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公开(公告)号:DE69005477D1
公开(公告)日:1994-02-10
申请号:DE69005477
申请日:1990-02-21
Applicant: TORAY INDUSTRIES
Inventor: IGUCHI YUICHIRO , KIMURA MICHIO , OKA KOICHIRO
IPC: C07C327/22 , C08F20/38 , C08F28/02 , G02B1/04
Abstract: A thiol methacrylate or acrylate compound represented by the formula (1) or (2): wherein R is H or CH3 and X is selected from: wherein R is H or CH3 and m is an integer of 1 to 4, is polymerizable to obtain a resin having a high refractive index, a large Abbe number, and a good hardness and heat resistance, and giving little or no smell on processing.
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公开(公告)号:DE3874507D1
公开(公告)日:1992-10-15
申请号:DE3874507
申请日:1988-12-27
Applicant: TORAY INDUSTRIES
Inventor: YAMADA BUNSHI , KIMURA MICHIO , NOGUCHI YOSHIO
IPC: C07C17/389 , C07C25/02 , C07C17/38
Abstract: A specific isomer of dichlorocumene is separated from a mixure containing dichlorocumene isomers by adsorptive separation, wherein the zeolite having at least 2 of silica/alumina molar ratio and 0.6 to 1.0 nm of pore size is used as the adsorbent and halogenated benzene or halogenated alkyl benzene is used as desorbent.
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公开(公告)号:CA2010364A1
公开(公告)日:1990-08-22
申请号:CA2010364
申请日:1990-02-19
Applicant: TORAY INDUSTRIES
Inventor: IGUCHI YUICHIRO , KIMURA MICHIO , OKA KOICHIRO
IPC: C07C327/22 , C08F20/38 , C08F28/02 , G02B1/04
Abstract: A thiol methacrylate or acrylate compound represented by the formula (1) or (2): wherein R is H or CH3 and X is selected from: wherein R is H or CH3 and m is an integer of 1 to 4, is polymerizable to obtain a resin having a high refractive index, a large Abbe number, and a good hardness and heat resistance, and giving little or no smell on processing.
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公开(公告)号:JP2002265597A
公开(公告)日:2002-09-18
申请号:JP2001064145
申请日:2001-03-07
Applicant: TORAY INDUSTRIES
Inventor: TOKUNAGA YUJI , KIMURA MICHIO , HORI HIDEO
Abstract: PROBLEM TO BE SOLVED: To provide a nylon 6 copolymer which controls the formation of white foreign matters without reducing the liquid and solid phase polymerization rate and has affinity to basic dyes. SOLUTION: In the method of manufacturing a nylon 6 copolymer by polymerizing ε-caprolactam, at least 0.1-3 mol% of a dialkyl ester of at least one kind of dicarboxysulfonate compound is added to the ε-caprolactam and further adding 10-90 mol% of a diamine compound is added to the sulfonate compound, and the fiber is prepared therefrom.
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公开(公告)号:JPH05181020A
公开(公告)日:1993-07-23
申请号:JP34591691
申请日:1991-12-27
Applicant: TORAY INDUSTRIES
Inventor: KIMURA MICHIO , OKA KOICHIRO
IPC: G02B6/00
Abstract: PURPOSE:To provide a surface light source for which this light transmission body is used and which has high surface brightness and excellent uniformity by constituting the light transmission body of a transparent plate, the medium of which has a refractive index distribution. CONSTITUTION:The transparent plate having the refractive index distribution is exemplified by a flat plate having the refractive index continuously changing in the thickness direction of the plate. Namely, parallel ray of light 4 of light entering from the end edge 2 of the transparent plate 1 having the refractive index distribution are bent to a high-refractive index side and arrive at a high- refractive index surface 3. The effect of the light transmission body is further enhanced by subjecting the high-refractive index surface 3 of the transparent plate 1 to a light diffusion treatment. The method of the light diffusion treatment is exemplified by finishing the surface to a satin state by sandpapering or honing, etc. The light arriving at the high-refractive index surface 3 is diffused by the light diffusion treatment of the surface and is emitted from the low-refractive index surface 5.
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公开(公告)号:JPH05181001A
公开(公告)日:1993-07-23
申请号:JP34591791
申请日:1991-12-27
Applicant: TORAY INDUSTRIES
Inventor: KIMURA MICHIO , OKA KOICHIRO
IPC: G02B1/04
Abstract: PURPOSE:To obtain a molding having high surface hardness and excellent heat resistance by a stage for mixing specific monomers A, B and a stage for polymerizing or curing a mixture composed thereof while or after imparting local polymn. conditions to this mixture. CONSTITUTION:The radical polymerizable monomer A and the monomer which is polymerized by reaction forms (polycondensation reaction, ring-opening- addition, etc.) are mixed to prepare a uniform soln. The uniform soln. is then packed into a container made of glass or resin and the local polymn. conditions are imparted thereto to cause the radical polymn. or the polymn. exclusive of the radical polymn. or curing to solidify the compsn. distribution. The bar- shaped body taken out of a glass tube is colorless and transparent and is cut and polished, by which a transparent plate 1 acting as a convex lens is obtd. The difference in the refractive index between the front surface (low-refractive index surface) 5 and the rear surface (high-refractive index surface) 3 is 0.025 and the refractive index changes continuously. The surface hardness is extremely high.
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公开(公告)号:JPH0513143B2
公开(公告)日:1993-02-19
申请号:JP25156184
申请日:1984-11-30
Applicant: TORAY INDUSTRIES
Inventor: KIMURA MICHIO , NOGUCHI YOSHIO
IPC: C07C201/16 , C07C67/00 , C07C201/00 , C07C205/44
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公开(公告)号:JPH04335029A
公开(公告)日:1992-11-24
申请号:JP10604691
申请日:1991-05-10
Applicant: TORAY INDUSTRIES
Inventor: KARASAWA HIROO , KIMURA MICHIO , KOBAYASHI KAZUHIKO
IPC: C08G75/10 , C08G75/02 , C08G75/0227 , C08G75/0254
Abstract: PURPOSE:To produce a polyarylene sulfide ketone having a high melt stability and a high heat resistance in a short time at a high yield by reacting a specific dihalogenated aryl ketone with an alkali metal sulfide in the presence of a quinone. CONSTITUTION:1mol of a dihalogenated aryl ketone of the formula (wherein R1, R2, R3, and R4 are each a 1-12C alkyl group, an arom. group, an alicyclic group, or a hydrogen atom; and X is a halogen atom) is reacted with 0.95-1.05-mol (in terms of total sulfur content) of an alkali metal sulfide in the presence of a quinone.
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公开(公告)号:JPH0358333B2
公开(公告)日:1991-09-05
申请号:JP5044083
申请日:1983-03-28
Applicant: TORAY INDUSTRIES
Inventor: MANGAYA YASUHIRO , KIMURA MICHIO , NOGUCHI YOSHIO
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公开(公告)号:JPH02261808A
公开(公告)日:1990-10-24
申请号:JP8212989
申请日:1989-03-31
Applicant: TORAY INDUSTRIES
Inventor: IGUCHI YUICHIRO , KIMURA MICHIO , OKA KOICHIRO
IPC: B29D11/00 , C08F16/00 , C08F18/00 , C08F18/24 , C08F290/00 , C08F299/00
Abstract: PURPOSE:To obtain a resin with high refractive index, excellent impact resistance and no generation of odor caused by hydrolysis by radical-polymerizing a monomer contg. a polyfunctional sulfur-contg. allyl carbonate as an essential component. CONSTITUTION:A monomer contg. at least one of polyfunctional sulfur-contg. allyl carbonates as an essential component is used for preparing a high refractive index resin by radical polymerization. It is pref. that at least one monomer selected from those of formulas I, II and III is used as the carbonate. In formulas I-III, (m) is 0 to 5; (n) is an integer of 0 to 4; R1 and R2 are each hydrogen, a 1 to 5C alkyl group or a sulfur-contg. substituent consisting of alpha S-groups and beta groups selected from CH2, formulas IV and V (wherein S-S is not incorporated; alpha is an integer of 1 to 5; beta is an integer of 1 to 10;); X is O or S; Y is O or S; provided that the case where both X and Y are O is included.
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