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公开(公告)号：KR100489448B1
公开(公告)日：2005-05-17
申请号：KR1020030001715
申请日：2003-01-10
Applicant: 충남대학교산학협력단
IPC: C10L5/48
Abstract: 본 발명은 폐플라스틱의 열분해 왁스를 이용한 고형연료 및 그의 제조방법에 관한 것으로, 열분해 반응기(2)에 질소가스(N
2 )로 퍼지시킨 다음 폐플라스틱과 제올라이트(zeolyte Y)촉매를 투입한 후 교반시키면서 200℃ ~ 300℃ 로 가열하여 열분해(thermal cracking)시켜 평균분자량이 약 1500 ~ 2000인 왁스(wax)를 성형시키는 1공정(10)과; 상기 1공정에서 얻어진 왁스에 가연성 배합제를 10wt% ~ 70 wt%로 혼합시킨 후 성형 건조시켜 고형연료를 제조하는 2공정(20);으로 이루어짐으로써 처리 곤란한 폐비닐과 같은 폐플라스틱을 촉매와 함께 비교적 낮은 온도에서 열분해하여 왁스를 제조하고, 제조된 왁스를 결합제(binder)로 하여 오니, 석탄, 톱밥 등의 가연성 배합제와 혼합하여 열량이 높은 고형연료를 저렴한 비용으로 제조할 수 있어 폐자원을 재활용할 수 있고, 환경오염을 줄일 수 있으며, 수거된 장소에서 곧바로 연료화할 수 있어 폐자원의 재활용효율을 극대화시킬 수 있다.-
公开(公告)号：KR1020040078451A
公开(公告)日：2004-09-10
申请号：KR1020030013398
申请日：2003-03-04
Applicant: 충남대학교산학협력단
IPC: C02F1/46
Abstract: PURPOSE: An electrolytic cell for electrochemical treatment of nitrate-nitrogen containing brine waste is provided to regenerate ion exchange resin of ion exchange tower for removing nitrate-nitrogen, and an apparatus for applying the electrolytic cell is provided. CONSTITUTION: The electrolytic cell is characterized in that an electrode rod(3) on which iridium is coated on titanium is installed in the electrolytic cell, a cylindrical nickel electrode(2) is surrounded on an outer part of the electrolytic cell, suction supporting member(1) and drain supporting member(1') are installed at both sides of the nickel electrode and the electrode rod respectively, a suction port(4) for sucking a regenerated solution from a regenerated solution tank is formed on the suction supporting member, a solution discharge port(6) is formed on the drain supporting member, an anode direct current contact point(5) is installed at one side end of the electrode rod, and a cathode direct current contact point(7) is installed at the nickel electrode.
Abstract translation: 目的：提供一种用于电化学处理硝酸盐 - 含氮盐水废水的电解池，用于再生用于除去硝酸盐 - 氮的离子交换塔的离子交换树脂，并提供了一种施加电解池的设备。 构成：电解槽的特征在于，在电解槽中安装有在其上涂覆有铱的电极棒（3），圆筒状的镍电极（2）被包围在电解槽的外侧，吸引支撑构件 （1）和排水支撑构件（1'）分别安装在镍电极和电极棒的两侧，在吸力支撑构件上形成用于从再生溶液罐吸出再生溶液的吸入口（4） 在排水支撑构件上形成排液口（6），阳极直流接触点（5）安装在电极棒的一侧，阴极直流接触点（7）安装在镍 电极。
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公开(公告)号：KR1020040064850A
公开(公告)日：2004-07-21
申请号：KR1020030001715
申请日：2003-01-10
Applicant: 충남대학교산학협력단
IPC: C10L5/48
Abstract: PURPOSE: Provided are a solid fuel by using wax made by thermal-cracking plastics and a method for preparing thereof, which provide the solid fuel providing high calorie without generating contaminates with moderate cost. CONSTITUTION: The method comprises steps of (a) a first process of after purging N2 gas in a thermal-cracking reactor and putting waste plastics and zeolite Y catalyst therein, thermally cracking it at a temperature of 200-300 °C with stirring to prepare a wax having an average molecular weight of about 1,500-2,000; and (b) a second process after mixing the wax of the step (a) with 10-70 wt.% of a flammable mixing agent, molding and drying the mixture to prepare a solid fuel.
Abstract translation: 目的：通过使用由热裂解塑料制成的蜡及其制备方法提供固体燃料，其提供提供高热量的固体燃料而不产生中等成本的污染物。 方法：该方法包括以下步骤：（a）在热裂解反应器中清洗N 2气体并在其中放入废塑料和沸石Y催化剂之后的第一工序，在200-300℃的温度下搅拌进行热裂解以制备 平均分子量为约1,500-2,000的蜡; 和（b）将步骤（a）的蜡与10-70重量％的可燃混合剂混合后的第二工序，模塑和干燥混合物以制备固体燃料。
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公开(公告)号：KR1020040009598A
公开(公告)日：2004-01-31
申请号：KR1020020043600
申请日：2002-07-24
Applicant: 충남대학교산학협력단
IPC: B01D39/14
CPC classification number: B01D39/14 , B01D39/2065 , B01D47/00 , B01D53/78 , B01D2239/0618 , B01D2239/065 , B01D2239/10
Abstract: PURPOSE: Provided is a method for fabricating an ion exchange filter being capable of treating VOCs as well as ionized hazardous gases with high efficiency, not causing secondary pollution such as a large amount of wastewater, being regenerable, and being easily produced by a simple process. CONSTITUTION: The method comprises the steps of preparing non woven fabric by mixing carbon fiber and ion exchange fiber, attaching the non woven fabric on the surface of a plastic panel, and assembling an ion exchange filter(7) by stacking a plurality of the non woven fabric panels(3) with supporting bars(4) and inner packings(5) every between the panels(3) and securing the panels(3) together by an external packing(6).
Abstract translation: 目的：提供一种能够高效率地处理VOC和离子化危险气体的离子交换过滤器的制造方法，不会产生二次污染，例如大量的废水，可再生，并且易于通过简单的方法生产 。 构成：该方法包括以下步骤：通过混合碳纤维和离子交换纤维来制备无纺织物，将无纺织物附着在塑料面板的表面上，并通过堆叠多个非织造织物组装离子交换过滤器（7） 每个面板（3）之间都有支撑杆（4）和内部填料（5）的编织织物面板（3），并通过外部填料（6）将面板（3）固定在一起。
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25.发明授权
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Patent Agency Ranking
公开(公告)号：KR100539285B1
公开(公告)日：2005-12-28
申请号：KR1020030032139
申请日：2003-05-21
Applicant: 충남대학교산학협력단
IPC: C07B41/08
Abstract: 본 발명은 PET(폴리에스터) 올리고머를 메탄올리시스하여, 분리 정제하여 폴리에스터 제조원료인 순수한 디메틸테레프탈레이트(DMT)를 얻는 새로운 방법에 관한 것이다.
본 발명에서는 메탄올리시스 반응기와 증류탑을 일체화시키고 공정의 압력을 전공정에서 DMT의 응고점 이상으로 유지시켜서 공정의 단순화와 DMT의 막힘문제로 인한 조업상의 문제점을 해결한다.
본 발명에 의한 복합장치에 의하면, 증류 작업 중 DMT가 석출되지 않아 조업의 안정성을 높이고, 반응 전환율을 최대화할 수 있기 때문에 반응 수율 및 분리 효율을 높이고 에너지 절약이 가능하게 된다.-
公开(公告)号：KR100514380B1
公开(公告)日：2005-09-30
申请号：KR1020020043600
申请日：2002-07-24
Applicant: 충남대학교산학협력단
IPC: B01D39/14
Abstract: 본 발명은 유기휘발성분(VOC) 및 이온성 유해가스를 동시에 처리가 가능하도록 한 배기가스 처리 스크러버용 유·무기 복합필터의 제조에 관한 것으로, 그 목적은 종래의 산업 유해가스 처리에 있어 사용하는 습식 및 건식 스크러버 방법에 있어서, VOC 또는 이온성 유해가스등 한종류의 처리에 국한되는 단점이 있고, 습식의 경우 처리후 다량의 폐수가 발생하여 2차 오염이 야기되며, 활성탄과 같은 무기물 흡착제를 사용한 필터는 1회용이고 특히 공정상 압력강하의 단점이 있어, 이들의 단점인 압력강하가 적고 VOC 및 이온성 유해가스를 고효율로 동시에 제거하고, 특히 1회용이 아닌 재생이 가능한 장수명의 배가스 처리 스크러버용 유·무기 복합필터 제조방법을 제공하는데 있다.
본 발명의 구성은 무기흡착제로 활성탄소섬유(ACF) 부직포와 유기흡착제로 섬유상 이온교환체(IXF) 부직포를 일정비율로 혼합한 스크러버 장치에 탈·부착이 간편하도록 만든 신개념의 표준필터이다.-
公开(公告)号：KR1020040099973A
公开(公告)日：2004-12-02
申请号：KR1020030032142
申请日：2003-05-21
Applicant: 충남대학교산학협력단
IPC: C07B41/08
CPC classification number: C07B63/00
Abstract: PURPOSE: An apparatus and an operation method thereof are provided to produce dimethyl terephthalate(DMT) and ethylene glycol(EG) as raw materials of a polyester from a polyester oligomer by a methanolysis using a circulation type bubble reactor. The apparatus increases a fractional conversion of the reaction remarkably. CONSTITUTION: The apparatus(9) contains an oligomer sludge supply device, a methanol supply device, and a stirring device(8), wherein a partition(7) is formed in the apparatus(9) on the same axis as the outer wall of the apparatus(9) and a methanol gas dispersing device(6) of the methanol supply device is mounted in the lower part of the partition(7). The stirring device(8) makes the oligomer sludge flow downward in the partition(7), therefore the oligomer sludge flows in the opposite direction to methanol bubbles in the partition(7). The oligomer sludge flows downward inside the partition(7) and flows upward outside the partition(7). And the partition(7) and the methanol gas dispersing device(6) can be mounted repeatedly in the vertical direction.
Abstract translation: 目的：提供一种装置及其操作方法，通过使用循环型气泡反应器通过甲醇分解从聚酯低聚物制备作为聚酯的聚酯的原料的对苯二甲酸二甲酯（DMT）和乙二醇（EG）。 该装置显着增加反应的分数转化率。 方案：装置（9）包含低聚物污泥供应装置，甲醇供应装置和搅拌装置（8），其中在装置（9）中在与外壁相同的轴上形成隔板（7） 装置（9）和甲醇供给装置的甲醇气体分散装置（6）安装在隔板（7）的下部。 搅拌装置（8）使得低分子污泥在分隔件（7）中向下流动，因此低聚物污泥在与隔板（7）中的甲醇气泡相反的方向上流动。 低聚物污泥在隔板（7）的内部向下流动，并向上流动到隔板（7）的外面。 分隔件（7）和甲醇气体分散装置（6）可以沿垂直方向重复安装。
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公开(公告)号：KR1020040076642A
公开(公告)日：2004-09-03
申请号：KR1020030011946
申请日：2003-02-26
Applicant: 충남대학교산학협력단
IPC: C10L5/48
Abstract: PURPOSE: A method for preparing a solid fuel by using waste plastic is provided, which is characterized in that waste plastic undergoes thermal cracking at about 250 deg.C after an appropriate amount of a catalyst is added to the waste plastic. CONSTITUTION: The method comprises steps of (a) after adding a catalyst to collected waste plastic, thermal cracking it within at 200 to 250 deg.C to obtain a liquid-phase substance having low molecular weight; and (b) after mixing the liquid substance with a flammable substance at certain mixing ratio, molding the mixture.
Abstract translation: 目的：提供一种通过使用废塑料制备固体燃料的方法，其特征在于，在将适量的催化剂加入到废塑料中之后，废塑料在约250℃发生热裂解。 方法：该方法包括以下步骤：（a）在收集的废塑料中加入催化剂后，在200〜250℃热裂解，得到低分子量的液相物质; 和（b）在一定混合比例下将液体物质与易燃物质混合后，将混合物成型。
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公开(公告)号：KR1020030091246A
公开(公告)日：2003-12-03
申请号：KR1020020029124
申请日：2002-05-25
Applicant: 충남대학교산학협력단
IPC: B01D39/16
CPC classification number: B01D39/1607 , B01D2239/10
Abstract: PURPOSE: A method for fabricating hybrid ion exchange fiber of adsorbent cake type which separates air pollutants, removes heavy metals from liquid phase waste and recovers valuable metal at high efficiency is provided. CONSTITUTION: The method comprises the processes of crushing ion exchange fiber to a size of 1 to 5 mm; crushing the swollen bead ion exchange body to a certain size by swelling a bead ion exchange body; dispersing the crushed bead ion exchange body into a water based binder added aqueous solution in a ratio of 0 to 30 vol.% for ion exchange fiber; putting the crushed bead ion exchange body dispersed solution into an acryl or glass tube having a certain diameter; removing water from the solution in the acryl or glass tube under the vacuum state of 750 mmHg or less; preparing adsorbent cake by pressing the water removed solution; separating the pressed adsorbent cake, and drying the separated pressed adsorbent cake in a vacuum oven of 60 deg.C for 24 hours, thereby completely removing water from the adsorbent cake.
Abstract translation: 目的：制造分离空气污染物的吸附剂饼型混合离子交换纤维的方法，从液相废物中除去重金属，并以高效率回收有价值的金属。 方法：该方法包括将离子交换纤维粉碎至1〜5mm的工序; 通过溶胀珠离子交换体，将溶胀的珠粒离子交换体破碎成一定的大小; 将粉碎的离子交换体以0〜30体积％的比例将离子交换纤维分散在水性粘合剂添加水溶液中; 将破碎的珠粒离子交换体分散溶液放入具有一定直径的丙烯酸或玻璃管中; 在750mmHg以下的真空状态下从丙烯酸或玻璃管中的溶液中除去水分; 通过按压除去水的溶液制备吸附剂滤饼; 分离压榨的吸附剂滤饼，并在60℃的真空烘箱中干燥分离的压制吸附剂饼24小时，从而完全从吸附剂滤饼中除去水分。
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