capable of reducing at least part of the molybdenum in the catalyst to a valence state below +6 selected from the group consisting of hydrazine hydrate, molybdenum, tungsten, magnesium, aluminum, and nickel. This catalyst may optionally contain one or more elements selected from the group consisting of Li, Ag, Ce, Cd, Co, As, Si, Zn, Ge, Bi, Ru, Pt, U, Al and Ni. Especially desirable yields of maleic anhydride are obtained from 1,3-butadiene in the presence of a catalyst wherein molybdenum metal is used as a reducing agent.