公开(公告)号：US10932994B2

公开(公告)日：2021-03-02

申请号：US15324760

申请日：2015-07-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Reinhold Hecht ,  Manfred Ludsteck ,  Andrea Stippschild-Boxler ,  Gioacchino Raia ,  Rainer A. Guggenberger

IPC: A61K6/887 ,  A61K6/62 ,  A61K6/30 ,  A61K6/80 ,  C08L33/10 ,  A61K6/61 ,  A61K6/20 ,  A61K6/54 ,  A61K6/76 ,  A61K6/77

Abstract: The present invention relates to a kit of parts comprising Part A and Part B, Part A comprising: ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s), The invention is also directed to a redox initiator system comprising ascorbic acid, component(s) comprising an ascorbic acid moiety or derivative(s) thereof, transition metal component(s), preferably comprising a copper or iron ion containing salt, organic peroxide(s), preferably comprising a hydroperoxide or di-peroxide. The kit of parts and redox initiator system are particularly useful in the dental field.

公开(公告)号：US20200206092A1

公开(公告)日：2020-07-02

申请号：US16622530

申请日：2018-06-05

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Andreas Herrmann ,  Gioacchino Raia ,  Malte Korten ,  Oliver Kappler ,  Bernhard Hofmann ,  Adrian Eckert ,  Helmar Mayr ,  Reinhold Hecht ,  Gallus Schechner ,  Rainer Guggenberger

IPC: A61K6/887 ,  A61K6/17 ,  A61K6/62 ,  A61K6/65 ,  A61C5/73 ,  A61K6/76 ,  A61K6/77 ,  C08L33/08 ,  C08L33/10 ,  C08L75/06

Abstract: The invention relates to A curable composition for producing dental composite crowns, the composition comprising a resin matrix comprising polymerizable (meth)acrylate(s) not comprising a urethane moiety, polymerizable urethane(meth)acrylate(s), wherein the polymerizable (meth)acrylate(s) not comprising an urethane moiety are used in excess over the polymerizable urethane(meth)acrylate(s), a filler matrix comprising nanocluster(s), fumed silica in an amount below 8 wt. % with respect to the weight of the whole composition, an initiator system comprising photoinitiator(s), organic dye(s), the curable composition not comprising softener in an amount of more than 5 wt. % with respect to the weight of the whole composition, the curable composition having a viscosity below 150 Pa*s at 23° C. and a shear rate of 1 s−1. The invention also relates to a cured article obtained by radiation curing this curable composition by use of an additive-manufacturing method.

公开(公告)号：US20190000721A1

公开(公告)日：2019-01-03

申请号：US15781403

申请日：2016-12-07

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Manfred Ludsteck ,  Reinhold Hecht ,  Kai U. Claussen ,  Hubert Rennschmid ,  Lilly Vogel

IPC: A61K6/083 ,  A61K6/00

Abstract: The invention relates to a kit of parts comprising Part A and Part B, Part A comprising: component(s) comprising an ascorbic acid moiety, stabilizer(s) selected from sulphite(s), phosphite(s) or mixtures thereof, optionally polymerizable component(s) without acidic moieties, optionally polymerizable component(s) with acidic moieties, and optionally filler(s), Part B comprising polymerizable component(s) without acidic moieties, polymerizable component(s) with acidic moieties, transition metal component(s), organic peroxide(s), and optionally filler(s). The invention is also directed to an initiator system comprising component(s) comprising an ascorbic acid moiety, stabilizer(s) selected from sulphite(s), phosphite(s) or mixtures thereof transition metal component(s), organic peroxide(s). The kit of parts and redox initiator system are particularly useful in the dental and orthodontic field.

公开(公告)号：US09132069B2

公开(公告)日：2015-09-15

申请号：US14360373

申请日：2012-11-30

Applicant: 3M INNOVATIVE PROPERTIES COMPANY

Inventor： Reinhold Hecht ,  Andrea Stippschild ,  Vitore Hasanaj ,  Gioacchino Raia ,  Manfred Ludsteck ,  Rainer Guggenberger

IPC: A61K6/083 ,  C09J133/10 ,  C09J133/14 ,  C09J175/16 ,  A61C13/15

CPC classification number: A61K6/083 ,  A61C19/003 ,  C09J133/10 ,  C09J133/14 ,  C09J175/16 ,  C08L33/00 ,  C08L43/02

Abstract: The invention relates to a one-component self-adhesive composition for dental use comprising radically polymerizable component(s) with an acidic moiety as component A, radically polymerizable component(s) without an acidic moiety as component (B), an oxidizing agent comprising persulfate(s) as component (C), transition metal component(s) as component (D), photoinitiator system(s) as component (E), optionally non acid-reactive filler(s) as component (F), and optionally additive(s) as component (G).

Abstract translation: 本发明涉及一种用于牙科用途的单组分自粘组合物，其包含具有酸性部分作为组分A的可自由基聚合的组分，不具有作为组分（B）的酸性部分的可自由基聚合的组分，包含 作为组分（C）的过硫酸盐，作为组分（D）的过渡金属组分，作为组分（E）的光引发剂体系，作为组分（F）的任选的非酸反应性填料，以及任选的 添加剂作为组分（G）。