公开(公告)号：US5464462A

公开(公告)日：1995-11-07

申请号：US120729

申请日：1993-09-13

Applicant: Alfred Langer ,  Andreas Genz ,  Manfred Deisenhofer ,  Walter Kiele ,  Bernd Lewandowski ,  Jurgen Reichardt

Inventor： Alfred Langer ,  Andreas Genz ,  Manfred Deisenhofer ,  Walter Kiele ,  Bernd Lewandowski ,  Jurgen Reichardt

IPC: C03B20/00 ,  C03C3/06 ,  H01J5/02 ,  H01J61/30 ,  H01J61/34 ,  H01J61/40 ,  H01J61/82 ,  C03B15/14 ,  C03B5/16 ,  C03C3/04 ,  C04B35/44

CPC classification number: H01J61/40 ,  C03C3/06 ,  H01J61/302 ,  H01J61/34 ,  H01J61/827 ,  C03C2201/3423 ,  C03C2201/36 ,  C03C2201/42 ,  C03C2203/10 ,  Y10S65/09

Abstract: Ultraviolet (UV) radiation in the UV-C and UV-B bands, which is particularly dangerous, is absorbed and filtered by quartz glass doped with between 0.065% and 3.25%, and preferably between 0.065% and 1.3%, by weight, of cerium metal, or cerium as such. Preferably, the cerium is added to quartz sand and/or rock crystal, in form of a fine-grained powder of up to 20 .mu.m grain size, in form of cerium aluminate (CeAlO.sub.3), present in up to about 5% by weight, and preferably up to about 2%, by weight, and melted together in a single step. The quartz glass so obtained is particularly suitable for a metal halide discharge lamp, e.g. as an outer envelope (1), or as the discharge vessel (27) itself, or for halogen incandescent lamps, to form the quartz-glass light bulb or an envelope therefor. A small quantity of titanium oxide, up to about 0.05%, may be added as a further doping agent to the melt to further improve the UV absorption in the B and C bands.

Abstract translation: 特别危险的UV-C和UV-B带中的紫外线（UV）辐射被掺入0.065％至3.25％，优选0.065％至1.3％重量的石英玻璃吸收和过滤 铈金属或铈。 优选地，以高达约5重量％的铈铝酸盐（CeAlO 3）的形式将铈添加到石英砂和/或岩石晶体，其形式为至多20μm的粒度的细粒粉末 ，优选至多约2重量％，并在一个步骤中熔融在一起。 如此获得的石英玻璃特别适用于金属卤化物放电灯，例如， 作为外封套（1），或作为放电容器（27）本身，或用于卤素白炽灯，以形成石英玻璃灯泡或其封套。 可以将少量至多约0.05％的氧化钛作为另外的掺杂剂加入到熔体中以进一步提高B和C带中的UV吸收。

公开(公告)号：US5068208A

公开(公告)日：1991-11-26

申请号：US682200

申请日：1991-04-05

Applicant: Niels Haun ,  Duncan T. Moore

Inventor： Niels Haun ,  Duncan T. Moore

IPC: C03B19/12 ,  C03C1/00 ,  C03C3/06 ,  C03C3/076

CPC classification number: C03C3/076 ,  C03B19/12 ,  C03C1/006 ,  C03C3/06 ,  C03C2201/10 ,  C03C2201/31 ,  C03C2201/32 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2203/26

Abstract: Gradient-index glass is produced in a sol-gel process by utilizing water or a mixture of water and alcohol. This technique is particularly suitable for production of glass bodies with a ternary system of metal alkoxides, including silicon alkoxide, an index modifying metal alkoxide, such as alkoxides of titanium and zirconium, and an additional metal alkoxide, such as an alkoxide of aluminum, boron, or germanium.

Abstract translation: 梯度折射率玻璃通过利用水或水和酒精的混合物在溶胶 - 凝胶法中制备。 该技术特别适用于具有金属醇盐三元体系的玻璃体的制造，所述金属醇盐包括硅醇盐，指数改性金属醇盐，例如钛和锆的烷氧化物，以及另外的金属醇盐，例如铝的醇盐，硼 ，或锗。

公开(公告)号：US4397666A

公开(公告)日：1983-08-09

申请号：US315494

申请日：1981-10-27

Applicant: Michiharu Mishima ,  Yuji Yamamoto ,  Kensuke Makita ,  Sumio Sakka ,  Kanichi Kamiya

Inventor： Michiharu Mishima ,  Yuji Yamamoto ,  Kensuke Makita ,  Sumio Sakka ,  Kanichi Kamiya

IPC: C01B33/152 ,  B05D7/00 ,  B32B17/00 ,  C03B8/02 ,  C03B19/12 ,  C03B37/01 ,  C03C1/00 ,  C03C3/04 ,  C03C3/06 ,  C03C17/02 ,  C04B41/50 ,  C04B41/86 ,  C03B19/06 ,  C03B20/00

CPC classification number: C04B41/009 ,  C03B19/12 ,  C03B37/011 ,  C03C1/008 ,  C03C3/04 ,  C03C3/06 ,  C04B41/5022 ,  C04B41/86 ,  C03C2201/02 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2203/26 ,  C03C2203/30 ,  Y02P40/57 ,  Y10S65/901

Abstract: In producing silica glass, which may contain additional metal(s) such as Ti or Zr, from a solution of a silicon alkoxide, mixed with alkoxide(s) of the additional metal(s) where necessary, in water and a hydrophilic organic solvent by shaping the solution into a desired form such as a coating film on a substrate, self-supporting film, fiber or lump when the solution exhibits a suitably high viscosity and sufficiently heating the shaped solution, a water-soluble organic polymeric substance is added to the solution as a viscosity adjusting agent to soon increase the viscosity of the solution to the desirable level. Therefore, shaping of the solution can be performed without awaiting the progress of hydrolysis of the alkoxide in the solution, and the glass can be obtained with improved uniformity of its properties. A cellulose ether is preferred as the viscosity adjusting agent, and hydroxypropyl cellulose is particularly preferable.

Abstract translation: 在可能含有另外的金属如Ti或Zr的二氧化硅玻璃中，从需要的金属醇盐与硅烷醇盐的溶液在水和亲水性有机溶剂中混合 通过将溶液成型为所需形状，例如基材上的涂膜，自支撑膜，纤维或块状物，当溶液表现出适当高的粘度并充分加热成型溶液时，将水溶性有机聚合物质加入 该溶液作为粘度调节剂，将溶液粘度迅速提高至理想水平。 因此，可以在不等待溶液中的醇盐的水解进行的情况下进行溶液的成形，并且可以获得具有改善的性能均匀性的玻璃。 优选纤维素醚作为粘度调节剂，特别优选羟丙基纤维素。

公开(公告)号：US4333847A

公开(公告)日：1982-06-08

申请号：US65752

申请日：1979-08-10

Applicant: Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

Inventor： Danh C. Tran ,  Pedro B. Macedo ,  Joseph H. Simmons ,  Catherine J. Simmons ,  Nicholas Lagakos

IPC: G21F9/02 ,  G21F9/30 ,  G21F9/36 ,  G21F9/16

CPC classification number: C03C1/002 ,  C03C1/026 ,  C03C11/005 ,  C03C21/001 ,  C03C23/0095 ,  C03C3/06 ,  C03C3/061 ,  C03C3/089 ,  G21F9/02 ,  G21F9/305 ,  G21F9/36 ,  C03C2201/10 ,  C03C2201/20 ,  C03C2201/23 ,  C03C2201/3411 ,  C03C2201/3423 ,  C03C2201/3429 ,  C03C2201/40 ,  C03C2201/42 ,  C03C2201/50 ,  C03C2201/54

Abstract: This invention relates to the immobilization of toxic, e.g., radioactive materials, internally in a silicate glass or silica gel matrix for extremely long periods of time. Toxic materials, such as radioactive wastes containing radioactive anions, and in some cases cations, which may be in the form of liquids, or solids dissolved or dispersed in liquids or gases, are internally incorporated into a glass matrix, having hydrous organofunctionalsiloxy groups, e.g., hydrous aminoalkylsiloxy or carboxyorganosiloxy, bonded to silicon atoms of said glass and/or hydrous polyvalent metals bonded to silicon atoms of said glass through divalent oxygen linkages or otherwise immobilized therein, by a process which involves the ion exchange of said toxic, radioactive anions with hydroxyl groups attached to said organofunctionalsiloxy groups or with hydroxyl groups attached to the hydrous polyvalent metal. Thereafter, the resulting glass now characterized by a distribution of internally bonded or immobilized, toxic, radioactive anions can be packaged in suitable containers, and disposed of as by burial, and/or they can be sintered to collapse the pores thereof prior to disposal or for producing useful radiation sources. The porous glass or a porous silica gel having said silicon-bonded organofunctionalsiloxy groups and/or said hydrous polyvalent metal oxy groups, the pores of said glass or silica gel remaining open and uncollapsed, can be used advantageously as a backfill for an underground radioactive waste burial site and as overpack in the waste disposal container. Also included is a novel method for bonding the polyvalent metal to the porous silica glass or gel by substituting the protons of the silicon-bonded hydroxyl groups thereof with an alkali metal or ammonium cation followed by displacement of said cation with the non-radioactive polyvalent metal cation.

Abstract translation: 本发明涉及在硅酸盐玻璃或硅胶基质中内部有毒的例如放射性物质固定极长时间。 含有放射性阴离子的放射性废物，以及在某些情况下，可能是液体形式的阳离子或溶解或分散在液体或气体中的固体的有毒材料内部加入到具有含水官能团的甲硅烷氧基的玻璃基质中，例如 ，含水氨基烷基甲硅烷氧基或羧基有机基甲硅烷氧基，通过涉及将所述有毒放射性阴离子与所述有机放射性阴离子的离子交换的方法，通过二价氧键键合到所述玻璃的硅原子和/或与所述玻璃的硅原子键合的含水多价金属， 连接到所述有机电致甲硅烷氧基基团的羟基或与水合多价金属连接的羟基的羟基。 此后，所得玻璃的特征在于内部结合或固定的，有毒的放射性阴离子的分布可以包装在合适的容器中，并且通过埋置进行处理和/或它们可以在处理之前烧结以使其孔隙塌缩，或 用于生产有用的辐射源。 所述多孔玻璃或多孔硅胶具有所述与硅键合的有机铁氧基甲硅烷氧基和/或所述含水多价金属氧基，所述玻璃或硅胶的孔保持开放和未破裂，可有利地用作地下放射性废物的回填 垃圾处理容器内的包装物， 还包括一种通过用碱金属或铵阳离子取代与硅键合的羟基的质子，然后用非放射性多价金属置换所述阳离子来将多价金属键合到多孔石英玻璃或凝胶上的新方法 阳离子。

公开(公告)号：US4047966A

公开(公告)日：1977-09-13

申请号：US680460

申请日：1976-04-26

Applicant: Peter P. Bihuniak ,  Donald L. Guile

Inventor： Peter P. Bihuniak ,  Donald L. Guile

IPC: C03C3/06 ,  C04B35/14

CPC classification number: C03C3/06 ,  C04B35/14 ,  C03C2201/20 ,  C03C2201/32 ,  C03C2201/42 ,  C03C2203/10 ,  C03C2203/22

Abstract: A method is disclosed wherein high purity fused silica is produced from a liquid flowable form of a silica slurry or sol and the refractoriness of the fused silica is enhanced by homogeneously doping the silica with aluminum and/or titanium oxide, preferably in conjunction with elemental silicon.

Abstract translation: 公开了一种方法，其中由二氧化硅浆料或溶胶的液体可流动形式产生高纯度熔融二氧化硅，并且通过用二氧化硅与铝和/或氧化钛均匀掺杂来优化熔融二氧化硅的耐火性，优选与元素硅 。

公开(公告)号：US20240174547A1

公开(公告)日：2024-05-30

申请号：US18420979

申请日：2024-01-24

Applicant: CORNING INCORPORATED

Inventor： Paulo Jorge Gaspar Marques ,  Antoine Marie Joseph Lepicard ,  Jian Luo ,  Lina Ma ,  Alexander I. Priven

IPC: C03C3/068

CPC classification number: C03C3/068 ,  C03C2201/3417 ,  C03C2201/42

Abstract: Glasses containing silicon dioxide (SiO2) and/or boron oxide (B2O3) as glass formers and having a refractive index nd of greater than or equal to 1.80, as measured at 587.56 nm, a density of less than or equal to 5.5 g/cm3, as measured at 25° C., and a high transmittance to, particularly to blue light, are provided. Optionally, the glasses may be characterized by a high transmittance in the visible and near-ultraviolet (near-UV) range of the electromagnetic spectrum and/or good glass forming ability.

公开(公告)号：US20240166547A1

公开(公告)日：2024-05-23

申请号：US18549129

申请日：2022-03-28

Applicant: Glassomer GmbH

Inventor： Bastian Rapp ,  Frederik Kotz-Helmer

IPC: C03B19/06 ,  C03C1/00 ,  C03C3/06

CPC classification number: C03B19/066 ,  C03C1/00 ,  C03C3/06 ,  C03B2201/06 ,  C03C2201/10 ,  C03C2201/32 ,  C03C2201/42 ,  C03C2201/50

Abstract: The present invention relates to a moldable nanocomposite for producing a transparent article made of multicomponent fused silica glass, the moldable nanocomposite comprising: an organic binder; and a fused silica glass powder dispersed in the organic binder, the fused silica glass powder comprising fused silica glass particles having a diameter in the range from 5 nm to 500 nm, wherein the fused silica glass powder is pre-modified with a dopant and/or wherein at least one non-crystalline modifying agent is contained in the moldable nanocomposite and one or more dopant reagents selected from organoelement compounds, metal complexes and salts are contained in the moldable nanocomposite as the at least one non-crystalline modifying agent, and wherein the content of the fused silica glass powder in the moldable nanocomposite is at least 5 parts per volume based on 100 parts per volume of the organic binder. Further, the present invention relates to a method of producing a transparent article made of multicomponent fused silica glass.

公开(公告)号：US11976004B2

公开(公告)日：2024-05-07

申请号：US17400444

申请日：2021-08-12

Applicant: CORNING INCORPORATED

Inventor： Paulo Jorge Gaspar Marques ,  Antoine Marie Joseph Lepicard ,  Jian Luo ,  Lina Ma ,  Alexander I Priven

IPC: C03C3/068

CPC classification number: C03C3/068 ,  C03C2201/3417 ,  C03C2201/42

Abstract: Glasses containing silicon dioxide (SiO2) and/or boron oxide (B2O3) as glass formers and having a refractive index nd of greater than or equal to 1.80, as measured at 587.56 nm, a density of less than or equal to 5.5 g/cm3, as measured at 25° C., and a high transmittance to, particularly to blue light, are provided. Optionally, the glasses may be characterized by a high transmittance in the visible and near-ultraviolet (near-UV) range of the electromagnetic spectrum and/or good glass forming ability.

公开(公告)号：US10017413B2

公开(公告)日：2018-07-10

申请号：US14950374

申请日：2015-11-24

Applicant: CORNING INCORPORATED

Inventor： Sezhian Annamalai ,  Carlos Alberto Duran ,  Kenneth Edward Hrdina ,  Lisa Anne Moore

IPC: C03C3/06 ,  C03C3/112 ,  C03C3/089 ,  G03F1/22 ,  C03B25/02 ,  C03B19/02 ,  C03C3/115 ,  C03C21/00 ,  C03C23/00 ,  C03B5/225 ,  C03B25/00

CPC classification number: C03C3/112 ,  C03B5/225 ,  C03B19/02 ,  C03B25/00 ,  C03B25/02 ,  C03B2201/10 ,  C03B2201/12 ,  C03B2201/14 ,  C03B2201/42 ,  C03C3/06 ,  C03C3/089 ,  C03C3/115 ,  C03C21/007 ,  C03C23/007 ,  C03C2201/10 ,  C03C2201/12 ,  C03C2201/14 ,  C03C2201/23 ,  C03C2201/30 ,  C03C2201/42 ,  C03C2203/10 ,  C03C2203/54 ,  G03F1/22

Abstract: A method of forming a doped silica-titania glass is provided. The method includes blending batch materials comprising silica, titania, and at least one dopant. The method also includes heating the batch materials to form a glass melt. The method further includes consolidating the glass melt to form a glass article, and annealing the glass article.

公开(公告)号：US10001699B2

公开(公告)日：2018-06-19

申请号：US15275719

申请日：2016-09-26

Applicant: HOYA CORPORATION

Inventor： Toshihiko Orihara ,  Kazuhiro Hamamoto ,  Hirofumi Kozakai ,  Youichi Usui ,  Tsutomu Shoki ,  Junichi Horikawa

IPC: G03F1/22 ,  C03C3/06 ,  G03F1/48 ,  G02B5/08 ,  B82Y10/00 ,  B82Y40/00 ,  G03F7/20 ,  C03C17/34 ,  C03C17/36 ,  C03C23/00 ,  G03F7/16 ,  H01L21/308

CPC classification number: G03F1/48 ,  B82Y10/00 ,  B82Y40/00 ,  C03C3/06 ,  C03C17/3435 ,  C03C17/3626 ,  C03C17/3636 ,  C03C17/3639 ,  C03C17/3649 ,  C03C17/3665 ,  C03C23/0075 ,  C03C2201/42 ,  C03C2218/33 ,  G02B5/08 ,  G02B5/0816 ,  G02B5/0891 ,  G03F1/22 ,  G03F7/16 ,  G03F7/2002 ,  G03F7/2004 ,  G03F7/70733 ,  H01L21/3081 ,  H01L21/3085

Abstract: Disclosed is a mask blank substrate for use in lithography, wherein the main surface on which the transfer pattern of the substrate is formed has a root mean square roughness (Rms) of not more than 0.15 nm obtained by measuring an area of 1 μm×1 μm with an atomic force microscope, and has a power spectrum density of not more than 10 nm4 at a spatial frequency of not less than 1 μm−1.