公开(公告)号：JPH04120192A

公开(公告)日：1992-04-21

申请号：JP24167690

申请日：1990-09-11

Applicant: AGENCY IND SCIENCE TECHN

Inventor： YOSHIDA TADASHI ,  MAEKAWA WAKINORI ,  YOSHIDA RYOICHI ,  KOTANIGAWA TAKESHI ,  YOKOYAMA SHINICHI ,  YAMAMOTO MITSUYOSHI ,  NAGAISHI HIROSHI ,  FUKUDA TAKASHI ,  IDOKAWA KIYOSHI ,  HIRAMA TOSHIMASA

IPC: B01J27/051 ,  C10G47/02 ,  C10G47/34

Abstract: PURPOSE:To improve heat efficiency of process and to efficiently improve light oil fraction yield by adding a hydrogen donative solvent to a heavy oil fraction and subjecting the fraction to hydrogenolysis reaction in the presence of a hydrogenating catalyst under a specific condition. CONSTITUTION:A hydrogen donative solvent such as tetralin, dihydroanthracene or dihydropyrene is added to a heavy oil fraction such as petroleum, tar sand bitumen or shale oil and subjected to hydrogenolysis reaction in the presence of a hydrogenating catalyst at 400-460 deg.C (preferably 420-450 deg.C) under 100-300kg/ cm G (preferably 100-200kg/cm G) hydrogen pressure to give a light oil fraction.

公开(公告)号：JP2001051276A

公开(公告)日：2001-02-23

申请号：JP2000208722

申请日：2000-07-10

Applicant: AGENCY IND SCIENCE TECHN ,  FUKUDA TAKASHI ,  MATSUDA HIROO

Inventor： FUKUDA TAKASHI ,  MATSUDA HIROO ,  NISHIKADO TADAMORI ,  KATO MASAO

IPC: G02F1/1337 ,  C08F2/48 ,  C08F20/34 ,  G02F1/1333

Abstract: PROBLEM TO BE SOLVED: To form a polymerized film, which controls interaction between a substrate and a liquid crystal, on a cell substrate by incorporating a divinyl compound into the liquid crystal and photopolymerizing the divinyl compound on a cell substrate by being irradiated with light from a transparent substrate side. SOLUTION: A polymerized film is formed on a liquid crystal cell substrate in which a liquid crystal is encapsulated between two substrates at least one of which is a transparent substrate. For this purpose, a divinyl compound is incorporated into the liquid crystal and photopolymerized on the substrate by being irradiated with light from the side of the transparent substrate. The used divinyl compound has two vinyl groups in its molecule and is a low molecular weight compound having a molecular weight of 1,000 or lower, preferably 400 or lower. The lower limit of the molecular weight is normally about 250. The divinyl compound expressed by the formula is preferably used. In the formula, A denotes a linear molecule backbone part and R3-R8 each denotes hydrogen or a substituent. The linear molecule backbone part A includes a linear bivalent aliphatic group and the like.

公开(公告)号：JPH11322685A

公开(公告)日：1999-11-24

申请号：JP14214298

申请日：1998-05-08

Applicant: AGENCY IND SCIENCE TECHN ,  MATSUDA HIROO ,  FUKUDA TAKASHI

Inventor： MATSUDA HIROO ,  FUKUDA TAKASHI ,  KIMURA TATSUMI ,  KATO MASAO ,  OKADA SHUJI ,  NAKANISHI HACHIRO

IPC: G02F1/35 ,  C07C227/18 ,  C07C229/60 ,  C07C253/30 ,  C07C255/55 ,  C07C323/62 ,  G02F1/355 ,  G02F1/361

Abstract: PROBLEM TO BE SOLVED: To obtain a novel compound that has a good level of optical transparency and the secondary nonlinear optical property and is useful as an organic secondary nonlinear optical material. SOLUTION: This novel compound is represented by formula I (X is a dialkylamino, an alkylthio; Y is nitro or cyano; n is 1-3), typically the compound of formula II. The compound of formula I is prepared by reaction of an aromatic carboxylic halide of formula III (Hal is a halogen), for example, 4- dimethylaminobenzoyl chloride, with a p-substituted phenol, for example, 4- cyanophenol or the like in the presence of a hydrogen halide acceptor in an inert solvent such as acetone and the like.

公开(公告)号：JPH1167591A

公开(公告)日：1999-03-09

申请号：JP23902097

申请日：1997-08-20

Applicant: AGENCY IND SCIENCE TECHN ,  FUKUDA TAKASHI ,  MATSUDA HIROO

Inventor： FUKUDA TAKASHI ,  MATSUDA HIROO ,  KATO MASAO ,  NAKANISHI HACHIRO

IPC: B32B17/10 ,  G02F1/061 ,  G02F1/361 ,  H01G7/02

Abstract: PROBLEM TO BE SOLVED: To provide an electret having high secondary non-linear optical characteristics by a method wherein the electret consists of a polar high- molecular thin film, which is formed on a glass substrate and is turned into an electret, and the electric resistance value between the surface and the rear of the glass substrate is set in a specified range. SOLUTION: A polar high-molecular thin film is formed on the surface of a glass substrate, the electric resistance value between the surface and the rear of which is in a range of satisfy 0.8Ω0

公开(公告)号：JPH1121272A

公开(公告)日：1999-01-26

申请号：JP13437198

申请日：1998-04-28

Applicant: AGENCY IND SCIENCE TECHN ,  MATSUDA HIROO ,  FUKUDA TAKASHI

Inventor： MATSUDA HIROO ,  FUKUDA TAKASHI ,  YAMADA SHINJI ,  KIMURA TATSUMI ,  KATO MASAO ,  DAN NOBUAKI ,  OKADA SHUJI ,  NAKANISHI HACHIRO

IPC: G02F1/35 ,  C07C67/14 ,  C07C69/92 ,  C07C69/94 ,  C07C201/12 ,  C07C205/43 ,  C07C255/01 ,  C07C255/38 ,  C07C255/55 ,  C07C317/22 ,  G02F1/355 ,  G02F1/361

Abstract: PROBLEM TO BE SOLVED: To obtain the subject new compound excellent in secondary nonlinear optical characteristics, having excellent optical transparency. SOLUTION: This compound is that one expressed by formula I [R is a lower alkyl; R is perfluoroalkyl, cyano, nitro, 2,2-dicyanoethenyl or methylsulfonyl; (n) is 1-3], e.g. 4-anisic acid 4-cyanophenyl-ester. The compound of formula I is obtained by adding p-substituted phenol expressed by formula III little by little into a solvent contg. an aromatic carboxylic halide expressed by formula II (X is a halide) at room temperature or under iced conditions, reacting with each other in the presence of a hydrogen halide catcher (e.g. a tertiary amine, such as trimethylamine, triethylamine, pyridine), preferably, in an inert solvent (e.g. acetone, methylethylketone, diethylether) for 1-30 hrs., washing the resulting product with water and separating the organic layer to remove the solvent.

公开(公告)号：JPH11322690A

公开(公告)日：1999-11-24

申请号：JP14213298

申请日：1998-05-08

Applicant: AGENCY IND SCIENCE TECHN ,  FUKUDA TAKASHI ,  MATSUDA HIROO

Inventor： FUKUDA TAKASHI ,  MATSUDA HIROO ,  MIYAJI YOJI ,  KATO MASAO ,  NAKANISHI HACHIRO

IPC: G02F1/35 ,  C07C245/08 ,  G02F1/355 ,  G02F1/361

Abstract: PROBLEM TO BE SOLVED: To produce a new divinyl compound capable of forming a three- dimensional network structure capable of manifesting high secondary nonlinear optical characteristics and useful as an organic secondary nonlinear optical material by carrying out a photopolymerization while applying an electrical field. SOLUTION: This compound is represented by formula I [R is H or methyl; R is a lower alkyl; (n) is 4-8], e.g. 4-biphenylphenyl 4'-[N-(6- methacryloyloxyhexyl)-N-methylamino]-azobenzene-4-carboxylate. The compound represented by formula I is produced by reacting a compound represented by formula II (e.g. N-methacryloyloxyhexyl-N-methylaniline) with 4-aminobenzoic acid and a nitrite such as sodium nitrite, forming an azo compound represented by formula III e.g. 4'-[N-(6-methacryloyloxyhexyl)-N-methylamino]-azobenzene-4- carboxylic acid}, then converting the resultant compound into an acid halide and subsequently reacting the prepared acid halide with p-vinylphenol.

公开(公告)号：JPH0647551A

公开(公告)日：1994-02-22

申请号：JP22099492

申请日：1992-07-29

Applicant: AGENCY IND SCIENCE TECHN

Inventor： FUKUDA TAKASHI ,  BABA YUKIHIKO

IPC: B23K9/028 ,  B23K9/23 ,  B23K35/30

Abstract: PURPOSE:To circumferentially weld steel pipes clad with Cu-Ni alloys to each other on one side from the outer peripheral side. CONSTITUTION:Beads of single layer or plural layers are formed side by using a welding material of the same material as that of the material to be welded having the same compsn. as the compsn. of cladding metals 2 or the compsn. analogous therewith at the time of joining the steel pipes clad with the Cu-Ni alloys as the cladding metals 2 to each other. The beads of the single layer or plural layers are then formed on the upper layer thereof by using an Cu-Ni alloy or Ni-Cr-Mo alloy welding material, by which these steel pipes are circumferentially welded. Then, the steel pipes clad with the Cu-Ni alloys are efficiently joined to each other by one-side welding; in addition, the excellent weldability is obtd.