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公开(公告)号：KR1020120076301A
公开(公告)日：2012-07-09
申请号：KR1020110121904
申请日：2011-11-21
Applicant: 제일모직주식회사
CPC classification number: C08L33/08 , C08L33/066 , C08L33/20 , C08L2201/02 , C08L2205/035 , C08L2207/04 , C08L2312/00
Abstract: PURPOSE: A low gloss thermoplastic resin composition is provided to have excellent thermal resistance and weatherability, even maintaining impact strength, and mechanical properties, and to have excellent low gloss property, and flexability. CONSTITUTION: A low gloss thermoplastic resin composition comprises a thermoplastic resin forming a first dispersed phase, and an acrylic resin forming a second dispersed phase. The first dispersed phase is network shape. The low gloss thermoplastic resin composition additionally comprises heat-resistant aromatic vinyl based copolymer. The thermoplastic resin comprises a (meth)acrylic acid alkyl ester based polymer, and aromatic vinyl-vinyl cyanide based copolymer. The (meth)acrylic acid alkyl ester has dispersed phase of network shape, and the aromatic vinyl-vinyl cyanide based copolymer has continuous phase.
Abstract translation: 目的：提供低光泽的热塑性树脂组合物以具有优异的耐热性和耐候性，甚至保持冲击强度和机械性能，并且具有优异的低光泽性和挠性。 构成：低光泽热塑性树脂组合物包含形成第一分散相的热塑性树脂和形成第二分散相的丙烯酸树脂。 第一个分散阶段是网络形状。 低光泽热塑性树脂组合物另外包含耐热芳族乙烯基共聚物。 热塑性树脂包括（甲基）丙烯酸烷基酯基聚合物和芳族乙烯基 - 乙烯基氰化物基共聚物。 （甲基）丙烯酸烷基酯具有网状分散相，芳香族乙烯基 - 乙烯基氰系共聚物具有连续相。
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公开(公告)号：KR100983239B1
公开(公告)日：2010-09-20
申请号：KR1020080108621
申请日：2008-11-03
Applicant: 제일모직주식회사
IPC: C08F279/04 , C08F279/00 , C08F2/01 , C08F2/22
Abstract: 본 발명의 무광택 고무변성 방향족 비닐-시안화 비닐 공중합체는 디엔계 고무 7 내지 20 중량%에 방향족 비닐-시안화 비닐 공중합체 80 내지 93 중량%가 그라프트되어 있으며, 분산상의 평균고무입경이 6 내지 20 ㎛이고, 스팬이 1.2 내지 2.8 인 것을 특징으로 한다. 또한 본 발명은 상기 무광택 고무변성 방향족 비닐-시안화 비닐 공중합체의 연속중합방법을 제공한다.
괴상중합, 용액중합, 연속중합, 무광 수지, ABS 수지, 광택도-
公开(公告)号：KR1020100077547A
公开(公告)日：2010-07-08
申请号：KR1020080135514
申请日：2008-12-29
Applicant: 제일모직주식회사
CPC classification number: C08L51/04 , C08L35/06 , C08L2205/02 , C08L2666/24 , C08L2666/04
Abstract: PURPOSE: A method for manufacturing a thermoplastic resin is provided to maintain mechanical properties of the thermoplastic resin, to easily increase heat resistance of the thermoplastic resin, and to improve the balance of the heat resistance and the impact strength. CONSTITUTION: A thermoplastic resin having excellent heat resistance and impact strength is obtained through the copolymerization of 0.005-0.2 parts by weight of a polyfunctional vinyl compound and 1-10 parts by weight of N-substituted maleimide compound and an aromatic vinyl compound. The reactant includes 5-20 weight% of a conjugated-diene, 0.5-8 weight% of an aromatic elastic copolymer, 15-29 weight% of a heat resistant vinyl compound, 10-50 weight% of the aromatic vinyl compound, and 10-30 weight% of an unsaturataed nitrile-based compound.
Abstract translation: 目的：提供热塑性树脂的制造方法，以保持热塑性树脂的机械性能，容易提高热塑性树脂的耐热性，提高耐热性和冲击强度的平衡。 构成：通过共聚0.005-0.2重量份的多官能乙烯基化合物和1-10重量份的N-取代的马来酰亚胺化合物和芳香族乙烯基化合物，获得了具有优异的耐热性和冲击强度的热塑性树脂。 反应物包括5-20重量％的共轭二烯，0.5-8重量％的芳族弹性共聚物，15-29重量％的耐热乙烯基化合物，10-50重量％的芳族乙烯基化合物和10 -30重量％的不饱和腈基化合物。
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公开(公告)号：KR100870754B1
公开(公告)日：2008-11-26
申请号：KR1020070140120
申请日：2007-12-28
Applicant: 제일모직주식회사
CPC classification number: C08L33/08 , C08L9/00 , C08L33/10 , C08L2666/08
Abstract: A thermoplastic resin composition is provided to secure scratch resistance and low gloss property while maintaining impact strength by dispersible butadiene-based rubber in the ter-polymer of a (meth)acrylate alkyl ester-aromatic vinyl-vinyl cyanide compound. A thermoplastic resin composition having scratch resistance and low gloss property comprises (A) 80-95 weight% of a ter-polymer of (meth)acrylate alkyl ester-aromatic vinyl-vinyl cyanide compound; and (B) 5-20 weight% of butadiene-based rubber.
Abstract translation: 提供热塑性树脂组合物以确保耐刮擦性和低光泽性，同时通过可分散的丁二烯类橡胶在（甲基）丙烯酸烷基酯 - 芳族乙烯基 - 乙烯基氰化合物的三元共聚物中保持冲击强度。 具有耐刮擦性和低光泽性的热塑性树脂组合物包含（A）80-95重量％的（甲基）丙烯酸酯 - 芳族乙烯基 - 乙烯基氰化合物的三元共聚物; 和（B）5-20重量％的丁二烯基橡胶。
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公开(公告)号：KR100781962B1
公开(公告)日：2007-12-06
申请号：KR1020060070718
申请日：2006-07-27
Applicant: 제일모직주식회사
CPC classification number: C08F220/14 , C08F2/02 , C08F2/38 , C08F6/001
Abstract: A method for preparing a polymethacrylic resin having a branched structure, and a polymethacrylic resin prepared by the method are provided to obtain a polymethacrylic resin having a branched structure to be polymerized stably under uniform stirring condition by bulk polymerization for improving productivity. A method for preparing a polymethacrylic resin having a branched structure comprises the steps of mixing a monomer mixture comprising an alkyl methacrylate and an alkyl acrylate, a multifunctional radical initiator, and a molecular weight controller; injecting the mixture into a reactor to polymerize until the polymerization ratio reaches 45-65 %; and removing the unreacted monomers, wherein the multifunctional radical initiator is 2,2-bis(4,4-di-t-butylperoxycyclohexyl)propane, polyether tetrakis(t-butylperoxy carbonate), or their mixture.
Abstract translation: 提供一种制备具有支链结构的聚甲基丙烯酸树脂和通过该方法制备的聚甲基丙烯酸树脂，以获得具有支化结构的聚甲基丙烯酸树脂，以通过本体聚合在均匀搅拌条件下稳定聚合以提高生产率。 制备具有支链结构的聚甲基丙烯酸树脂的方法包括以下步骤：混合包含甲基丙烯酸烷基酯和丙烯酸烷基酯，多官能自由基引发剂和分子量控制剂的单体混合物; 将混合物注入反应器进行聚合直到聚合比达到45-65％; 并除去未反应的单体，其中多官能自由基引发剂是2,2-双（4,4-二叔丁基过氧环己基）丙烷，聚醚四（叔丁基过氧化碳酸酯）或它们的混合物。
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Patent Agency Ranking
公开(公告)号：KR1020070066451A
公开(公告)日：2007-06-27
申请号：KR1020050127638
申请日：2005-12-22
Applicant: 제일모직주식회사
Abstract: Provided are a method for preparing a branched styrene-based thermoplastic resin composition to improve fluidity, processability, impact strength and appearance and to prevent gelation, and a branched styrene-based thermoplastic resin composition prepared by the method. The method comprises the step of polymerizing a mixture comprising 100 parts by weight of an aromatic vinyl compound; 0.001-3 parts by weight of a multifunctional vinyl compound; and 0.001-0.3 parts by weight of a multifunctional initiator. Preferably, the aromatic vinyl compound further comprises 0-40 wt% of a cyanovinyl compound; and the multifunctional vinyl compound is selected from the group consisting of ethylene dimethacrylate, diethylene glycol methacrylate, triethylene glycol dimethacrylate, trimethylene propane trimethacrylate, trimethylene propane triacrylate, 1,3-butanediol methacrylate, 1,6-hexanediol dimethacrylate and allyl acrylate.
Abstract translation: 提供一种制备支链苯乙烯类热塑性树脂组合物以提高流动性，加工性，冲击强度和外观以及防止凝胶化的方法，以及通过该方法制备的支链苯乙烯类热塑性树脂组合物。 该方法包括使包含100重量份芳族乙烯基化合物的混合物聚合的步骤; 0.001-3重量份多官能乙烯基化合物; 和0.001-0.3重量份的多官能引发剂。 优选地，芳族乙烯基化合物还包含0-40重量％的氰基乙烯基化合物; 多官能乙烯基化合物选自乙烯二甲基丙烯酸酯，二甘醇甲基丙烯酸酯，三甘醇二甲基丙烯酸酯，三亚甲基丙烷三甲基丙烯酸酯，三亚甲基丙烷三丙烯酸酯，1,3-丁二醇甲基丙烯酸酯，1,6-己二醇二甲基丙烯酸酯和丙烯酸烯丙酯。
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公开(公告)号：KR100726485B1
公开(公告)日：2007-06-12
申请号：KR1020050135312
申请日：2005-12-30
Applicant: 제일모직주식회사
IPC: C08F279/04 , C08F2/02
Abstract: A method for preparing a transparent rubber-modified styrenic resin through a continuous mass polymerization process is provided to obtain an ABS resin having excellent impact strength and processability while maintaining transparency by using a rubber phase and a matrix phase having the same refractive index. The method for preparing a transparent rubber-modified styrenic resin through a continuous mass polymerization process comprises the steps of: (A) reacting a reaction mixture containing a styrene-butadiene monomer dissolved in a reaction medium, styrene monomer, methyl methacrylate monomer and acrylonitrile monomer in a first reactor at 90-130 deg.C for 1-2 hours to form a first polymerizate having a conversion ratio of 10-20%; (B) introducing the first polymerizate continuously into a second reactor and polymerizing it at 110-145 deg.C for 1-2 hours to form a second polymerizate having a conversion ratio of 45-85%; (C) introducing the second polymerizate continuously into a third reactor and polymerizing it at 130-160 deg.C for 0.5-1.5 hours to form a third polymerizate having a conversion ratio of 80-90%; and (D) introducing the third polymerizate into a volatile component remover to remove unreacted monomer and the solvent. In step (A), the monomer mixture is an azeotropic mixture containing 58-78 parts by weight of a styrene monomer, 5-45 parts by weight of a methyl methacrylate monomer and 1-23 parts by weight of an acrylonitrile monomer. In step (B) or (C), at least one of the styrene monomer, methyl methacrylate monomer and acrylonitrile monomer is continuously introduced into the second or the third reactor to allow the rubber phase to have the same refractive index as the matrix phase formed of the monomers.
Abstract translation: 提供一种通过连续本体聚合法制备透明橡胶改性苯乙烯树脂的方法，以通过使用具有相同折射率的橡胶相和基体相来保持透明性，同时获得具有优异冲击强度和加工性的ABS树脂。 通过连续本体聚合法制备透明橡胶改性苯乙烯树脂的方法包括以下步骤：（A）使包含溶于反应介质中的苯乙烯 - 丁二烯单体，苯乙烯单体，甲基丙烯酸甲酯单体和丙烯腈单体的反应混合物 在90-130℃的第一反应器中进行1-2小时以形成转化率为10-20％的第一聚合产物; （B）将第一聚合产物连续引入第二反应器中，并在110-145℃聚合1-2小时，形成转化率为45-85％的第二聚合产物; （C）将第二聚合产物连续引入第三反应器并在130-160℃聚合0.5-1.5小时以形成转化率为80-90％的第三聚合产物; 和（D）将第三聚合产物引入挥发性组分去除剂中以除去未反应的单体和溶剂。 在步骤（A）中，单体混合物是含有58-78重量份苯乙烯单体，5-45重量份甲基丙烯酸甲酯单体和1-23重量份丙烯腈单体的共沸混合物。 在步骤（B）或（C）中，将苯乙烯单体，甲基丙烯酸甲酯单体和丙烯腈单体中的至少一种连续引入到第二或第三反应器中以使橡胶相具有与形成的基体相同的折射率 的单体。
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公开(公告)号：KR100595979B1
公开(公告)日：2006-07-03
申请号：KR1020040034208
申请日：2004-05-14
Applicant: 제일모직주식회사
IPC: H01B1/22
Abstract: 본 발명의 이방성 도전성 필름에 분산되어 함유되는 절연 도전성 미립자(1)는 도전성 미립자(11)와 그 표면에 절연성 미립자(12)가 불연속적으로 고정되어 복합화된 구조를 갖는 것을 그 특징으로 한다. 상기 도전성 미립자(11)는 고분자 성분으로 이루어지는 고분자 미립자와 금속 성분으로 이루어지는 금속 미립자가 모두 적용가능하다. 상기 도전성 미립자(11)가 고분자 미립자인 경우에, 그 고분자 미립자는 고분자 코아 미립자(111)와 그 코아 미립자의 표면에 금속 성분으로 도금한 금속 도금층으로 이루어진다. 상기 금속 도금층은 니켈 도금층(112)과 금 도금층(113)으로 구성되는 것이 바람직하다.
이방성 도전성 필름, 절연 도전성 미립자, 도전성 미립자, 절연성 미립자, 고분자 코아 미립자, 금속 도금층-
公开(公告)号：KR1020050108503A
公开(公告)日：2005-11-17
申请号：KR1020040033282
申请日：2004-05-12
Applicant: 제일모직주식회사
IPC: H01B1/14
CPC classification number: H01B1/22 , H01L2224/29399 , H01L2924/01019 , H01L2924/01079 , H01L2924/07811 , H05K3/323 , H05K2201/0212 , H05K2201/0224 , Y10T428/24917 , Y10T428/25 , Y10T428/254 , Y10T428/259 , Y10T428/29 , Y10T428/2991 , Y10T428/2998 , H01L2924/00
Abstract: 본 발명에 따른 절연 전도성 미립자는 전도성 미립자, 및 상기 전도성 미립자의 표면에 불연속적으로 고정화되고, 인접한 미립자 사이에서 절연성을 부여하기 위한 절연 고착성 미립자로 이루어지고, 상기 절연 고착성 미립자가 이탈함으로써 상기 전도성 미립자가 전극 사이에 전기적으로 접속될 수 있는 것을 특징으로 한다. 또한, 본 발명에서는 절연 전도성 미립자의 제조방법, 절연 전도성 미립자를 함유하는 이방 전도성 접착 필름 및 전기적 접속 구조체가 제공된다.
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公开(公告)号：KR100506862B1
公开(公告)日：2005-08-05
申请号：KR1020030078804
申请日：2003-11-07
Applicant: 제일모직주식회사
IPC: C08F2/24
Abstract: 본 발명에 따른 캡슐화 또는 표면 관능화된 단분산성 고분자 미립자(5)는 완전-IPN(Full-Interpenetrating Polymer Network)구조를 갖는 고분자 미립자를 유화제가 용해된 수용액에 분산시켜 고분자 분산체(1)를 제조하고; 단량체, 개시제, 및 가교제가 용해된 유기용매와 분산 안정제가 용해된 수용액을 혼합·교반하여 분산체(2)를 별도로 제조하고; 상기 혼합·교반된 분산체(2)를 상기 고분자 분산체(1)와 다시 혼합·교반하여, 상기 혼합·교반된 분산체에 의해 포집된 고분자 분산체(3)를 제조하고; 상기 포집된 고분자 분산체(3)를 침적중합하여 고분자 분산체의 표면에 침적층을 형성시켜 표면 관능화된 고분자 분산체(4)를 제조하고; 그리고 상기 표면 관능화된 고분자 분산체(4) 상의 유기용매를 제거하는 단계로 제조되는 것을 특징으로 한다. 아울러 본 발명에 따른 캡슐화 또는 표면 관능화된 단분산성 고분자 미립자를 이용하여 액정 표시 장치(LCD)용 스페이서(spacer)를 제조할 수 있다.
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