公开(公告)号：US3919257A

公开(公告)日：1975-11-11

申请号：US33108873

申请日：1973-02-09

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  MIKO STEVEN J

IPC: B01J8/06 ,  B01J23/887 ,  B01J27/057 ,  B01J27/186 ,  C07C5/48 ,  C07C51/215 ,  C07C51/25 ,  C07D307/60

CPC classification number: C07C51/25 ,  B01J8/06 ,  B01J23/8876 ,  B01J27/0576 ,  B01J27/186 ,  B01J2208/00212 ,  B01J2208/00256 ,  B01J2208/00876 ,  B01J2523/00 ,  C07C5/48 ,  C07C51/215 ,  C07C51/252 ,  Y02P20/582 ,  C07C11/167 ,  C07C57/145 ,  B01J2523/13 ,  B01J2523/51 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  B01J2523/845 ,  B01J2523/847 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/52 ,  B01J2523/34 ,  B01J2523/64 ,  B01J2523/17 ,  B01J2523/31 ,  B01J2523/43

Abstract: Maleic anhydride is made from n-butane or n-butene in a tubular reactor having an undivided reaction zone which contains two different catalysts-the first catalyst converts at least part of the n-butane or n-butene to butadiene and the second catalyst converts at least part of this product to maleic anhydride.

Abstract translation: 马来酸酐在具有不同的反应区的管式反应器中由正丁烷或正丁烯制成，该反应区包含两种不同的催化剂 - 第一催化剂将至少部分正丁烷或正丁烯转化为丁二烯，第二催化剂转化为 该产物的至少一部分与马来酸酐反应。

公开(公告)号：US3928240A

公开(公告)日：1975-12-23

申请号：US39177573

申请日：1973-08-27

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/883 ,  B01J37/16 ,  C07C51/25 ,  C07C51/31 ,  B01J23/16 ,  B01J23/18 ,  B01J23/24

CPC classification number: C07C51/252 ,  B01J23/28 ,  B01J23/30 ,  B01J23/883 ,  B01J37/16 ,  B01J2523/00 ,  C07C51/25 ,  C07C51/313 ,  C07C57/145 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/41 ,  B01J2523/55 ,  B01J2523/51

Abstract: Molybdenum containing oxidation catalysts are prepared by reducing hexavalent molybdenum to a valence state below +6 prior to or during the catalyst preparation. Reproducible catalysts with superior catalytic activity are conveniently made by this process.

Abstract translation: 含钼氧化催化剂通过在催化剂制备之前或期间将六价钼还原成低于+6的价态来制备。 通过该方法可方便地制备具有优异催化活性的可再现催化剂。

公开(公告)号：US3907834A

公开(公告)日：1975-09-23

申请号：US17710571

申请日：1971-09-01

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R ,  HARDMAN HARLEY F

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/28 ,  B01J23/30 ,  B01J23/887 ,  B01J37/16 ,  C07B61/00 ,  C07C51/25 ,  C07C51/31 ,  C07C57/14

CPC classification number: C07C51/252 ,  B01J23/28 ,  B01J23/30 ,  B01J23/8876 ,  B01J37/16 ,  B01J2523/00 ,  C07C51/25 ,  C07C51/313 ,  C07C57/145 ,  B01J2523/53 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/847

Abstract: The process in this invention relates to the conversion of organic compounds selected from the group consisting of the nbutylenes, butadiene, crotonaldehyde and furan in a selective manner to maleic anhydride in the presence of a catalyst comprising the mixed oxides of antimony and molybdenum.

Abstract translation: 本发明的方法涉及在包含锑和钼的混合氧化物的催化剂存在下，将选自正丁烯，丁二烯，巴豆醛和呋喃的有机化合物以选择性方式转化为马来酸酐。

公开(公告)号：US3904653A

公开(公告)日：1975-09-09

申请号：US25066072

申请日：1972-05-05

Applicant: STANDARD OIL CO OHIO

Inventor： MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: B01J23/28 ,  B01J23/30 ,  B01J23/88 ,  C07C51/23 ,  C07C51/25 ,  C07C51/31 ,  C07D307/60

CPC classification number: B01J23/8876 ,  B01J23/28 ,  B01J23/30 ,  B01J23/8877 ,  B01J2523/00 ,  C07C51/23 ,  C07C51/25 ,  C07C51/252 ,  C07C51/313 ,  C07C57/145 ,  C07C57/04 ,  B01J2523/53 ,  B01J2523/55 ,  B01J2523/68 ,  B01J2523/69 ,  B01J2523/842 ,  B01J2523/41 ,  B01J2523/31 ,  B01J2523/847 ,  B01J2523/22

Abstract: Catalysts containing antimony and molybdenum are promoted by the addition of iron or vanadium or mixture thereof to give very desirable catalysts for the preparation of maleic anhydride from 1,3-butadiene, n-butylenes, crotonaldehyde and furan.

公开(公告)号：CA1090815A

公开(公告)日：1980-12-02

申请号：CA278087

申请日：1977-05-10

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C ,  EVANS SANDRA R

IPC: C07D307/60 ,  B01J23/00 ,  B01J23/22 ,  B01J23/28 ,  B01J27/00 ,  B01J27/199 ,  B01J37/02 ,  C07B61/00 ,  C07C51/31

Abstract: THE USE OF COATED CATALYSTS IN TEE PREPARATION OF MALEIC ANHYDRIDE Very desirable temperature control and selectivity are obtained in the oxidation of benzene to maleic anhydride using an oxidation catalyst of an essentially inert support of at least 20 microns containing on its outer surface a coating of a catalytically active oxide material or a catalytically active oxide material and an oxide support.

公开(公告)号：DD132335A5

公开(公告)日：1978-09-20

申请号：DD19872777

申请日：1977-05-03

Applicant: STANDARD OIL CO OHIO

Inventor： SHAW WILFRID G ,  TERRIL DAVID B ,  MILBERGER ERNEST C ,  WOODBURY DAVID R ,  DOLHYJ SERGE R

IPC: C07D307/60 ,  B01J23/28 ,  B01J23/30 ,  B01J23/31 ,  B01J23/32 ,  B01J23/34 ,  B01J23/36 ,  B01J23/68 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04 ,  B01J21/02 ,  B01J23/16 ,  B01J23/54 ,  B01J23/76 ,  C07C51/32

公开(公告)号：CS184784B2

公开(公告)日：1978-09-15

申请号：CS425575

申请日：1975-06-17

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C

IPC: B01J23/00 ,  B01J23/30 ,  B01J23/34 ,  B01J23/88 ,  B01J23/887 ,  B01J23/888 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07C57/04

Abstract: Coated catalysts having an inert support material with an outer surface and a coating of active catalyst containing tungsten, vanadium and molybdenum plus optionally one or more of Fe, Mn, Cu, Sn, Sb, Cr, Ce, U, Co, Ni, Zn, Mg or mixture thereof have been found to be especially effective catalysts for the production of unsaturated acids from the corresponding unsaturated aldehydes, for example, acrolein is oxidized to acrylic acid using these catalysts. The catalysts give a very low exotherm, very high single pass yields of the desired acid and reduce the undesirable by-products.

公开(公告)号：CA998059A

公开(公告)日：1976-10-05

申请号：CA212675

申请日：1974-10-30

Applicant: STANDARD OIL CO OHIO

Inventor： BREMER NOEL J ,  MILBERGER ERNEST C ,  DOLHYJ SERGE R

IPC: C07D307/60 ,  B01J23/22 ,  B01J27/00 ,  B01J27/198 ,  C07B61/00 ,  C07C51/215 ,  C07C51/25

Abstract: Catalysts containing the oxides of vanadium, phosphorus and uranium have been found to be especially effective in the oxidation of n-butane, n-butenes and butadiene with molecular oxygen in the vapor phase to yield maleic anhydride. The reaction with n-butane gives an especially pure product in high yield.

公开(公告)号：CA1152109A

公开(公告)日：1983-08-16

申请号：CA366876

申请日：1980-12-16

Applicant: STANDARD OIL CO OHIO

Inventor： SUNDEEN MARCIA H ,  VELENYI LOUIS J ,  DOLHYJ SERGE R

IPC: B01J31/00 ,  C07C67/00 ,  C07C407/00 ,  C07C409/02 ,  C07C409/08 ,  C07C409/10 ,  C07C409/14 ,  C07C179/035

Abstract: MANUFACTURE OF HYDROPEROXIDES Hydroperoxides, such as cyclohexylbenzene hydroperoxide, are manufactured by the oxidation of aryl compounds, such as cyclohexylbenzene, in the presence of a catalyst selected from the group consisting of C6 - C18 primary amines and polyvinylpyrrolidone.

公开(公告)号：CS212754B2

公开(公告)日：1982-03-26

申请号：CS904174

申请日：1974-12-27

Applicant: STANDARD OIL CO OHIO

Inventor： DOLHYJ SERGE R ,  MILBERGER ERNEST C ,  BREMER NOEL J

IPC: C07C69/54 ,  B01J23/12 ,  B01J23/22 ,  B01J23/24 ,  B01J23/30 ,  B01J23/31 ,  B01J23/34 ,  B01J23/84 ,  B01J23/88 ,  B01J23/888 ,  B01J23/89 ,  B01J27/198 ,  B01J27/199 ,  C07B61/00 ,  C07C51/00 ,  C07C51/25 ,  C07C57/055 ,  C07C67/00 ,  C07D307/60