METHOD FOR PRODUCING ALKYLPOLYALKYLENE GLYCOL CARBOXYLATE

    公开(公告)号:JP2003138007A

    公开(公告)日:2003-05-14

    申请号:JP2002173836

    申请日:2002-06-14

    Applicant: BASF AG

    Abstract: PROBLEM TO BE SOLVED: To provide a catalyst which is suitable for the reaction of a carboxylic ester with an alkylene oxide and enables to produce a desired alkylpolyalkylene glycol carboxylate under a mild reaction condition without any undesirable byproduct formed. SOLUTION: The alkylpolyalkylene glycol carboxylate can be produced by a method comprising a process for reacting a carboxylic ester with an alkylene oxide in the presence of a multimetal cyanide compound as a catalyst represented by formula (I): M 2 M a [M (CN)b (A)c ]d fM g Xn mM p Yq h(H2 O)eLkP, for example, by formula (II): M Fe[Fe(CN)6 ]nH2 O [wherein M is a potassium ion (K ) or an ammonium ion (NH4 )]; and can be used as a raw material for a concrete fluidizing polymer.

    6.
    发明专利
    未知

    公开(公告)号:DE50011779D1

    公开(公告)日:2006-01-12

    申请号:DE50011779

    申请日:2000-01-07

    Applicant: BASF AG

    Abstract: An acylated polyamine polymers (I) are new. New acylated polyamine polymers (I) comprise acyl groups of formulas -CO-R (i) or -CO-R (ii) on some of the nitrogen atoms of the polyamine (I). R = 7-27C alkyl, 7-27C alkenyl or 7-27C hydroxyalkyl; and R = H, 1-6C alkyl or 1-6C hydroxyalkyl. Independent claims are also included for: (1) the preparation of (I) by reacting a polyamine with at least one carboxylic acid of formula R -COOH and at least one carboxylic acid of formula R -COOH or their esters, anhydrides or halogenated derivatives; (2) the preparation of (I) by cationic ring opening polymerization of: (a) at least one 4,5-dihydro-oxazole and/or 5,6-dihydro-4H-1,3-oxazine, both substituted with R on position 2; and (b) at least one 4,5-dihydro-oxazole and/or 5,6-dihydro-4H-1,3-oxazine, both substituted with R on position 2; and (c) optionally at least one other comonomer; (3) an aqueous composition comprising at least one acylated polyamine (I); (4) a method for increasing the viscosity of a composition containing surfactants by adding (I).

    10.
    发明专利
    未知

    公开(公告)号:DE59813264D1

    公开(公告)日:2006-01-12

    申请号:DE59813264

    申请日:1998-04-16

    Applicant: BASF AG

    Abstract: The disclosure sets forth aqueous cationic surfactant formulations and a process for their preparation. The formulations contains in solution a) from 10 to 50% by weight of a quaternary ammonium compound of the formula I:where: the substituents have the meanings set forth in the description, and b) from 0.01 to 15% by weight of an amine of the formula III:and c) from 0.1 to 5.0% by weight of a buffer which maintains a pH in a range from 4 to 9. The surfactant formulation is prepared by reacting an amine of the formula IIIin aqueous solution with a dialkyl sulfate of the formula IVwhere R1 to R5 are in a molar ratio range from 85 to 99.99 mol %, based on the amine and at from 20 to 100 degrees C. and then adding to the reaction solution from 0.1 to 5.0% by weight of a buffer which maintains a pH in a range from 4 to 9.

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