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公开(公告)号：KR101655143B1
公开(公告)日：2016-09-07
申请号：KR1020130160456
申请日：2013-12-20
Applicant: 현대자동차주식회사 , 충남대학교산학협력단
CPC classification number: C01B3/08 , C01F7/00 , C01F7/428 , H01M8/065 , H01M2250/20 , Y02E60/36 , Y02E60/50 , Y02T90/32
Abstract: 연료전지의수소공급시스템에서알루미늄및 금속수산화물의반응을통해수소를생성하는단계; 상기반응에서수소와동시에생성된알루미늄화합물을회수하는단계; 상기알루미늄화합물로부터알루미늄수산화물을수득하는단계; 상기알루미늄수산화물을열처리하여산화알루미늄을수득하는단계; 상기산화알루미늄을환원하여알루미늄을수득하는단계; 및상기수득된알루미늄을상기수소생성단계의원료로재공급하는단계를포함하는연료전지수소공급시스템의원료재생방법및 원료재생시스템에관한것이다.
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公开(公告)号：KR101500069B1
公开(公告)日：2015-03-06
申请号：KR1020130039835
申请日：2013-04-11
Applicant: 현대자동차주식회사 , 숭실대학교산학협력단
CPC classification number: H01M4/9075 , H01M4/925 , Y02E60/50
Abstract: 본 발명은 연료전지용 촉매전극을 위한 티타늄 서브옥사이드 지지체와 이의 저온 합성방법에 관한 것으로서, 더욱 상세하게는 연료전지의 촉매전극의 지지체로 유용한 티타늄 서브옥사이드(Ti
x O
2x-1 ) 나노입자와, TiO
2 , Co 촉매 및 수소가스를 이용하여 600∼900℃의 낮은 온도에서 상기 티타늄 서브옥사이드(Ti
x O
2x-1 ) 나노입자를 합성하는 방법에 관한 것이다.
상기 티타늄 서브옥사이드 나노입자는 산에 대한 부식저항성이 뛰어나고 열적, 전기적인 전기전도도가 크고, 내구성이 뛰어난 장점을 가지고 있으므로, 이를 지지체로 사용하여 제조된 촉매전극은 연료전지 테스트를 통해 높은 촉매활성과 산화환원 특성이 향상된 효과를 나타낸다.-
公开(公告)号：KR1020130035076A
公开(公告)日：2013-04-08
申请号：KR1020110099337
申请日：2011-09-29
Applicant: 현대자동차주식회사 , 주식회사 동진쎄미켐
CPC classification number: B01D71/82 , H01M8/1027 , H01M8/1032 , H01M8/1044 , H01M8/1048 , H01M8/1051
Abstract: PURPOSE: A proton-conducting polymer is provided to have a plurality of proton-conducting polymers, to have excellent dimensional stability, and to have high ion exchange capacity and hydrogen ion conductivity. CONSTITUTION: A proton-conducting polymer is represented by chemical formula 1. In the chemical formula 1: m is an integer from 0.01-0.99; n is an integer from 10-1,000; Y is a chemical bond, oxygen, or sulfur, independently; each of D and E is a divalent coupling group which comprises one or more selected from a substituted or unsubstituted C1-10 alkylene group, a substituted or unsubstituted C2-10 alkenylene group, a substituted or unsubstituted C6-20 arylene group, a sulfone group, or a carbonyl group; and Z is represented by chemical formula 2a.
Abstract translation: 目的：提供质子传导聚合物以具有多个质子传导聚合物，具有优异的尺寸稳定性，并具有高离子交换能力和氢离子传导性。 构成：质子导电聚合物由化学式1表示。在化学式1中：m是0.01-0.99的整数; n为10-1000的整数; Y是独立的化学键，氧或硫; D和E中的每一个是包含一个或多个选自取代或未取代的C 1-10亚烷基，取代或未取代的C 2-10亚烯基，取代或未取代的C 6-20亚芳基，砜基 ，或羰基; Z由化学式2a表示。
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公开(公告)号：KR1020120057432A
公开(公告)日：2012-06-05
申请号：KR1020100119155
申请日：2010-11-26
Applicant: 현대자동차주식회사 , 기아자동차주식회사 , 연세대학교 산학협력단
Abstract: PURPOSE: A method for manufacturing alloy catalyst based on conductive polymer protective coating is provided to improve dispersity by suppressing the size growth of catalytic particles based on the carbonization of conductive polymer. CONSTITUTION: A carbon immersed platinum catalyst is prepared. The surface of the platinum catalyst is coated with conductive polymer. Transition metal salt is immersed to the coated catalyst. The transition metal salt immersed catalyst is thermally treated. The carbon is one selected from carbon nano-tubes, carbon nano-fiber, carbon nano-coils, and carbon nano-cages. The conductive polymer is polypyrrole or polyaniline.
Abstract translation: 目的：提供一种基于导电聚合物保护涂层制造合金催化剂的方法，以通过基于导电聚合物的碳化抑制催化剂颗粒的尺寸生长来改善分散性。 构成：制备碳浸铂催化剂。 铂催化剂的表面涂覆有导电聚合物。 将过渡金属盐浸入涂覆的催化剂中。 过渡金属盐浸渍催化剂进行热处理。 碳选自碳纳米管，碳纳米纤维，碳纳米线圈和碳纳米笼。 导电聚合物是聚吡咯或聚苯胺。
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公开(公告)号：KR101134478B1
公开(公告)日：2012-04-13
申请号：KR1020100013909
申请日：2010-02-16
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
IPC: C08F293/00 , C08F297/00 , H01M8/02 , H01M8/10
CPC classification number: H01M8/1023 , C08F8/36 , C08F293/00 , C08G65/48 , C08G75/23 , C08G2261/722 , C08G2650/40 , C08L71/00 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , Y02P70/56 , C08L25/06 , C08L25/04 , C08F293/005
Abstract: 본 발명은 양친성 블록 공중합체 , 이의 제조방법 및 이를 이용한 연료전지용 막에 관한 것이다. 보다 상세하게는 소수부로서 PSEK[poly(arylene sulfone ether ketone)]과 친수부의 PSSAN[poly(sulfonated styrene-co-acrylonitrile)]을 포함하는 블록 공중합체에 관한 것이다.
상기 양친성 블록 공중합체를 이용하여 제조된 고분자 전해질 막은 100℃ 이상의 고온에서도 수소이온전도도가 감소하는 경향을 보이지 않고, 오히려 증가하는 경향을 보였으며, 높은 열적/화학적 치수안정성을 보인다.-
Patent Agency Ranking
公开(公告)号：KR101113632B1
公开(公告)日：2012-03-13
申请号：KR1020090103747
申请日：2009-10-29
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
CPC classification number: H01M4/92 , H01M4/8663 , H01M4/885 , H01M4/926 , Y02E60/50
Abstract: 본 발명은 탄소에 담지된 전이금속 나노입자 촉매의 제조방법에 관한 것으로서, 더욱 상세하게 설명하면 에탄올에 안정화제를 녹인 혼합액에 담지체를 넣어 분산액을 제조하고, 여기에 전이금속 전구체를 에탄올에 용해시킨 전구체 용액을 혼합 및 교반한 후 환원공정을 거쳐 전이금속 나노입자 촉매를 제조하는 것을 특징으로 한다. 본 발명의 탄소에 담지된 전이금속 나노입자 촉매의 제조방법은 간단한 공정으로 좁은 입자 크기 분포와 넓은 분산도를 가지는 탄소분말에 담지된 전이금속 나노입자의 제조가 가능하여 연료전지의 전극물질 등에 유용하게 적용될 수 있다.
연료전지, 전이금속, 수소화붕소나트륨, 안정화제, 나노입자-
公开(公告)号：KR1020110094498A
公开(公告)日：2011-08-24
申请号：KR1020100013909
申请日：2010-02-16
Applicant: 현대자동차주식회사 , 서울대학교산학협력단
IPC: C08F293/00 , C08F297/00 , H01M8/02 , H01M8/10
CPC classification number: H01M8/1023 , C08F8/36 , C08F293/00 , C08G65/48 , C08G75/23 , C08G2261/722 , C08G2650/40 , C08L71/00 , C08L2205/05 , H01M8/1025 , H01M8/1027 , H01M8/1044 , H01M8/1072 , H01M2300/0082 , Y02P70/56 , C08L25/06 , C08L25/04 , C08F293/005
Abstract: PURPOSE: A hydrophilic-hydrophobic block copolymer is provided to ensure excellent thermomechanical stability, and to obtain an electrolyte film for a polymer electrolyte fuel cell with excellent thermal, chemical, and mechanical stability while having high hydrogen ion conductivity at high temperature. CONSTITUTION: A hydrophilic-hydrophobic block copolymer comprises one or more of homopolymers having hydrophobicity and polymers having hydrophilicity. The hydrophobic part includes the structure represented by chemical formula 1 and the hydrophilic part includes the structure represented by chemical formula 2. In chemical formula 2, p, m and are mutually independent integer, and m > r.
Abstract translation: 目的：提供亲水疏水性嵌段共聚物，以确保优异的机械稳定性，并获得具有优异的热稳定性，化学稳定性和机械稳定性的聚合物电解质燃料电池的电解质膜，同时在高温下具有高的氢离子传导性。 构成：亲水疏水性嵌段共聚物包含一种或多种具有疏水性的均聚物和具有亲水性的聚合物。 疏水部分包括由化学式1表示的结构，亲水部分包括由化学式2表示的结构。在化学式2中，p，m和相互独立的整数，并且m> r。
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28.发明公开술폰산기를 갖는 폴리(아릴렌에테르) 공중합체, 이의 제조방법 및 이를 이용한 연료전지용 고분자 전해질 막 有权磺化聚（亚乙基醚）共聚物，其制备方法和聚合物电解质膜用于使用共聚物的燃料电池
公开(公告)号：KR1020110063178A
公开(公告)日：2011-06-10
申请号：KR1020090120133
申请日：2009-12-04
Applicant: 현대자동차주식회사 , 주식회사 동진쎄미켐
IPC: C08G65/334 , C08G65/32 , C08J5/22 , H01M8/10
CPC classification number: H01M8/1025 , C08G65/4012 , C08G65/48 , C08G75/23 , C08G2261/722 , C08J5/2256 , C08J2371/12 , C08J2481/06 , H01M8/1027 , H01M8/103 , H01M8/1032 , H01M8/1039 , H01M8/1044 , H01M8/1048 , H01M8/1051 , H01M8/1072 , H01M2300/0082 , H01M2300/0091 , Y02P70/56
Abstract: PURPOSE: A poly(arylene ether) copolymer having a sulfonic acid group is provided to ensure high hydrogen ion conductivity and excellent mechanical properties due to high sulfonation degree and high average molecular weight. CONSTITUTION: A poly(arylene ether) copolymer having a sulfonic acid group is represented by chemical formula 3. A polymer electrolyte membrane comprises the poly(arylene ether) copolymer. The polymer electrolyte membrane further includes one or more polymers selected from the group consisting of polyimide, polyetherketone, polysulfone, polyethersulfone, polyetherethersulfone, polybenzimidazole, polyphenylene oxide, polyphenylene sulfide, polystyrene, polytrifluorostyrene sulfonic acid, polystyrenesulfonic acid, polyurethane, and branched sulfonated polysulfone ketone copolymers.
Abstract translation: 目的：提供具有磺酸基的聚（亚芳基醚）共聚物，以确保高磺化程度和高平均分子量的高氢离子传导性和优异的机械性能。 构成：具有磺酸基的聚（亚芳基醚）共聚物由化学式3表示。聚合物电解质膜包含聚（亚芳基醚）共聚物。 聚合物电解质膜还包括一种或多种选自聚酰亚胺，聚醚酮，聚砜，聚醚砜，聚醚醚砜，聚苯并咪唑，聚苯醚，聚苯硫醚，聚苯乙烯，聚三氟苯乙烯磺酸，聚苯乙烯磺酸，聚氨酯和支链磺化聚砜酮 共聚物。
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公开(公告)号：KR1020110060094A
公开(公告)日：2011-06-08
申请号：KR1020090116575
申请日：2009-11-30
Applicant: 현대자동차주식회사
CPC classification number: H01M4/8605 , H01M4/8896 , H01M4/921 , H01M4/926
Abstract: PURPOSE: An electrode for a polymer electrolyte membrane fuel cell is provided to reinforce mechanical strength and to maintain the thickness of a catalyst layer after long time driving by adding carbon nano fibers to an electrode catalyst layer of a fuel cell. CONSTITUTION: An electrode for a polymer electrolyte membrane fuel cell comprises, 100.0 parts by weight of a catalyst, 20~80 parts by weight of hydrogen ion conductive polymer electrolyte binder, 1~60 parts by weight of carbon nanofiber, 1~20 parts by weight of radical inhibitor. The carbon nano fiber is one selected from the group consisting of carbon nanotubes with 5~100 nm size, carbon nanofiber, carbon nanowires, carbon nanohorns, and carbon nanorings, and their mixture.
Abstract translation: 目的：提供一种聚合物电解质膜燃料电池用电极，通过向燃料电池的电极催化剂层添加碳纳米纤维，来增强机械强度并长时间驱动后维持催化剂层的厚度。 构成：用于聚合物电解质膜燃料电池的电极包括：100.0重量份催化剂，20〜80重量份氢离子导电聚合物电解质粘合剂，1〜60重量份碳纳米纤维，1〜20重量份 自由基抑制剂的重量。 碳纳米纤维是选自具有5〜100nm尺寸的碳纳米管，碳纳米纤维，碳纳米线，碳纳米角和碳纳米线的组合，以及它们的混合物。
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公开(公告)号：KR1020090062108A
公开(公告)日：2009-06-17
申请号：KR1020070129213
申请日：2007-12-12
Applicant: 현대자동차주식회사
CPC classification number: H01M4/8605 , H01M4/8663 , H01M4/8814 , H01M4/926 , H01M8/1004 , Y02E60/521
Abstract: A membrane electrode assembly for a polymer electrolyte fuel cell is provided to improve the performance of a fuel cell due to low diffusion resistance to reactive gas and high limit current by employing a catalyst layer including micro pores. A membrane electrode assembly for a polymer electrolyte fuel cell comprises a platinum catalyst supported in carbon, a hydrogen-ion-conductive polymer, and a catalyst layer(11) including micropores(18) at both ends of the polymer electrolyte membrane. The catalyst layer additionally includes pores of 0.02~0.2 micron and micro pores of average 0.5~3 micron diameter.
Abstract translation: 提供了一种用于聚合物电解质燃料电池的膜电极组件，以通过使用包括微孔的催化剂层，由于对反应气体的低扩散阻力和高限度电流而改善燃料电池的性能。 用于聚合物电解质燃料电池的膜电极组件包括负载在碳中的铂催化剂，氢离子导电聚合物和在聚合物电解质膜的两端包括微孔（18）的催化剂层（11）。 催化剂层另外包括0.02〜0.2微米的孔和平均0.5〜3微米直径的微孔。
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