Use of copolymers containing alkylene oxide units, (meth)acrylic acids or their salts, and nonionic monomer as anti coating washing and cleaning material additives

    公开(公告)号:DE10225594A1

    公开(公告)日:2003-12-18

    申请号:DE10225594

    申请日:2002-06-07

    Applicant: BASF AG

    Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.

    Use of copolymers that contain 0.2-20 wt.% vinylphosphoric acids and/or their alkali metal- or ammonium salts as color run inhibitors in washing and cleaning agents.

    公开(公告)号:DE10045314A1

    公开(公告)日:2002-03-21

    申请号:DE10045314

    申请日:2000-09-12

    Applicant: BASF AG

    Abstract: The use of copolymers that contain 0.2-20 wt.% vinylphosphoric acids and/or their alkali metal- or ammonium salts as color run inhibitors in washing and cleaning agents is claimed. The use of copolymers that contain (A) 40-99.8 wt.% 1-vinylpyrrolidone, 1-vinylcaprolactam, 1-vinyltriazole, 1-vinylimidazole, 1-vinyloxazolidinone, 2-vinylpyridine, 4-vinylpyridine, 2-vinylpyridine-N-oxide, 4-vinylpyridine-N-oxide, quaternized vinylimidazoles of formula (1) and/or vinylpyridine-betaine compounds of formula (2). (B) 0.2-20 wt.% vinylphosphoric acids and/or their alkali metal- or ammonium salts, (C) 0-30 wt.% of at least one monoethylenically unsaturated monomers comprising 1-olefins, vinyl esters of saturated carboxylic acids, vinyl ether, ester, amides and nitriles of ethylenically unsaturated carboxylic acids, styrene, alpha -methylstyrene, vinylchloride, vinylidene chloride, vinylsulfonic acid, acrylamido-2-methylpropansulfonic acid, N-vinylpiperidone, N-vinylformamide, N-methyl-N-vinylacetamide, acid anhydrides of monoethylenically unsaturated carboxylic acids, ethylenically unsaturated carboxylic acids and/or their salts. (D) 0-10 wt.% of at least one monomer containing two ethylenic double bonds. as color run inhibitors in washing and cleaning agents is claimed. R = 1-22C alkyl; R ,R = H, 1-4C alkyl or aryl; X = anion; M = H, alkali metal or ammonium; n = 1-5

    uso de um copolímero para ação inibidora de transferência de corantes de materiais têxteis coloridos durante a operação de lavagem detergente líquida ou sólida

    公开(公告)号:BRPI0510240B1

    公开(公告)日:2016-02-10

    申请号:BRPI0510240

    申请日:2005-04-26

    Applicant: BASF AG

    Abstract: uso de um copolímero, copolímero, processo para preparar o mesmo, e, formulação detergente líquida ou sólida. a invenção está relacionada ao uso de um copolímero que compreende, em uma forma polimerizada: (a) de 80 a 99,9 por cento em moles de pelo menos um monômero a contendo um respectivo heterocíclico que é provido de pelo menos um átomo de n e é composto de 3 a 10 membros no anel, e um grupo c~ 2~-c~ 6~ alquenil que é ligado a um átomo de c do anel ou a um átomo de n do anel do heterocíclico; e (b) de 0,1 a 20 por cento em moles de pelo menos um monômero b que é polimerizável com o monômero a e contém uma monoetilenicamente insaturada dupla ligação, e um grupo linear ou ramificado poli c~ 2~-c~ 4~ óxido de alquileno com uma média de 4 a 500 unidades de c~ 2~-c~ 4~ óxido de alquileno, em formulações detergentes liquidas ou sólidas, os percentuais sendo em relação à quantidade total de monômeros polimerizados para produzir o copolímero. a invenção está relacionada ainda a um método para produzir esses copolímeros e formulações detergentes líquidas ou sólidas compreendendo pelo menos um desses copolímeros.

    USE OF COPOLYMERS CONTAINING SULFONIC ACID GROUPS AS ADDITIVE IN DETERGENTS AND CLEANERS

    公开(公告)号:CA2488329C

    公开(公告)日:2010-11-23

    申请号:CA2488329

    申请日:2003-06-04

    Applicant: BASF AG

    Abstract: The invention relates to sulfonic acid group-containing copolymers, which also contain the following constituents that are incorporated by polymerization in a statistical or block-by-block manner: (a) 30 to 95 mol % of a least one monoethylenically unsaturated carboxylic acid, one monoethylenically unsaturated carboxylic acid ester, or one water-soluble salt of a monoethylenically unsaturated carboxylic acid; (b) 3 to 35 mol % of at least one sulfonic acid group-containing monomer of formula (I), in which the variables have the following meanings: R represents hydrogen or methyl; X represents a chemical bond or -COO-R1-; R1 represents unbranched or branched C1-C4 alkylene; M represents hydrogen, alkali metal or ammonium, and; (c) 2 to 35 mol % of at least one non-ionic monomer of formula (II), in which the variables have the following meanings: R2 represents hydrogen or methyl; R3 represents a chemical bond or unbranched or branched C1-C6 alkylene; R4 represents identical or different unbranched or branched C2-C4 alkylene groups; R5 represents unbranched or branched C1-C6 alkyl, C5-C8 cycloalkyl or aryl, and; n represents 3 to 50. These copolymers are used as an additive in detergents and cleansers.

    USE OF COPOLYMER CONTAINING ALKYLENE OXIDE UNITS AS ADDITIVE IN DETERGENTS AND CLEANERS

    公开(公告)号:CA2488032C

    公开(公告)日:2010-09-14

    申请号:CA2488032

    申请日:2003-06-04

    Applicant: BASF AG

    Abstract: The invention relates to copolymers which contain alkylene oxide units and also contain the following constituents that are incorporated by polymerization in a statistical or block-by-block manner: (a) 50 to 93 mol % of acrylic acid and/or of a water-soluble salt of the acrylic acid; (b) 5 to 30 mol % of methacrylic acid and/or of a water-soluble salt of the methacrylic acid, and; (c) 2 to 20 mol % of at least one non-ionic monomer of formula (II), in which the variables have the following meanings: R1 represents hydrogen or methyl; R2 represents a chemical bond or unbranched or branched C1-C6 alkylene; R3 represents identical or different unbranched or branched C2-C4 alkylene groups; R4 represents unbranched or branched C1-C6 alkyl, and; n ranges from 3 to 50. These copolymers are used as an additive in detergents and cleansers.

    30.
    发明专利
    未知

    公开(公告)号:DE50305365D1

    公开(公告)日:2006-11-23

    申请号:DE50305365

    申请日:2003-06-04

    Applicant: BASF AG

    Abstract: The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its a water soluble (50-93), (b) methacrylic acid and/or one of its a water soluble salts (5-30), and (c) at least one nonionic monomer (2-20), statistically or block polymerized as washing and cleaning material additives is new. The use of copolymers containing alkylene oxide units and (mole%): (a) acrylic acid and/or one of its water soluble salts (50-93); (b) methacrylic acid and/or one of its a water soluble salts (5-30); and (c) at least one nonionic monomer (2-20) of formula (I). R1 = H or Me, R2 = chemical bond or optionally branched 1-6C alkylene, R3 = optionally branched 2-4C alkylene, R4 = optionally branched 1-6C alkyl, n = 3-50, statistically or block polymerized as washing and cleaning material additives. An Independent claim is also included for a washing and cleaning material containing the copolymer as a coating inhibiting additive.

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