-
1.发明公开Catalytic process for the manufacture of acrylonitrile and hydrogen cyanide 审中-公开Kalalytisches Verfahren zur Produktion von Acrylnitril undBlausäure
公开(公告)号：EP1321188A1
公开(公告)日：2003-06-25
申请号：EP03075784.3
申请日：1998-08-17
Applicant: The Standard Oil Company
Inventor： Drenski, Tama Lee , Friedrich, Maria Strada , Seely, Michael J. , Paparizos, Christos , Suresh, Dev Dhanaraj
IPC: B01J23/881 , B01J23/887 , C01C3/02 , C07C253/26
CPC classification number: C07C253/18 , B01J23/002 , B01J23/31 , B01J23/8876 , B01J37/0045 , B01J37/08 , B01J2523/00 , C01C3/0216 , C01G53/006 , Y02P20/52 , B01J2523/13 , B01J2523/15 , B01J2523/22 , B01J2523/23 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/842 , B01J2523/847 , C07C255/08
Abstract: A process for preparing acrylonitrile comprises ammoxidising propylene in the presence of a complex oxide catalyst having the empirical formula:
A a B b C c D d Fe e Bi f Mo 12 O x
where A is Cs, K or mixtures thereof
B is one or more of Mg, Mn, Ni, Co, Ag, Pb, Re, Cd and Zn or mixtures
thereof
C is one or more of Ce, Cr, P, Ge and mixtures thereof
D is Ca and optionally one of Sr, Ba or mixtures thereof
and a = 0.01 to 1.0
b and e = 1.0 to 10
c, d and f = 0.1 to 5.0
and x is a number determined by the valence requirements of the other elements present.Abstract translation: 制备丙烯腈的方法包括在具有以下经验式的复合氧化物催化剂存在下使丙烯氨氧化：AaBbCcDdFeeBifMo12Ox其中A为Cs，K或其混合物。B为Mg，Mn，Ni，Co，Ag，Pb，Re中的一种或多种 ，Cd和Zn或其混合物C是Ce，Cr，P，Ge及其混合物中的一种或多种，D是Ca和任选的Sr，Ba或其混合物中的一种，a = 0.01至1.0b且e = 1.0至10c ，d和f = 0.1至5.0，x是由其它存在的元素的化合价要求确定的数。
-
2.发明公开Production of improved antimony containing catalysts, catalysts so produced and use thereof 失效制备改进的含锑催化剂这样制备的催化剂和它们的用途。
公开(公告)号：EP0036464A2
公开(公告)日：1981-09-30
申请号：EP80304632.5
申请日：1980-12-19
Applicant: THE STANDARD OIL COMPANY
Inventor： Suresh, Dev Dhanaraj , Grasselli, Robert Karl , Brazdil, James Frank
IPC: C07C120/14 , B01J23/24 , B01J23/88
CPC classification number: B01J23/8876 , B01J23/002 , B01J23/24 , B01J23/887 , B01J37/0201 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/17 , B01J2523/53 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/64 , B01J2523/67 , C07C255/08
Abstract: Antimony-based oxide complex catalysts are improved by adding to these catalysts an antimony-containing compound such as Sb 2 O 3 , in an amount of 0.1 to 25% based on an atomic basis of the antimony relative to the antimony already present in the catalyst. In this way a catalyst is produced which gives improved yields for example in the procuction of acrylonitrile by the ammoxidation of propylene.
-
公开(公告)号：EP0069439A3
公开(公告)日：1984-03-28
申请号：EP82301865
申请日：1982-04-08
Applicant: The Standard Oil Company
Inventor： Grasselli, Robert Karl , Suresh, Dev Dhanaraj , Zagata, Robert Joseph , Force, Gary Edward
CPC classification number: B01J23/8435 , B01J23/18 , B01J37/0236
Abstract: A slurry process for producing a fluid-bed catalyst comprising an antimonate-based oxide complex supported on a catalyst support in which (1) source compounds containing all of the elements of said oxide complex and said support material are combined to form a pre-catalyst slurry, (2) the liquid removed from said pre-catalyst slurry to form a pre-catalyst, and (3) said pre-catalyst is heated at elevated temperature to form said catalyst, in which the support material combined with the source compounds in step (1) is composed of (a) a fumed catalyst support material, such as fumed silica, and (b) a catalyst support material sol, such as a silica sol. The pre-catalyst slurry is formed without the addition of a slurry-derived solid containing fumed catalyst support material and one or more of the source compounds. The process is preferably a single slurry process. The catalyst produced has improved catalytic properties and attrition resistance.
-
4.发明公开Production of improved antimony containing catalysts, catalysts so produced and use thereof 失效生产改进的含有催化剂的催化剂，生产和使用的催化剂
公开(公告)号：EP0036464A3
公开(公告)日：1981-11-18
申请号：EP80304632
申请日：1980-12-19
Applicant: THE STANDARD OIL COMPANY
Inventor： Suresh, Dev Dhanaraj , Grasselli, Robert Karl , Brazdil, James Frank
IPC: C07C120/14 , B01J23/24 , B01J23/88
CPC classification number: B01J23/8876 , B01J23/002 , B01J23/24 , B01J23/887 , B01J37/0201 , B01J2523/00 , C07C253/26 , Y02P20/52 , B01J2523/17 , B01J2523/53 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/64 , B01J2523/67 , C07C255/08
Abstract: Antimony-based oxide complex catalysts are improved by adding to these catalysts an antimony-containing compound such as Sb 2 O 3 , in an amount of 0.1 to 25% based on an atomic basis of the antimony relative to the antimony already present in the catalyst. In this way a catalyst is produced which gives improved yields for example in the procuction of acrylonitrile by the ammoxidation of propylene.
-
公开(公告)号：EP0002626A3
公开(公告)日：1979-08-08
申请号：EP78300870
申请日：1978-12-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Suresh, Dev Dhanaraj , Grasselli, Robert Karl , Orndoff, David Allan
IPC: B01J23/84 , C07C120/00 , C07B03/00 , C07C05/48
CPC classification number: B01J23/8437 , B01J23/84 , B01J27/0576 , B01J27/186 , B01J2523/00 , C07C45/34 , C07C253/26 , Y02P20/52 , B01J2523/17 , B01J2523/41 , B01J2523/53 , B01J2523/54 , B01J2523/68 , B01J2523/69 , B01J2523/842 , B01J2523/67 , B01J2523/72 , C07C255/08
Abstract: A catalyst comprising an oxide complex of the general formula
in which
A represents Cu, Ce, U, V, Cr, Mn and/or Te; B represents an alkali metal, alkaline earth metal, Co, Ni, Zn, Cd, rare earth, Ga, TI and/or Th; C represents Mo, W, Nb, Ta, Sn, Ge, Ti, Zr, P, B, and/or As; a is 0 - 20; b is 0 - 20; c is 0 - 20; a+b+c is greater than 0 and x is a number determined by the oxygen requirements of the other elements present. The catalysts are useful in the production of nitriles by the vapour phase ammoxidation of olefins, aldehydes and alcohols; the vapour phase oxidation of olefins containing not more than three contiguous carbon atoms and the vapour phase oxydehydrogenation of olefins containing four or more contiguous carbon atoms. A particularly preferred catalyst according to the invention has the formula W 0.2 Mo 1 Bi 2 Cu 3 Fe 12 O x .-
Patent Agency Ranking6.发明公开Regeneration of molybdenum based catalysts by the addition of ammonium dimolybdate 审中-公开通过加入硫酸铵含钼催化剂的再生
公开(公告)号：EP0922492A1
公开(公告)日：1999-06-16
申请号：EP98309585.2
申请日：1998-11-24
Applicant: THE STANDARD OIL COMPANY
Inventor： Drenski, Tama Lee , Seely, Michael J. , Friedrich, Maria Strada , Suresh, Dev Dhanaraj , Paparizos, Christos
Abstract: A process for regenerating molybdenum containing ammoxidation catalyst comprising replacing the molybdenum loss from the catalyst during the ammoxidation reaction wherein ammonium dimolybdenum is utilized as the source for replacement of the molybdenum loss from the original catalyst.
-
7.发明公开Production of catalysts by impregnation and use thereof in oxidation type reactions 无效通过浸渍和它们的氧化反应使用催化剂的制备。
公开(公告)号：EP0086292A1
公开(公告)日：1983-08-24
申请号：EP82300744.8
申请日：1982-02-15
Applicant: THE STANDARD OIL COMPANY
IPC: B01J23/88 , C07C5/48 , C07C45/34 , C07C51/00 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J23/8878 , B01J27/0515 , B01J27/0576 , B01J27/19 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C51/25 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C11/12 , B01J2523/54 , B01J2523/68 , B01J2523/842 , C07C255/08
Abstract: A process for improving the catalytic properties of a substantially crystalline iron bismuth molybdate oxide complex interim catalyst comprises incorporating at least one element from Groups IA, IB, IIB, IIIA and IIIB of the periodic Table into the catalyst by impregnation, none of the Group IA elements incorporated into the catalyst by impregnation being derived from a molybdate or silicate. The catalysts provide improved results in oxidation type reactions.
Abstract translation: 一种用于改善基本上结晶的铁钼酸铋氧化物复合临时催化剂的催化性能的方法包括选自IA，IB，IIB，IIIA和周期表的IIIB结合的至少一种元素到催化剂通过浸渍，没有IA族的 掺入到通过浸渍催化剂元件从钼酸盐或硅酸盐得到的。 催化剂提供在氧化型反应改善的结果。
-
8.发明公开Promoted bismuth cerium molybdate catalysts and use thereof in oxidation-type reactions 失效Aktivierte Wismut-Cer-Molybdat-Katalysatoren und deren Verwendung in Oxidationsreaktionen。
公开(公告)号：EP0064821A2
公开(公告)日：1982-11-17
申请号：EP82301991.4
申请日：1982-04-19
Applicant: THE STANDARD OIL COMPANY
Inventor： Brazdil, James Frank , Suresh, Dev Dhanaraj , Grasselli, Robert Karl
IPC: B01J23/31 , C07C120/14 , C07C121/32
CPC classification number: C07C253/26 , B01J23/31 , B01J23/686 , B01J23/885 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C45/35 , C07C45/37 , C07C45/38 , C07C2521/06 , C07C2523/04 , C07C2523/08 , C07C2523/10 , C07C2523/12 , C07C2523/18 , C07C2523/26 , C07C2523/28 , C07C2523/31 , C07C2523/50 , C07C2523/72 , C07C2527/057 , Y02P20/52 , C07C47/22 , B01J2523/13 , B01J2523/3712 , B01J2523/54 , B01J2523/68 , B01J2523/15 , B01J2523/34 , B01J2523/69 , B01J2523/41 , B01J2523/53 , B01J2523/67 , B01J2523/64 , B01J2523/3706 , B01J2523/36 , B01J2523/3718 , B01J2523/3725 , B01J2523/47 , C07C255/08
Abstract: A bismuth cerium molybdate catalysts oxide complex catalyst contains a promoting amount of an alkali metal TI, Sm, Ag, Cu, Cr, Sb, rare earth metal other than Ce and Sm, Te, Ti, Zr, Th or mixture thereof.
Such catalyst provides high yields of acrylonitrile in the ammoxidation of propylene and give improved results in other oxidation-type reactions.Abstract translation: 钼酸铋催化剂氧化物络合物催化剂含有除Ce和Sm，Te，Ti，Zr，Th或其混合物之外的碱金属Ti，Sm，Ag，Cu，Cr，Sb，稀土金属的促进量。 这种催化剂在丙烯的氨氧化中提供高产率的丙烯腈，并在其它氧化型反应中得到改善的结果。
-
公开(公告)号：EP0005067A3
公开(公告)日：1980-01-02
申请号：EP79300663
申请日：1979-04-20
Applicant: THE STANDARD OIL COMPANY
Inventor： Bradzdil, James Frank , Grasselli, Robert Karl , Suresh, Dev Dhanaraj
Abstract: A process for producing a molybdate or tungstate activated oxide complex catalyst in which the elements of the catalyst are combined together in a precatalyst aqueous slurry, the slurry obtained is dried to form a precatalyst precipitate, and the precatalyst precipitate is then calcined to form the catalyst, characterised in that the key catalytic phase of the catalyst defined as a molybdate or tungstate of Bi, Te, Sb, Sn, Cu or mixtures thereof is preformed prior to combining with the other elements of the catalyst, provided that when one or more elements in the catalyst is supplied to the precatalyst aqueous slurry in the form of
(a) a source salt having a heat-decomposable cation or anion, (b) an inorganic salt reaction product of the source salt or (c) an aqueous slurry of either (a) or (b) then the elements of the catalyst are combined so that the precatalyst precipitate contains a substantial amount of at least one of the heat-decomposable anions or cations. The catalysts produced by this process are useful in the oxidation and ammoxidation of dlefins.-
10.发明授权Production of catalysts by impregnation and use thereof in oxidation type reactions 无效通过在氧化反应中产生催化剂并使用它们
公开(公告)号：EP0086292B1
公开(公告)日：1986-04-23
申请号：EP82300744.8
申请日：1982-02-15
Applicant: THE STANDARD OIL COMPANY
IPC: B01J23/88 , C07C5/48 , C07C45/34 , C07C51/00 , C07C120/14
CPC classification number: B01J23/8872 , B01J23/8874 , B01J23/8875 , B01J23/8876 , B01J23/8878 , B01J27/0515 , B01J27/0576 , B01J27/19 , B01J2523/00 , C07C5/48 , C07C45/34 , C07C51/25 , C07C51/252 , C07C253/26 , Y02P20/52 , C07C11/12 , B01J2523/54 , B01J2523/68 , B01J2523/842 , C07C255/08
-
-
-
-
-
-
-
-
-
Search Results
23
records
(took 0.028 seconds)
