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1.发明公开Mo-Bi-Fe-Ca based catalyst for the manufacture of acrylonitrile and hydrogen cyanide 审中-公开含Mo，铋，Fe，Ca的丙烯腈和氰化氢的催化剂制造
公开(公告)号：EP0900592A1
公开(公告)日：1999-03-10
申请号：EP98306542.6
申请日：1998-08-17
Applicant: THE STANDARD OIL COMPANY
Inventor： Friedrich, Maria Strada , Drenski, Tama Lee , Paparizos, Christos , Seely, Michael J. , Suresh, Dev Dhanaraj
IPC: B01J23/881 , B01J23/887 , C01C3/02 , C07C253/26
CPC classification number: C07C253/18 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J37/0045 , B01J37/08 , B01J2523/00 , C01C3/0216 , C01G53/006 , Y02P20/52 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , C07C255/08
Abstract: A catalyst composition comprising a complex of catalytic oxides of iron, bismuth, molybdenum and calcium and characterized by the following empirical formula:
A a B b C c D d Fe e Bi f Mo 12 O x
where
A = one or more of Li, Na, K, Rb and Cs or mixtures thereof
B = one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures thereof
C = one or more of Ce, Cr, Al, Sb, P, Ge, La, Sn, V and W or mixtures thereof
D = one or more of Ca, Sr, Ba or mixtures thereof
and a = 0.01 to 1.0; b and e = 1.0 - 10;
c, d, and f = 0.1 to 5.0 and x is a number determined by the valence requirements of the other elements present.-
2.发明公开Catalytic process for the manufacture of acrylonitrile and hydrogen cyanide 审中-公开Kalalytisches Verfahren zur Produktion von Acrylnitril undBlausäure
公开(公告)号：EP1321188A1
公开(公告)日：2003-06-25
申请号：EP03075784.3
申请日：1998-08-17
Applicant: The Standard Oil Company
Inventor： Drenski, Tama Lee , Friedrich, Maria Strada , Seely, Michael J. , Paparizos, Christos , Suresh, Dev Dhanaraj
IPC: B01J23/881 , B01J23/887 , C01C3/02 , C07C253/26
CPC classification number: C07C253/18 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J37/0045 , B01J37/08 , B01J2523/00 , C01C3/0216 , C01G53/006 , Y02P20/52 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , C07C255/08
Abstract: A process for preparing acrylonitrile comprises ammoxidising propylene in the presence of a complex oxide catalyst having the empirical formula:
A a B b C c D d Fe e Bi f Mo 12 O x
where A is Cs, K or mixtures thereof
B is one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures
thereof
C is one or more of Ce, Cr, P, Ge and mixtures thereof
D is Ca and optionally one of Sr, Ba or mixtures thereof
and a = 0.01 to 1.0
b and e = 1.0 to 10
c, d and f = 0.1 to 5.0
and x is a number determined by the valence requirements of the other elements present.Abstract translation: 制备丙烯腈的方法包括在具有以下经验式的复合氧化物催化剂存在下使丙烯氨氧化：AaBbCcDdFeeBifMo12Ox其中A为Cs，K或其混合物。B为Mg，Mn，Ni，Co，Ag，Pb，Re中的一种或多种 ，Cd和Zn或其混合物C是Ce，Cr，P，Ge及其混合物中的一种或多种，D是Ca和任选的Sr，Ba或其混合物中的一种，a = 0.01至1.0b且e = 1.0至10c ，d和f = 0.1至5.0，x是由其它存在的元素的化合价要求确定的数。
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Patent Agency Ranking3.发明公开Regeneration of molybdenum based catalysts by the addition of ammonium dimolybdate 审中-公开通过加入硫酸铵含钼催化剂的再生
公开(公告)号：EP0922492A1
公开(公告)日：1999-06-16
申请号：EP98309585.2
申请日：1998-11-24
Applicant: THE STANDARD OIL COMPANY
Inventor： Drenski, Tama Lee , Seely, Michael J. , Friedrich, Maria Strada , Suresh, Dev Dhanaraj , Paparizos, Christos
Abstract: A process for regenerating molybdenum containing ammoxidation catalyst comprising replacing the molybdenum loss from the catalyst during the ammoxidation reaction wherein ammonium dimolybdenum is utilized as the source for replacement of the molybdenum loss from the original catalyst.
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4.发明公开Production of catalysts by impregnation and use thereof in oxidation type reactions 无效通过浸渍和它们的氧化反应使用催化剂的制备。
公开(公告)号：EP0086292A1
公开(公告)日：1983-08-24
申请号：EP82300744.8
申请日：1982-02-15
Applicant: THE STANDARD OIL COMPANY
IPC: B01J23/88 , C07C5/48 , C07C45/34 , C07C51/00 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J23/8878 , B01J27/0515 , B01J27/0576 , B01J27/19 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C51/25 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C11/12 , B01J2523/54 , B01J2523/68 , B01J2523/842 , C07C255/08
Abstract: A process for improving the catalytic properties of a substantially crystalline iron bismuth molybdate oxide complex interim catalyst comprises incorporating at least one element from Groups IA, IB, IIB, IIIA and IIIB of the periodic Table into the catalyst by impregnation, none of the Group IA elements incorporated into the catalyst by impregnation being derived from a molybdate or silicate. The catalysts provide improved results in oxidation type reactions.
Abstract translation: 一种用于改善基本上结晶的铁钼酸铋氧化物复合临时催化剂的催化性能的方法包括选自IA，IB，IIB，IIIA和周期表的IIIB结合的至少一种元素到催化剂通过浸渍，没有IA族的 掺入到通过浸渍催化剂元件从钼酸盐或硅酸盐得到的。 催化剂提供在氧化型反应改善的结果。
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5.发明授权Production of catalysts by impregnation and use thereof in oxidation type reactions 无效通过在氧化反应中产生催化剂并使用它们
公开(公告)号：EP0086292B1
公开(公告)日：1986-04-23
申请号：EP82300744.8
申请日：1982-02-15
Applicant: THE STANDARD OIL COMPANY
IPC: B01J23/88 , C07C5/48 , C07C45/34 , C07C51/00 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J23/8878 , B01J27/0515 , B01J27/0576 , B01J27/19 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C51/25 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C11/12 , B01J2523/54 , B01J2523/68 , B01J2523/842 , C07C255/08
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6.发明授权Catalysts containing iron and molybdenum and the use of these catalysts in the preparation of acrylonitrile or methacrylonitrile 失效含有铁和钼的催化剂以及这些催化剂在制备丙烯腈或甲基丙烯酸酯中的应用
公开(公告)号：EP0000564B1
公开(公告)日：1982-05-19
申请号：EP78100469.2
申请日：1978-07-21
Applicant: THE STANDARD OIL COMPANY
Inventor： Grasselli, Robert Karl , Suresh, Dev Dhanaraj , Friedrich, Maria Strada , Orndoff, David Allan
IPC: B01J23/88 , B01J27/18 , B01J27/02 , C07C121/32 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8875 , B01J23/8876 , B01J23/8993 , B01J27/0576 , B01J27/186 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/72 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/42 , B01J2523/43 , B01J2523/3718 , B01J2523/17 , B01J2523/305 , B01J2523/3712 , B01J2523/53 , C07C255/08
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7.发明公开
公开(公告)号：EP0000564A1
公开(公告)日：1979-02-07
申请号：EP78100469.2
申请日：1978-07-21
Applicant: THE STANDARD OIL COMPANY
Inventor： Grasselli, Robert Karl , Suresh, Dev Dhanaraj , Friedrich, Maria Strada , Orndoff, David Allan
IPC: B01J23/88 , B01J27/18 , B01J27/02 , C07C121/32 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8875 , B01J23/8876 , B01J23/8993 , B01J27/0576 , B01J27/186 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/13 , B01J2523/41 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/72 , B01J2523/842 , B01J2523/845 , B01J2523/847 , B01J2523/42 , B01J2523/43 , B01J2523/3718 , B01J2523/17 , B01J2523/305 , B01J2523/3712 , B01J2523/53 , C07C255/08
Abstract: The invention is related to new catalysts containing iron, bismuth, molybdenum and various additional elements which exhibit extremely attractive catalytic properties for the oxidation and ammoxidation of various olefins. The invention is further related to the use of such catalysts in the ammoxidation of propylene and isobutylene to acrylonitrile and respectively, methacrylonitrile.
Abstract translation: 本发明涉及含有铁，铋，钼和表现出各种烯烃的氧化和氨氧化反应非常有吸引力的催化性能的各种附加元素的新催化剂。 本发明还涉及使用在丙烯和异丁烯氨氧化成丙烯腈和分别甲基丙烯腈测试催化剂。
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