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公开(公告)号:JPH11181215A
公开(公告)日:1999-07-06
申请号:JP35814597
申请日:1997-12-25
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , TAMURA SHINICHI
IPC: C08K5/3477 , C08K5/521 , C08L51/04 , C08L55/02
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition having permanent antistaticity and excellent flame retardancy, mechanical properties and molding processability by compounding each specific amount of a phosphorusbased flame retardant and another component in a resin composition comprising a rubber-reinforced styrene-based resin and a polymer having a specific electrical resistance. SOLUTION: This composition is obtained by compounding (A) 100 pts.wt. of a resin composition composed of (1) 60-99 wt.% of a rubberreinforced styrene- based resin and (2) 1-40 wt.% of a polymer with a volume resistivity of Ωcm with (B) 1-30 pts.wt. of an organophosphorus compound of formula I [X is an arylene; R to R are each a (substituted) phenyl; (n) is >=0; (k) and (m) are each 0-2, and (k+m) is 0-2] and (C) 0.1-20 pts.wt. of a mixture of (1) 1-40 wt.% of a salt made from a compound of formula II (R is an aryl or the like; R to R are each H, an aryl, aralkyl, cycloalkyl or the like) and cyanuric or isocyanuric acid and (2) 99-60 wt.% of a polyamide resin.
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公开(公告)号:JPH1129686A
公开(公告)日:1999-02-02
申请号:JP18241697
申请日:1997-07-08
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , TAMURA SHINICHI
IPC: B29C45/00 , B29K96/02 , C08K5/3492 , C08K5/521 , C08L51/04
Abstract: PROBLEM TO BE SOLVED: To obtain the subject composition capable of providing self- extinguishable a molding product having excellent flame retardance in terms of drip, and extremely superior in thermal stability, molding processability, and falling weight impact resistance of a thin-wall product. SOLUTION: This composition is obtained by compounding (A) 100 pts.wt. rubber-reinforced styrenic resin, (B) 1-30 pts.wt. organic phosphorus compound of formula I [X is an arylene; R to R are each a (substituted) phenyl], (C) 0.1-20 pts.wt. mixture of (i) 1-40 wt.% salt of a compound of formula II (R to R are each H, an aryl, an alkyl, etc.; R is NR R , NR R , etc.), and cyanuric acid or isocyanuric acid with (ii) 99-60 wt.% polyamide resin. Preferably, the component C is previlusly melted and kneaded at 190-300 deg.C.
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公开(公告)号:JPH10120892A
公开(公告)日:1998-05-12
申请号:JP27967596
申请日:1996-10-22
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , TAMURA SHINICHI , YAMAUCHI KOJI
Abstract: PROBLEM TO BE SOLVED: To obtain a thermoplastic resin composition excellent in impact resistance, heat resistance, molding flowability and flame retardancy by mixing a mixture of an aromatic polycarbonate with an ABS resin with a specified polyphosphate and a fluororesin. SOLUTION: This composition is prepared by mixing 100 pts.wt. resin composition comprising 10-98wt.% aromatic polycarbonate, 90-2wt.% graft (co)polymer prepared by grafting an aromatic vinyl monomer or a mixture thereof onto a rubbery polymer and 0-88wt.% vinyl polymer prepared by polymerizing a monomer comprising 20-100wt.% aromatic vinyl monomer, 0-60wt.% vinyl cyanide monomer and 0-80wt.% other copolymerizable vinyl monomers or a mixture thereof with 1-100 pts.wt. phosphorus-containing polymer having a glass transition temperature of 120 deg.C or below, 0-20 pts.wt. phenolic resin and 0.01-5 pts.wt. fluororesin and/or 0.01-5 pts.wt. silicon-containing polymer.
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公开(公告)号:JPH09216979A
公开(公告)日:1997-08-19
申请号:JP3163497
申请日:1997-02-17
Applicant: TORAY INDUSTRIES
Inventor: YANO KAZUHISA , FUKUMOTO TADAO , IWAMOTO MASAAKI
IPC: C08J5/00 , C08L25/12 , C08L33/00 , C08L33/04 , C08L33/14 , C08L33/18 , C08L55/00 , C08L55/02 , C08L67/00 , C08L67/02
Abstract: PROBLEM TO BE SOLVED: To obtain a molding having the chemical and heat resistances inherent in the constituent polyester and the impact resistance higher than that of the ABS resin without detriment to the moldability inherent in the constituent ABS resin. SOLUTION: This molding is made from a thermoplastic resin composition comprising 1-98 pts.wt. ABS resin (A), 98-1 pt.wt. aromatic polyester resin (B), and 1-70 pts.wt. modified vinyl polymer (C) comprising an aromatic vinyl, vinyl cyanide and an epoxidized vinyl monomer (the total of components A to C being 100 pts.wt.) and having a diene rubber content of 5-50wt.%.
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公开(公告)号:JP2546313B2
公开(公告)日:1996-10-23
申请号:JP33629987
申请日:1987-12-29
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , YANO KAZUHISA , IWAMOTO MASAAKI
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公开(公告)号:JPH0684462B2
公开(公告)日:1994-10-26
申请号:JP28153887
申请日:1987-11-06
Applicant: TORAY INDUSTRIES
Inventor: YANO KAZUHISA , FUKUMOTO TADAO , IWAMOTO MASAAKI
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公开(公告)号:JPH0680138B2
公开(公告)日:1994-10-12
申请号:JP8946585
申请日:1985-04-25
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , IWAMOTO MASAAKI , KISHIMOTO AKIHIKO
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公开(公告)号:JPH05202239A
公开(公告)日:1993-08-10
申请号:JP1246692
申请日:1992-01-28
Applicant: TORAY INDUSTRIES
Inventor: TANAKA SEIJI , FUKUMOTO TADAO , CHIBA KAZUMASA
Abstract: PURPOSE:To obtain the title composition having permanent antistatic properties, not causing the exudation of the constituent polyether ester amide and excellent in mechanical properties. CONSTITUTION:The title composition comprises a polyolefin (A), a polyether ester amide (B) and a polyamide (C), wherein the weight ratio (A) to (B) is (10-99)/(90-1), and the amount of (C) added is 1-50 pts.wt. per 100 pts.wt. total of (A) and (B).
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公开(公告)号:JPH0524175B2
公开(公告)日:1993-04-07
申请号:JP22906988
申请日:1988-09-13
Applicant: TORAY INDUSTRIES
Inventor: FUKUMOTO TADAO , YANO KAZUHISA , IWAMOTO MASAAKI
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公开(公告)号:JPH02127457A
公开(公告)日:1990-05-16
申请号:JP28102388
申请日:1988-11-07
Applicant: TORAY INDUSTRIES
Inventor: YANO KAZUHISA , FUKUMOTO TADAO , IWAMOTO MASAAKI
Abstract: PURPOSE:To obtain the subject composition, excellent in molding processability, impact, chemical resistance and surface appearance and suitable as automotive exterior trim parts, etc., by blending a graft copolymer prepared by carrying out graft copolymerization of a specific monomer mixture onto a diene-based rubber with a polyamide resin in a specified proportion. CONSTITUTION:A thermoplastic resin composition obtained by blending (A) 5-95 pts.wt., preferably 10-85 pts.wt. graft copolymer prepared by grafting 90-15 pts.wt. monomer mixture consisting of (A2) (i) 50-90wt.% aromatic vinyl compound (e.g., styrene), (ii) 9-50wt.% vinyl cyanide (e.g., acrylonitrile) and (iii) 0.1-20wt.% alpha,beta-unsaturated carboxylic acid (metal salt) satisfying a relationship expressed by the formula (x is wt.% of the metal salt of the alpha,beta-unsaturated carboxylic acid; y is wt.% of the alpha,beta-unsaturated carboxylic acid) onto (A1) 10-85 pts.wt. diene-based rubber (e.g., polybutadiene) with (B) 5-95 pts.wt., preferably 15-90 pts.wt. polyamide resin (e.g., nylon 6).
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