公开(公告)号：EP0086292A1

公开(公告)日：1983-08-24

申请号：EP82300744.8

申请日：1982-02-15

Applicant: THE STANDARD OIL COMPANY

Inventor： Friedrich, Maria Strada ,  Grasselli, Robert Karl ,  Suresh, Dev Dhanaraj

IPC: B01J23/88 ,  C07C5/48 ,  C07C45/34 ,  C07C51/00 ,  C07C120/14

CPC classification number: B01J23/8872 ,  B01J23/8874 ,  B01J23/8875 ,  B01J23/8876 ,  B01J23/8878 ,  B01J27/0515 ,  B01J27/0576 ,  B01J27/19 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/34 ,  C07C51/25 ,  C07C51/252 ,  C07C253/26 ,  Y02P20/52 ,  C07C11/12 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/842 ,  C07C255/08

Abstract: A process for improving the catalytic properties of a substantially crystalline iron bismuth molybdate oxide complex interim catalyst comprises incorporating at least one element from Groups IA, IB, IIB, IIIA and IIIB of the periodic Table into the catalyst by impregnation, none of the Group IA elements incorporated into the catalyst by impregnation being derived from a molybdate or silicate. The catalysts provide improved results in oxidation type reactions.

Abstract translation: 一种用于改善基本上结晶的铁钼酸铋氧化物复合临时催化剂的催化性能的方法包括选自IA，IB，IIB，IIIA和周期表的IIIB结合的至少一种元素到催化剂通过浸渍，没有IA族的 掺入到通过浸渍催化剂元件从钼酸盐或硅酸盐得到的。 催化剂提供在氧化型反应改善的结果。

公开(公告)号：EP0085815A1

公开(公告)日：1983-08-17

申请号：EP82306965.3

申请日：1982-12-24

Applicant: THE STANDARD OIL COMPANY

Inventor： Coffey, Gerald Paul ,  Cepulis, Rimvydas L. ,  Curatolo, Benedict Salvatore

IPC: C08G69/00 ,  C08G69/08

CPC classification number: C08G69/00 ,  C08G69/28

Abstract: A polyamide is produced by polymerizing at least one of alpha, beta unsaturated carboxylic acid, an ammonium salt of an alpha, beta unsaturated carboxylic acid, an alpha, beta unsaturated nitrile and water, a beta-amino propionic acid or alkyl derivative thereof and an alpha, beta unsaturated amide and ammonia in the presence of a catalyst containing cobalt. Preferred catalysts comprise cobaltous carboxylates and cobaltic salts of the enol of beta-di-ketones.

公开(公告)号：EP0016882B1

公开(公告)日：1983-07-27

申请号：EP79300539.8

申请日：1979-04-02

Applicant: THE STANDARD OIL COMPANY

Inventor： Rosen, Irving

IPC: C08L33/20 ,  C08L33/12 ,  C08L51/04

CPC classification number: C08L33/20 ,  C08L25/12 ,  C08L25/14 ,  C08L33/12 ,  C08L51/04 ,  C08L55/02 ,  C08L2666/24 ,  C08L2666/04

公开(公告)号：EP0082692A2

公开(公告)日：1983-06-29

申请号：EP82306754.1

申请日：1982-12-17

Applicant: THE STANDARD OIL COMPANY

Inventor： Pesa, Frederick Anthony ,  Graham, Anne Marie

IPC: B01J23/89 ,  B01J27/24 ,  C07C1/04 ,  C07C27/20 ,  C07C29/15 ,  C07C29/14 ,  C07C29/136 ,  C07C51/10

CPC classification number: C07C51/10 ,  B01J23/89 ,  B01J23/8946 ,  B01J27/24 ,  C07C1/0435 ,  C07C1/0485 ,  C07C9/00 ,  C07C29/157 ,  C07C29/158 ,  C07C31/04 ,  C07C31/08 ,  C07C2521/04 ,  C07C2521/08 ,  C07C2521/12 ,  C07C2521/16 ,  C07C2523/04 ,  C07C2523/42 ,  C07C2523/46 ,  C07C2523/72 ,  C07C2523/89 ,  C07C2527/224 ,  C07C2527/24 ,  Y02P20/52 ,  C07C31/10 ,  C07C31/12 ,  C07C31/125

Abstract: A process of upgrading synthesis gas to hydrocarbons and oxygenated hydrocarbons, particularly olefins and carboxylic acids, comprises contacting synthesis gas with catalysts comprising the mixed oxides of ruthenium, copper, an alkali or alkaline earth metal, and optionally a metal selected from Ce, Cr, Fe, Mn, Mo, Th, Zn or mixtures thereof. The synthesis gas upgrading product may be contacted with a hydrogenation catalyst to provide alkanes, alcohols and esters, useful for fuels.
Catalysts comprising the mixed oxides of ruthenium, copper, at least one alkali metal and at least one of rhodium, iridium, palladium, and platinum are further disclosed which are useful in the upgrading of synthesis gas, particularly for obtaining alkanes and alcohols.

Abstract translation: 将合成气升级成烃和含氧烃，特别是烯烃和羧酸的方法包括使合成气与包含钌，铜，碱金属或碱土金属的混合氧化物和任选的选自Ce，Cr， Fe，Mn，Mo，Th，Zn或其混合物。 合成气改质产物可以与氢化催化剂接触以提供可用于燃料的烷烃，醇和酯。 还公开了包含钌，铜，至少一种碱金属和铑，铱，钯和铂中的至少一种的混合氧化物的催化剂，其可用于合成气的升级，特别是用于获得烷烃和醇。

公开(公告)号：EP0016614B1

公开(公告)日：1983-06-01

申请号：EP80300774.9

申请日：1980-03-13

Applicant: THE STANDARD OIL COMPANY

Inventor： Wiggins, Wayne Thomas ,  Gerry, Frank Scott

IPC: B32B27/08 ,  B32B27/30

CPC classification number: B32B27/08 ,  B32B7/12 ,  B32B27/28 ,  B32B27/32 ,  B32B27/322

公开(公告)号：EP0064821A3

公开(公告)日：1983-05-18

申请号：EP82301991

申请日：1982-04-19

Applicant: THE STANDARD OIL COMPANY

Inventor： BRAZDIL, JAMES FRANK ,  SURESH, DEV DHANARAJ ,  GRASSELLI, ROBERT KARL

IPC: C07C57/055 ,  B01J23/31 ,  B01J23/68 ,  B01J23/88 ,  B01J23/885 ,  B01J27/057 ,  C07B61/00 ,  C07C1/00 ,  C07C5/48 ,  C07C11/02 ,  C07C45/00 ,  C07C45/34 ,  C07C45/35 ,  C07C45/37 ,  C07C45/38 ,  C07C47/22 ,  C07C51/00 ,  C07C51/21 ,  C07C67/00 ,  C07C253/00 ,  C07C255/08 ,  C07C120/14 ,  C07C121/32

CPC classification number: C07C253/26 ,  B01J23/31 ,  B01J23/686 ,  B01J23/885 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/34 ,  C07C45/35 ,  C07C45/37 ,  C07C45/38 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/18 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/31 ,  C07C2523/50 ,  C07C2523/72 ,  C07C2527/057 ,  Y02P20/52 ,  C07C47/22 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/15 ,  B01J2523/34 ,  B01J2523/69 ,  B01J2523/41 ,  B01J2523/53 ,  B01J2523/67 ,  B01J2523/64 ,  B01J2523/3706 ,  B01J2523/36 ,  B01J2523/3718 ,  B01J2523/3725 ,  B01J2523/47 ,  C07C255/08

公开(公告)号：EP0077424A1

公开(公告)日：1983-04-27

申请号：EP81304939.2

申请日：1981-10-21

Applicant: THE STANDARD OIL COMPANY

Inventor： Shaw, Wilfrid Garside ,  Paparizos, Christos ,  Velenyi, Louis Joseph

IPC: B01D53/34

CPC classification number: B01D53/56 ,  B01D53/8628

Abstract: A process for the conversion of oxides of nitrogen to nitrogen gas comprises the step of passing the oxide of nitrogen over a reactant carbon fiber material at a temperature of from 450°C to 750°C. The process may be carried out continuously, a carbon-containing gas such as carbon monoxide or methane being passed with the oxide of nitrogen over the reactant carbon fiber material optionally with the co-use of hydrogen. The reactant carbon fiber material may comprise carbon and a host material comprising reduced metal and a support material.

Abstract translation: 将氮氧化物转化为氮气的方法包括在450℃至750℃的温度下使氮氧化物通过反应物碳纤维材料的步骤。该方法可以连续进行，碳 （如一氧化碳或甲烷）与氮氧化物一起通过反应物碳纤维材料，任选与氢气共同使用。 反应物碳纤维材料可以包含碳和主体材料，其包含还原金属和载体材料。

公开(公告)号：EP0066413A1

公开(公告)日：1982-12-08

申请号：EP82302550.7

申请日：1982-05-19

Applicant: THE STANDARD OIL COMPANY

Inventor： Isley, Ralph Eugene

IPC: C08L33/20 ,  C08L25/12 ,  C08L55/02

CPC classification number: C08K3/34 ,  C08K3/26 ,  C08K5/09 ,  C08L33/20

Abstract: A nitrile barrier resin composition which comprises a blend of (1) a copolymer produced by the polymerization of a major proportion of a mono-unsaturated nitrile and a minor proportion of another monovinyl monomer component polymerizable therewith optionally in the presence of a preformed diene rubber; (2) a carboxylic acid; and (3) an alkaline filler containing a polyvalent cation.
The physical properties of a nitrile barrier resin, particularly the tensile modulus, heat distortion temperature and processability, are improved by including therein the carboxylic acid processing aid and the alkaline filler material.

Abstract translation: 腈阻隔树脂组合物，其包含（1）通过主要部分的单不饱和腈的聚合制得的共聚物和可预聚合的二烯橡胶存在下可聚合的另一种单乙烯基单体组分的少量的共聚物; （2）羧酸; 和（3）含有多价阳离子的碱性填料。 腈类阻隔性树脂的物性，特别是拉伸模量，热变形温度和加工性，通过在其中包含羧酸加工助剂和碱性填料而提高。

公开(公告)号：EP0064821A2

公开(公告)日：1982-11-17

申请号：EP82301991.4

申请日：1982-04-19

Applicant: THE STANDARD OIL COMPANY

Inventor： Brazdil, James Frank ,  Suresh, Dev Dhanaraj ,  Grasselli, Robert Karl

IPC: B01J23/31 ,  C07C120/14 ,  C07C121/32

CPC classification number: C07C253/26 ,  B01J23/31 ,  B01J23/686 ,  B01J23/885 ,  B01J2523/00 ,  C07C5/48 ,  C07C45/34 ,  C07C45/35 ,  C07C45/37 ,  C07C45/38 ,  C07C2521/06 ,  C07C2523/04 ,  C07C2523/08 ,  C07C2523/10 ,  C07C2523/12 ,  C07C2523/18 ,  C07C2523/26 ,  C07C2523/28 ,  C07C2523/31 ,  C07C2523/50 ,  C07C2523/72 ,  C07C2527/057 ,  Y02P20/52 ,  C07C47/22 ,  B01J2523/13 ,  B01J2523/3712 ,  B01J2523/54 ,  B01J2523/68 ,  B01J2523/15 ,  B01J2523/34 ,  B01J2523/69 ,  B01J2523/41 ,  B01J2523/53 ,  B01J2523/67 ,  B01J2523/64 ,  B01J2523/3706 ,  B01J2523/36 ,  B01J2523/3718 ,  B01J2523/3725 ,  B01J2523/47 ,  C07C255/08

Abstract: A bismuth cerium molybdate catalysts oxide complex catalyst contains a promoting amount of an alkali metal TI, Sm, Ag, Cu, Cr, Sb, rare earth metal other than Ce and Sm, Te, Ti, Zr, Th or mixture thereof.
Such catalyst provides high yields of acrylonitrile in the ammoxidation of propylene and give improved results in other oxidation-type reactions.

Abstract translation: 钼酸铋催化剂氧化物络合物催化剂含有除Ce和Sm，Te，Ti，Zr，Th或其混合物之外的碱金属Ti，Sm，Ag，Cu，Cr，Sb，稀土金属的促进量。 这种催化剂在丙烯的氨氧化中提供高产率的丙烯腈，并在其它氧化型反应中得到改善的结果。

公开(公告)号：EP0061830A1

公开(公告)日：1982-10-06

申请号：EP82300739.8

申请日：1982-02-15

Applicant: THE STANDARD OIL COMPANY

Inventor： Callahan, James Louis ,  Shaw, Wilfrid Garside ,  Grasselli, Robert Karl

IPC: B01J37/02 ,  B01J37/04 ,  C07C45/35 ,  C07C51/25

CPC classification number: B01J37/04 ,  B01J35/0006 ,  B01J37/0203 ,  C07C45/35 ,  C07C47/22

Abstract: A composite oxidation catalyst is prepared by forming and activating a first oxidation catalyst; forming a second oxidation catalyst; contacting the first catalyst with the second catalyst and a substantially non-aqueous organic fluid to form a composite catalyst; and drying the composite catalyst. The second catalyst may be formed in situ on the first. The catalyst has utility in preparing unsaturated aldehydes and acids from propylene and isobutylene in a single reactor.

Abstract translation: 一种复合氧化催化剂通过形成和激活第一氧化催化剂制备 形成第二氧化催化剂; 接触，第二催化剂和基本上非水有机液体以形成复合催化剂的第一催化剂; 并干燥该复合催化剂。 第二催化剂可以原位形成在第一。 该催化剂具有在单个反应器中制备丙烯和异丁烯的不饱和醛和酸的效用。