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公开(公告)号:DE10225594A1
公开(公告)日:2003-12-18
申请号:DE10225594
申请日:2002-06-07
Applicant: BASF AG
Inventor: BAUM PIA , MICHL KATHRIN , WEINGART FRANZ , NIED STEPHAN , BRODT GREGOR
IPC: C08F290/06 , C11D3/37
Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.
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公开(公告)号:DE10156133A1
公开(公告)日:2003-05-28
申请号:DE10156133
申请日:2001-11-16
Applicant: BASF AG
Inventor: BAUM PIA , MUELLER CHRISTINE , OSWALD ANKE , POTTHOFF-KARL BIRGIT
IPC: C08F261/06 , C08F283/06 , C08F287/00 , C08L51/00 , C08L51/08 , C11D3/00 , C11D3/37 , C08F283/10
Abstract: Graft polymer, comprising (A) a polymer graft skeleton with no mono-ethylenic unsaturated units and (B) polymer sidechains formed from co-polymers of two different mono-ethylenic unsaturated monomers (B1) and (B2), each comprising a nitrogen-containing heterocycle, whereby the proportion of the sidechains (B) amounts to more than 55 wt. % of the total polymer.
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公开(公告)号:CA2467308A1
公开(公告)日:2003-05-22
申请号:CA2467308
申请日:2002-11-11
Applicant: BASF AG
Inventor: POTTHOFF-KARL BIRGIT , BAUM PIA , OSWALD ANKE , MUELLER CHRISTINE
IPC: C08F261/06 , C08F283/06 , C11D3/37
Abstract: Graft polymer, comprising (A) a polymer graft skeleton with no mono-ethyleni c unsaturated units and (B) polymer sidechains formed from co-polymers of two different mono-ethylenic unsaturated monomers (B1) and (B2), each comprising a nitrogen-containing heterocycle, whereby the proportion of the sidechains (B ) amounts to 35 to 55 wt. % of the total polymer.
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公开(公告)号:DE10045314A1
公开(公告)日:2002-03-21
申请号:DE10045314
申请日:2000-09-12
Applicant: BASF AG
Inventor: KOLTZENBURG SEBASTIAN , MUELLER CHRISTINE , BAUM PIA
Abstract: The use of copolymers that contain 0.2-20 wt.% vinylphosphoric acids and/or their alkali metal- or ammonium salts as color run inhibitors in washing and cleaning agents is claimed. The use of copolymers that contain (A) 40-99.8 wt.% 1-vinylpyrrolidone, 1-vinylcaprolactam, 1-vinyltriazole, 1-vinylimidazole, 1-vinyloxazolidinone, 2-vinylpyridine, 4-vinylpyridine, 2-vinylpyridine-N-oxide, 4-vinylpyridine-N-oxide, quaternized vinylimidazoles of formula (1) and/or vinylpyridine-betaine compounds of formula (2). (B) 0.2-20 wt.% vinylphosphoric acids and/or their alkali metal- or ammonium salts, (C) 0-30 wt.% of at least one monoethylenically unsaturated monomers comprising 1-olefins, vinyl esters of saturated carboxylic acids, vinyl ether, ester, amides and nitriles of ethylenically unsaturated carboxylic acids, styrene, alpha -methylstyrene, vinylchloride, vinylidene chloride, vinylsulfonic acid, acrylamido-2-methylpropansulfonic acid, N-vinylpiperidone, N-vinylformamide, N-methyl-N-vinylacetamide, acid anhydrides of monoethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acids and/or their salts. (D) 0-10 wt.% of at least one monomer containing two ethylenic double bonds. as color run inhibitors in washing and cleaning agents is claimed. R = 1-22C alkyl; R ,R = H, 1-4C alkyl or aryl; X = anion; M = H, alkali metal or ammonium; n = 1-5
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公开(公告)号:BRPI0510240B1
公开(公告)日:2016-02-10
申请号:BRPI0510240
申请日:2005-04-26
Applicant: BASF AG
Inventor: BRODT GREGOR , GUZMANN MARCUS , BAUM PIA , SEEBECK TANJA
IPC: C08F26/06 , C08F226/06 , C11D3/00 , C11D3/37
Abstract: uso de um copolímero, copolímero, processo para preparar o mesmo, e, formulação detergente líquida ou sólida. a invenção está relacionada ao uso de um copolímero que compreende, em uma forma polimerizada: (a) de 80 a 99,9 por cento em moles de pelo menos um monômero a contendo um respectivo heterocíclico que é provido de pelo menos um átomo de n e é composto de 3 a 10 membros no anel, e um grupo c~ 2~-c~ 6~ alquenil que é ligado a um átomo de c do anel ou a um átomo de n do anel do heterocíclico; e (b) de 0,1 a 20 por cento em moles de pelo menos um monômero b que é polimerizável com o monômero a e contém uma monoetilenicamente insaturada dupla ligação, e um grupo linear ou ramificado poli c~ 2~-c~ 4~ óxido de alquileno com uma média de 4 a 500 unidades de c~ 2~-c~ 4~ óxido de alquileno, em formulações detergentes liquidas ou sólidas, os percentuais sendo em relação à quantidade total de monômeros polimerizados para produzir o copolímero. a invenção está relacionada ainda a um método para produzir esses copolímeros e formulações detergentes líquidas ou sólidas compreendendo pelo menos um desses copolímeros.
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公开(公告)号:CA2512600C
公开(公告)日:2011-08-09
申请号:CA2512600
申请日:2003-12-24
Applicant: BASF AG
Inventor: DETERING JURGEN , SCHNEIDER TANJA , KLUGLEIN MATTHIAS , BAUM PIA
IPC: C08F267/04 , C08F8/14 , C08F222/08 , C08F283/06 , C08L51/00 , C08L51/08 , C11D3/00 , C11D3/37
Abstract: Copolymers obtainable by free-radical polymerization of (A) at least one monoethylenically unsaturated C4-C8-dicarboxylic anhydride, (B) at least one vinylaromatic compound from the group consisting of styrene and substituted styrenes and (C) at least one monoethylenically unsaturated monomer which contains at least one heteroatom and is different from (A), and partial esterification of the resulting copolymers with (D) alcohol alkoxylates of the formula I (see formula I) in which the variables have the following meanings: R is C2-C6-alkylene radicals, which, when n is > 1, may be identical or different; R1 is C1-C30-alkyl; n is 1 to 200, and if desired hydrolysis of the anhydride groups still present in the copolymers to give carboxyl groups, and use of the copolymers as additive for detergents and cleaners.
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27.
公开(公告)号:CA2488329C
公开(公告)日:2010-11-23
申请号:CA2488329
申请日:2003-06-04
Applicant: BASF AG
Inventor: BAUM PIA , MICHL KATHRIN , WEINGART FRANZ , NIED STEPHAN , BRODT GREGOR
IPC: C11D3/37 , C08F290/06
Abstract: The invention relates to sulfonic acid group-containing copolymers, which also contain the following constituents that are incorporated by polymerization in a statistical or block-by-block manner: (a) 30 to 95 mol % of a least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic acid ester, or one water-soluble salt of a monoethylenically unsaturated carboxylic acid; (b) 3 to 35 mol % of at least one sulfonic acid group-containing monomer of formula (I), in which the variables have the following meanings: R represents hydrogen or methyl; X represents a chemical bond or -COO-R1-; R1 represents unbranched or branched C1-C4 alkylene; M represents hydrogen, alkali metal or ammonium, and; (c) 2 to 35 mol % of at least one non-ionic monomer of formula (II), in which the variables have the following meanings: R2 represents hydrogen or methyl; R3 represents a chemical bond or unbranched or branched C1-C6 alkylene; R4 represents identical or different unbranched or branched C2-C4 alkylene groups; R5 represents unbranched or branched C1-C6 alkyl, C5-C8 cycloalkyl or aryl, and; n represents 3 to 50. These copolymers are used as an additive in detergents and cleansers.
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公开(公告)号:CA2488032C
公开(公告)日:2010-09-14
申请号:CA2488032
申请日:2003-06-04
Applicant: BASF AG
Inventor: BAUM PIA , MICHL KATHRIN , WEINGART FRANZ , NIED STEPHAN , BRODT GREGOR
IPC: C11D3/37 , C08F290/06
Abstract: The invention relates to copolymers which contain alkylene oxide units and also contain the following constituents that are incorporated by polymerization in a statistical or block-by-block manner: (a) 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of the acrylic acid; (b) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of the methacrylic acid, and; (c) 2 to 20 mol % of at least one non-ionic monomer of formula (II), in which the variables have the following meanings: R1 represents hydrogen or methyl; R2 represents a chemical bond or unbranched or branched C1-C6 alkylene; R3 represents identical or different unbranched or branched C2-C4 alkylene groups; R4 represents unbranched or branched C1-C6 alkyl, and; n ranges from 3 to 50. These copolymers are used as an additive in detergents and cleansers.
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公开(公告)号:AT369317T
公开(公告)日:2007-08-15
申请号:AT04739138
申请日:2004-05-06
Applicant: BASF AG
Inventor: BAUM PIA , LUTZ ERICH , GUZMANN MARCUS , BUECHNER KARL-HEINZ , BRODT GREGOR
IPC: C02F5/12 , C08F8/00 , C08F8/34 , C08F20/58 , C08F220/06 , C08F220/58 , C23F11/173
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公开(公告)号:DE50305365D1
公开(公告)日:2006-11-23
申请号:DE50305365
申请日:2003-06-04
Applicant: BASF AG
Inventor: BAUM PIA , MICHL KATHRIN , WEINGART FRANZ , NIED STEPHAN , BRODT GREGOR
IPC: C11D3/37 , C08F290/06
Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.
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