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公开(公告)号:DE19917897A1
公开(公告)日:2000-10-26
申请号:DE19917897
申请日:1999-04-20
Applicant: BASF AG
Inventor: LORENZ REINHARD , BAUER STEPHAN , JUNGE DIETER , BAUM EVA , HARRE KATHRIN , ERBES JOERG , OSTROWSKI THOMAS , GROSCH GEORG HEINRICH
Abstract: A polyurethane (I) is prepared by reaction of (A) a polyisocyanate with (B) a compound having at least two isocyanate reactive hydrogen atoms. (B) is a polyether alcohol, prepared by addition of an alkylene oxide with an H functional started compound by means of a multi-metal cyanide catalyst and reaction in the presence of at least one metal salt. An Independent claim is included for the polyether alcohol (B).
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公开(公告)号:CA2260343A1
公开(公告)日:1999-08-13
申请号:CA2260343
申请日:1999-02-11
Applicant: BASF AG
Inventor: REICHELT MICHAEL , JUNG LUDWIG , ROTERMUND UDO , BAUM EVA
Abstract: Rigid foams based on isocyanate are produced by reacting a) organic and/or modified organic polyisocyanates with b) at least one relatively high molecular weight compound containing at least two reactive hydrogen atoms and, if desired, c) low molecular weight chain extenders and/or crosslinkers in the presence of d) carbon dioxide as sole or additional blowing agent, e) foam stabilizers, f) catalysts and, if desired, g) further auxiliaries and/or additives, wherein at least one organosilicon compound having a relative ethylene oxide/propylene oxide weight ratio of over 70/30 is used as foam stabilizer, with the total Si content being greater than or equal to 5% by weight, based on the weight of the foam stabilizer or stabilizers used. The isocyanate-based rigid foams produced in this way can be used as insulation material.
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公开(公告)号:DE19546371A1
公开(公告)日:1997-06-19
申请号:DE19546371
申请日:1995-12-12
Applicant: BASF AG
Inventor: HINZ WERNER DR , KRECH RUEDIGER , ROTERMUND UDO DR , BAUM EVA
IPC: C08G18/10 , C08G18/12 , C08G18/40 , C08G18/64 , C08G18/42 , C08G18/48 , C08G18/50 , C08G18/65 , C08L75/04 , D06N7/00
Abstract: A method of preparing an isocyanate prepolymer mixture containing urethane groups and reactive isocyanate groups, comprises reacting: (a) di- and/or polyisocyanate(s) with: (b-1) oligo- and/or polysaccharide(s); and optionally (b-2) polyester-polyol(s) and/or polyether-polyol(s) to give the isocyanate prepolymer mixture containing 5-30 wt.% reactive isocyanate groups. Also claimed are: (1) the isocyanate prepolymer mixt.; (2) use of a reaction extruder in the preparation of an isocyanate prepolymer mixture; (3) a method (I) of producing compact or cellular polyurethane containing oligo- and/or polysaccharide(s) from an isocyanate prepolymer mixture; (4) the polyurethane per se; and (5) mouldings made from the polyurethane.
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公开(公告)号:ES2288699T3
公开(公告)日:2008-01-16
申请号:ES04797695
申请日:2004-11-06
Applicant: BASF AG
Inventor: OSTROWSKI THOMAS , RUPPEL RAIMUND , BAUM EVA , HARRE KATHRIN
Abstract: Un proceso para la preparación continua de alcoholes polietéricos mediante reacción de óxidos de alquileno con sustancias iniciadoras H-funcionales en presencia de catalizadores DMC, caracterizado porque comprende al comienzo del proceso a) colocar primero material de carga inicial y cataliador DMC en un reactor, b) dosificar óxido de alquileno de modo que la velocidad de dosificación que se mantiene para la operación continua del reactor se logre en un tiempo desde 100 hasta 3000 segundos, c) dosificar sustancia iniciadora durante o después del paso b) de modo que la velocidad de dosificación que se mantiene para la operación continua se logra en un tiempo de 5 hasta 500 segundos, d) después de que se haya alcanzado el nivel de llenado deseado en el reactor para la operación continua del reactor, retirar el producto continuamente del reactor mientras que al mismo tiempo se dosifica sustancia iniciadora y óxidos de alquileno en tal cantidad que el nivel de llenado en el reactor se mantieneconstante y dosificar catalizador DMC para que en el reactor se mantenga la concentración de catalizador necesaria para la operación continua del reactor.
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公开(公告)号:DK1537159T3
公开(公告)日:2007-12-03
申请号:DK03790810
申请日:2003-07-24
Applicant: BASF AG
Inventor: BAUER STEPHAN , RUPPEL RAIMUND , BAUM EVA , WINKLER JUERGEN , BOHRES EDWARD
Abstract: The present invention provides a process for producing low-emission flexible polyurethane foams having a reduced odor and reduced fogging by reacting a) polyisocyanates with b) compounds having at least two hydrogen atoms which are reactive toward isocyanate groups, c) blowing agents wherein polyether alcohols which have been prepared by addition of alkylene oxides onto compounds derived from renewable raw materials using DMC catalysts are used as compounds b) having at least two hydrogen atoms which are reactive toward isocyanate groups.
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公开(公告)号:RU2308465C2
公开(公告)日:2007-10-20
申请号:RU2004115338
申请日:2002-10-18
Applicant: BASF AG , RIDZHENTS OF DZE UNIV OF MICHI
Inventor: MJULLER UL RIKH , SHTESSER MIKHAEL , RUPPEL RAJMUND , BAUM EVA , BORES EHDVARD , ZIGI MARKUS , LOBRI LAJZA , JAGI OMAR M , EDDAUDI MOKHAMED
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27.
公开(公告)号:PT1537159E
公开(公告)日:2007-10-19
申请号:PT03790810
申请日:2003-07-24
Applicant: BASF AG
Inventor: BAUER STEPHAN , BAUM EVA , BOHRES EDWARD , RUPPEL RAIMUND , WINKLER JUERGEN
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公开(公告)号:DE502004004261D1
公开(公告)日:2007-08-16
申请号:DE502004004261
申请日:2004-11-06
Applicant: BASF AG
Inventor: OSTROWSKI THOMAS , RUPPEL RAIMUND , BAUM EVA , HARRE KATHRIN
Abstract: The invention relates to a process for the continuous preparation of polyether alcohols by reaction of alkylene oxides with H-functional starter substances in the presence of DMC catalysts, which comprises, at the beginning of the process a) firstly placing initial charge material and DMC catalyst in a reactor, b) metering in alkylene oxide so that the metering rate which is maintained for continuous operation of the reactor is reached in a time of from 100 to 3000 seconds, c) metering in starter substance during or after step b) so that the metering rate which is maintained for continuous operation of the reactor is reached in a time of from 5 to 500 seconds, d) after the fill level in the reactor which is desired for continuous operation of the reactor has been reached, taking product off continuously from the reactor while at the same time metering in starter substance and alkylene oxides in such an amount that the fill level in the reactor remains constant and metering in DMC catalyst so that the catalyst concentration necessary for continuous operation of the reactor is maintained in the reactor.
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公开(公告)号:DE102005020347A1
公开(公告)日:2006-11-09
申请号:DE102005020347
申请日:2005-05-02
Applicant: BASF AG
Inventor: BOHRES EDWARD , STOESER MICHAEL , VOELKEL LUDWIG , RUPPEL RAIMUND , BAUM EVA , WAGNER NORBERT , SUNDERMEYER JOERG , GARRELTS UDO , ZIRNSTEIN MICHAEL
Abstract: Process for preparing double metal cyanide catalysts of the general formula (I) M2a[M1(CN)rXt]b (I) where M2 is preferably Co(III) or Fe(III), and M1 is preferably Zn(II), X is a group other than cyanide which forms a coordinate bond to M1 and is selected from the group consisting of carbonyl, cyanate, isocyanate, nitrile, thiocyanate and nitrosyl, a, b, r, t are integers which are selected so that the compound is electrically neutral, by reacting a) a cyanometallic acid of the general formula (II) Hw[M1(CN)r(X)t] where M1 and X are as defined above, r and t are as defined above and w is selected so that the compound is electrically neutral, with b) a readily protolyzable metal compound (IIIa) M2Rw and/or (IIIb) M2RuYv, where M2 is as defined above, the groups R are identical or different and are each the anion of a very weak protic acid having a pKa of >=20, and Y is the anion of an inorganic mineral acid or a moderately strong to strong organic acid having a pKa of from -10 to +10, w corresponds to the valence of M2, u+v corresponds to the valence of M2, with u and v each being at least 1, with the reaction being carried out in a nonaqueous, aprotic solvent.
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公开(公告)号:DE50204894D1
公开(公告)日:2005-12-15
申请号:DE50204894
申请日:2002-08-10
Applicant: BASF AG
Inventor: BAUM EVA , GROSCH HEINRICH , BECHTEL SIEGFRIED , RUPPEL RAIMUND , HARRE KATHRIN , BOHRES EDWARD
Abstract: The catalytic activity of multimetal cyanide compounds used as catalysts for the addition of alkylene oxides onto H-functional starter substances is increased by subjecting the multimetal cyanide compounds to deagglomeration immediately before they are mixed with the H-functional starter substances.
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